Synthesis, Hydration Processes and Ionic Conductivity of Novel Gadolinium-Doped Ceramic Materials Based on Layered Perovskite BaLa2In2O7 for Electrochemical Purposes

Abstract

The search for novel highly effective materials with target properties for different electrochemical purposes is active for now. Ceramic materials with high levels of ionic conductivity can be applied as electrolytic materials in solid oxide fuel cells and in electrolyzers. Layered perovskites are a novel class of ionic conductors demonstrating almost-pure proton transportation at mid-temperatures. Gadolinium-doped ceramic materials based on layered perovskite BaLa2In2O7 were obtained and investigated for the first time in this study. The effect of the dopant concentrations on the hydration processes and on ionic conductivity was revealed. It was shown that compositions 0 ≤ x ≤ 0.15 of BaLa2–xGdxIn2O7 exhibited proton conductivity when under wet air and at mid-temperatures (lower than ~450 °C). Gadolinium doping led to an increase in the conductivity values up to an order of magnitude of ~0.5. The protonic conductivity of the most conductive composition BaLa1.85Gd0.15In2O7 was 2.7∙10−6 S/cm at 400 °C under wet air. The rare earth doping of layered perovskites is a prospective approach for the design of ceramics for electrochemical devices for energy applications. © 2022 by the authors.