Please use this identifier to cite or link to this item:
http://elar.urfu.ru/handle/10995/27463
Title: | Synthesis and kinetics of the cyclization of 3-(dialkylaminophenyl)-2- (phenylcarbonyl)-prop-2-enenitriles |
Authors: | Platonova, A. Y. Glukhareva, T. V. Zimovets, O. A. El'tsov, O. S. Morzherin, Y. Y. |
Issue Date: | 2013 |
Publisher: | Chemistry of Heterocyclic Compounds |
Citation: | Synthesis and kinetics of the cyclization of 3-(dialkylaminophenyl)-2- (phenylcarbonyl)-prop-2-enenitriles / A. Y. Platonova, T. V. Glukhareva, O. A. Zimovets [et al.] // Chemistry of Heterocyclic Compounds. — 2013. — Vol. 49. — № 5. — P. 736-745. |
Abstract: | The reaction of ortho-(N,N-dialkylamino)benzaldehydes with benzoylacetonitrile gave fused 1,2,3,4-tetra-hydroquinolino-5-carbonitriles due to cyclization of the intermediate 2-(phenylcarbonyl)-3-[2-[(dialkyl-amino) phenyl]prop-2-enenitriles through a tert-amino effect mechanism. Kinetic studies were carried out on the cyclization of 2-(phenylcarbonyl)-3-[2-(piperidin-1-yl) phenyl]prop-2-enenitrile. © 2013 Springer Science+Business Media New York. |
Keywords: | 1,2,3,4-TETRAHYDROQUINOLINES CYCLIZATION N,N-DIALKYL-O-VINYLANILINES REACTION KINETICS STEREOSELECTIVITY TERT-AMINO EFFECT |
URI: | http://elar.urfu.ru/handle/10995/27463 |
SCOPUS ID: | 84882858124 |
WOS ID: | 000323201200010 |
PURE ID: | 922584 |
ISSN: | 0009-3122 1573-8353 |
DOI: | 10.1007/s10593-013-1305-2 |
Appears in Collections: | Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
scopus-2013-0612.pdf | 665,43 kB | Adobe PDF | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.