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http://elar.urfu.ru/handle/10995/132372
Title: | Gigantic supramolecular assemblies built from dynamic hierarchical organization between inorganic nanospheres and porphyrins |
Authors: | Grzhegorzhevskii, K. Haouas, M. Lion, M. Vashurin, A. Denikaev, A. Marfin, Y. Kim, G. Falaise, C. Cadot, E. |
Issue Date: | 2022 |
Publisher: | Royal Society of Chemistry |
Citation: | Grzhegorzhevskii, K, Haouas, M, Lion, M, Vashurin, A, Denikaev, A, Marfin, Y, Kim, G, Falaise, C & Cadot, E 2022, 'Gigantic supramolecular assemblies built from dynamic hierarchical organization between inorganic nanospheres and porphyrins', Chemical Communications, Том. 59, № 1, стр. 86-89. https://doi.org/10.1039/D2CC05193A Grzhegorzhevskii, K., Haouas, M., Lion, M., Vashurin, A., Denikaev, A., Marfin, Y., Kim, G., Falaise, C., & Cadot, E. (2022). Gigantic supramolecular assemblies built from dynamic hierarchical organization between inorganic nanospheres and porphyrins. Chemical Communications, 59(1), 86-89. https://doi.org/10.1039/D2CC05193A |
Abstract: | Noncovalent ionic interactions between nanosized Keplerate-type capsules {Mo132} and tetra-cationic porphyrins have been investigated in aqueous solution using small-angle X-ray scattering, 1H NMR and photophysical methods. These complementary multiscale methods reveal the formation of large hybrid oligomers built from a short-range organization in which the cationic porphyrin is glued onto the large POM surface. The local structuring appears to be strongly dependent on the dye : {Mo132} ratio changing the morphology of the oligomers from linear to dense aggregates. © 2023 The Royal Society of Chemistry. |
Keywords: | MAGNETIC RESONANCE SPECTROSCOPY NANOSPHERES PORPHYRINS MORPHOLOGY OLIGOMERS X RAY SCATTERING CATION NANOSPHERE OLIGOMER POLYANION POLYOXOMETALATE PORPHYRIN UNCLASSIFIED DRUG CATIONIC PORPHYRIN HIERARCHICAL ORGANIZATIONS HYBRID OLIGOMERS INORGANIC NANOSPHERES IONIC INTERACTION MULTISCALE METHOD NONCOVALENT PHOTOPHYSICAL SMALL ANGLE X-RAY SCATTERING SUPRAMOLECULAR ASSEMBLIES AQUEOUS SOLUTION ARTICLE CHEMICAL STRUCTURE CONTROLLED STUDY DIFFUSION COEFFICIENT MOLECULAR INTERACTION MORPHOLOGY PROTON NUCLEAR MAGNETIC RESONANCE STOICHIOMETRY SURFACE PROPERTY TITRIMETRY X RAY CRYSTALLOGRAPHY CHEMISTRY NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY PORPHYRINS |
URI: | http://elar.urfu.ru/handle/10995/132372 |
Access: | info:eu-repo/semantics/openAccess |
SCOPUS ID: | 85143967787 |
WOS ID: | 902043400001 |
PURE ID: | 33223880 518347de-a07d-43b1-a42f-0040af33ec33 |
ISSN: | 1359-7345 |
DOI: | 10.1039/d2cc05193a |
Appears in Collections: | Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC |
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