Please use this identifier to cite or link to this item:
http://elar.urfu.ru/handle/10995/123419
Title: | Advancements in N-heterocyclic Carbenes (NHCs) Catalysis for Benzoin Reactions: A Comprehensive Review from Past to Present |
Authors: | Noppawan, P. Phungpis, B. Worawut, K. |
Issue Date: | 2023-06 |
Publisher: | Уральский федеральный университет Ural Federal University |
Citation: | Advancements in N-heterocyclic Carbenes (NHCs) Catalysis for Benzoin Reactions: A Comprehensive Review from Past to Present / P. Noppawan, B. Phungpis, K. Worawut // Chimica Techno Acta. — 2023. — Vol. 10, No. 2. — No. 202310214. |
Abstract: | N-heterocyclic carbenes (NHCs) catalyze benzoin condensation, which is a unique carbon-carbon bond-forming reaction. It entails a coupling reaction between two aldehydes catalyzed by NHCs that produce α-hydroxycarbonyl compounds (acyloins). NHCs have emerged as a potent class of organocatalysts, catalyzing numerous benzoin and benzoin-type reactions. This review provides an overview of the historical development of NHCs and their application in benzoin reactions. Additionally, recent advancements in NHC catalysis, including the use of chiral NHCs, are discussed. This review aims to provide a comprehensive understanding of the current state of NHC catalysis for benzoin reactions and its potential for future developments in synthetic chemistry. |
Keywords: | ACYLOIN α-AMINOCARBONYL COMPOUND BENZOIN CONDENSATION α-HYDROXYCARBONYL COMPOUND N-HETEROCYCLIC CARBENE ORGANOCATALYSIS |
URI: | http://elar.urfu.ru/handle/10995/123419 |
RSCI ID: | https://elibrary.ru/item.asp?id=54268156 |
ISSN: | 2411-1414 |
DOI: | 10.15826/chimtech.2023.10.2.14 |
Origin: | Chimica Techno Acta. 2023. Vol. 10. № 2 |
Appears in Collections: | Chimica Techno Acta |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
cta-2023-2-15.pdf | 2,25 MB | Adobe PDF | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.