Synthesis of a novel planar-chiral nido-carborane amino acid

Telegina, A. A.; Gruzdev, D. A.; Levit, G. L.; Krasnov, V. P.

doi:10.1007/s11172-021-3121-7

Please use this identifier to cite or link to this item: http://elar.urfu.ru/handle/10995/132450

Title:	Synthesis of a novel planar-chiral nido-carborane amino acid
Authors:	Telegina, A. A. Gruzdev, D. A. Levit, G. L. Krasnov, V. P.
Issue Date:	2021
Publisher:	Springer
Citation:	Telegina, AA, Gruzdev, DA, Levit, GL & Krasnov, VP 2021, 'Synthesis of a novel planar-chiral nido-carborane amino acid', Russian Chemical Bulletin, Том. 70, № 3, стр. 539-544. https://doi.org/10.1007/s11172-021-3121-7 Telegina, A. A., Gruzdev, D. A., Levit, G. L., & Krasnov, V. P. (2021). Synthesis of a novel planar-chiral nido-carborane amino acid. Russian Chemical Bulletin, 70(3), 539-544. https://doi.org/10.1007/s11172-021-3121-7
Abstract:	The deboronation of enantiomers of planar-chiral benzyl (3-formamido-1,2-dicarba-closo-dodecaboran-1-yl)acetate gave the individual (RP)- and (SP)-enantiomers (ee > 98%) of a new amino acid containing a nido-carborane fragment, (3-ammonio-7,8-dicarba-nido-undecaboran-7-yl)acetic acid. Chiral HPLC methods for the analysis of enantiomeric purity of this compound was developed. © 2021, Springer Science+Business Media LLC.
Keywords:	AMINO ACID CARBORANE DEBORONATION PLANAR CHIRALITY
URI:	http://elar.urfu.ru/handle/10995/132450
Access:	info:eu-repo/semantics/openAccess cc-by
SCOPUS ID:	85103534319
WOS ID:	000633737400018
PURE ID:	bcab6646-4e75-473d-ab96-bac276416c31 21181733
ISSN:	1066-5285
DOI:	10.1007/s11172-021-3121-7
Sponsorship:	Ministry of Education and Science of the Russian Federation, Minobrnauka, (AAAA-A19-119012490007-8) This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation (Project No. AAAA-A19-119012490007-8). Equipment of the Centre for Joint Use “Spectroscopy and Analysis of Organic Compounds” (CJU “SAOC”) at the Postovsky Institute of Organic Synthesis of the Russian Academy of Sciences (Ural Branch) was used.
Appears in Collections:	Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC

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