Please use this identifier to cite or link to this item: http://hdl.handle.net/10995/112223
Title: Efficient Hydrogen Evolution Reaction with Bulk and Nanostructured Mitrofanovite Pt3 Te4
Authors: D’olimpio, G.
Zhang, L.
Kuo, C. -N.
Farias, D.
Ottaviano, L.
Lue, C. S.
Fujii, J.
Vobornik, I.
Agarwal, A.
Torelli, P.
Boukhvalov, D. W.
Politano, A.
Issue Date: 2022
Publisher: MDPI
MDPI AG
Citation: Efficient Hydrogen Evolution Reaction with Bulk and Nanostructured Mitrofanovite Pt3 Te4 / G. D’olimpio, L. Zhang, C. -N. Kuo et al. // Nanomaterials. — 2022. — Vol. 12. — Iss. 3. — 558.
Abstract: Here, we discuss the key features of electrocatalysis with mitrofanovite (Pt3 Te4 ), a recently discovered mineral with superb performances in hydrogen evolution reaction. Mitrofanovite is a layered topological metal with spin-polarized topological surface states with potential applications for spintronics. However, mitrofanovite is also an exceptional platform for electrocatalysis, with costs of the electrodes suppressed by 47% owing to the partial replacement of Pt with Te. Remarkably, the Tafel slope in nanostructured mitrofanovite is just 33 mV/dec, while reduced mitrofanovite has the same Tafel slope (36 mV/dec) as state-of-the-art electrodes of pure Pt. Mitrofanovite also affords surface stability and robustness to CO poisoning. Accordingly, these findings pave the way for the advent of mitrofanovite for large-scale hydrogen production. © 2022 by the authors. Licensee MDPI, Basel, Switzerland.
Keywords: ELECTROCATALYSIS
HYDROGEN EVOLUTION REACTION
METAL CHALCOGENIDES
URI: http://hdl.handle.net/10995/112223
Access: info:eu-repo/semantics/openAccess
SCOPUS ID: 85123945901
PURE ID: 29558783
ISSN: 2079-4991
metadata.dc.description.sponsorship: Funding: D.W.B. acknowledges support from the Ministry of Science and Higher Education of the Russian Federation (through the basic part of the government mandate, Project No. FEUZ-2020– 0060) and the Jiangsu Innovative and Entrepreneurial Talents Project. This work has been partially supported by the Spanish Ministerio de Ciencia e Innovación under Project PID2019–109525RB-I00. D.F. acknowledges financial support from the Spanish Ministry of Economy and Competitiveness, through the “Maríade Maeztu” Programme for Units of Excellence in R&D (CEX2018-000805-M). I.V., J. F., and P.T. thank NFFA-Trieste.
Appears in Collections:Научные публикации, проиндексированные в SCOPUS и WoS CC

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