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Title: | Influence of irradiation with fast electron beam on energy transport in praseodymium-ion doped phosphates |
Authors: | Kiselev, S. A. Pustovarov, V. A. |
Issue Date: | 2023 |
Publisher: | Elsevier B.V. |
Citation: | Kiselev, SA & Pustovarov, VA 2023, 'Influence of irradiation with fast electron beam on energy transport in praseodymium-ion doped phosphates', Optical Materials: X, Том. 18, 100239. https://doi.org/10.1016/j.omx.2023.100239 Kiselev, S. A., & Pustovarov, V. A. (2023). Influence of irradiation with fast electron beam on energy transport in praseodymium-ion doped phosphates. Optical Materials: X, 18, [100239]. https://doi.org/10.1016/j.omx.2023.100239 |
Abstract: | This paper reports the spectroscopic properties of praseodymium-doped phosphates, KLuP2O7, Sr9Sc(PO4)7, K3Lu(PO4)2 doped with Pr3+ ions. Spectra of photoluminescence (PL) upon selective UV photon excitation, PL excitation spectra as well as luminescence spectra and decay kinetics upon pulse synchrotron X-ray excitation were studied. Recordings of luminescence spectra were done with pure samples and after irradiating with fast electrons (E = 10 MeV) using linear electron accelerator. The absorbed dose varied in the range of 150–300 kGy. Pure samples demonstrated three typical channels of emission: interconfigurational d – f transitions, intraconfigurational f – f transitions and defect-related luminescence. After irradiating, two scenarios of changing optical properties were investigated: increasing of defect-related luminescence impact in total light output and “suppressing” of defect-located energy emission. © 2023 The Author(s) |
Keywords: | 4F 15D 1 – 4F 2 RADIATIVE TRANSITIONS DEFECT-RELATED LUMINESCENCE DEFECTS RADIATION FORMATION ELECTRON BEAM IRRADIATION ENERGY TRANSFER PHOSPHATES POINT DEFECTS ELECTRON BEAMS ELECTRONS IRRADIATION LUMINESCENCE OPTICAL PROPERTIES PHOSPHATES POINT DEFECTS POTASSIUM COMPOUNDS STRONTIUM COMPOUNDS 4F 15D 1 – 4F 2 RADIATIVE TRANSITION DEFECT RADIATION FORMATION DEFECT-RELATED LUMINESCENCE ELECTRON BEAM IRRADIATION ENERGY-TRANSFER ENERGY-TRANSPORT FAST ELECTRON BEAM LUMINESCENCE SPECTRUM PRASEODYMIUM IONS RADIATIVE TRANSITIONS ENERGY TRANSFER |
URI: | http://elar.urfu.ru/handle/10995/130536 |
Access: | info:eu-repo/semantics/openAccess cc-by-nc-nd |
License text: | https://creativecommons.org/licenses/by-nc-nd/4.0/ |
SCOPUS ID: | 85160748127 |
PURE ID: | 40102774 |
ISSN: | 2590-1478 |
DOI: | 10.1016/j.omx.2023.100239 |
Sponsorship: | Russian Academy of Sciences, РАН; Ministry of Education and Science of the Russian Federation, Minobrnauka: FEUZ–2023–0013; Università degli Studi di Verona The work was partially supported by the Ministry of Science and Higher Education of the Russian Federation (through the basic part of the government mandate, project No. FEUZ–2023–0013). The time-resolved X-ray excited measurements were performed at the shared research center SSTRC on the basis of the VEPP-4 - VEPP-2000 complex at Budker Institute of Nuclear Physics (Siberian Branch of Russian Academy of Sciences, Novosibirsk, Russia). Authors appreciate assistance and want to thank Prof. M. Bettinelli and Dr. F. Piccinelli (University of Verona, Italy) for submitting certified samples for these primary studies and Dr. K. Ivanovskikh (Ural Federal University, Ekaterinburg) for the fruitful discussion. The work was partially supported by the Ministry of Science and Higher Education of the Russian Federation (through the basic part of the government mandate, project No. FEUZ–2023–0013 ). The time-resolved X-ray excited measurements were performed at the shared research center SSTRC on the basis of the VEPP-4 - VEPP-2000 complex at Budker Institute of Nuclear Physics (Siberian Branch of Russian Academy of Sciences, Novosibirsk, Russia). Authors appreciate assistance and want to thank Prof. M. Bettinelli and Dr. F. Piccinelli (University of Verona, Italy) for submitting certified samples for these primary studies and Dr. K. Ivanovskikh (Ural Federal University, Ekaterinburg) for the fruitful discussion. |
Appears in Collections: | Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC |
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