On the electropolishing and anodic oxidation of Ti-15Mo alloy

Abstract

This paper presents research on modifying the surface of Ti-15Mo alloy using electropolishing and anodic passivation. The electropolishing process was carried out in solutions containing sulfuric acid, ethylene glycol, ammonium fluoride and oxalic acid. Whereas a voltage range from 20 to 100 V and a 1 M orthophosphoric acid solution were used during the anodic passivation. The influence of above mentioned processes parameters on the quality of the obtained oxide layer on Ti-15Mo alloy was investigated. The analysis of Ti-15Mo surface after modification was performed using scanning electron microscopy (SEM), atomic force microscopy (AFM), energy-dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS), ellipsometry, and mechanical tests. Moreover, the corrosion resistance was investigated using a potentiostatic method in Ringer's solution. It was found that electropolishing leads to an increase in the surface homogeneity and to the form of an oxide layer, which consisted of TiO2 and MoO3. Whereas the oxide layers obtained during anodic passivation were characterized by different properties depending on the applied voltage. The anodic passivation at various voltages (20-100 V) increased the surface wettability (94.5°-87.6°) in comparison to the electropolished sample (97.5°). Moreover, the obtained oxide layer after anodization exhibited a high hardness. The electrolytic polishing and anodic passivation of Ti-15Mo also improved corrosion resistance of the alloy in contact with Ringer's solution. The sample anodized at 80 V presented the highest corrosion resistance by the smallest corrosion current density (1.4 nA cm-2) and the highest polarization resistance (37.4 MΩ cm2). © 2016 Elsevier Ltd. All rights reserved.