Please use this identifier to cite or link to this item: http://hdl.handle.net/10995/96740
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dc.contributor.authorBhattacherjee, D.en
dc.contributor.authorZyryanov, G. V.en
dc.contributor.authorDas, P.en
dc.contributor.authorЗырянов, Г. В.ru
dc.date.accessioned2021-03-15T09:16:11Z-
dc.date.available2021-03-15T09:16:11Z-
dc.date.issued2020-
dc.identifier.citationBhattacherjee D. Hypervalent Iodine(III) promoted ring-rearrangement strategies in conformationally rigid ring systems / D. Bhattacherjee, G. V. Zyryanov, P. Das // Актуальные вопросы органической химии и биотехнологии : материалы очных докладов международной научной конференции (Екатеринбург, 18–21 ноября 2020 г.). — Екатеринбург : Издательство АМБ, 2020. — С. 62-63.ru
dc.identifier.isbn978-5-6045430-2-3-
dc.identifier.urihttp://hdl.handle.net/10995/96740-
dc.description.abstractThe ring-rearrangement reactions are among the important class of atom economic chemical transformations as it involves direct construction of carbocylic or heterocyclic rings through bond migration reactions. The usefulness of such operation has been realized by many publications [1] and applications in the field of organic synthesis, medicinal chemistry, natural product synthesis and chemical biology [2]. Moreover, the inclusion of environmental benign hypervalent iodine(III) reagents in such processes allows to design a milder pathway to achieve desired ring-rearrangement reactions [3]. Herein, in the present context we have demonstrated a milder pathway for hypervalent iodine(III) mediated ring contraction of conformationally rigid exocyclic-β-enaminones for the synthesis of cyclopentanones with concurrent cyanation [4]. Furthermore, the synthesized cyclopentanones serves as a basic template for the synthesis of new class of ∂-valerolactams by the applications of hypervalent iodine reagents [5].en
dc.description.sponsorshipThe work was supported by the Russian Science Foundation grant 19-73-10144 and RFBR grant 18-03-00715.en
dc.format.mimetypeapplication/pdfen
dc.language.isoruen
dc.publisherИздательство АМБru
dc.relationinfo:eu-repo/grantAgreement/RSF//19-73-10144en
dc.relation.ispartofАктуальные вопросы органической химии и биотехнологии. — Екатеринбург, 2020ru
dc.subjectHYPERVALENT IODINE(III)en
dc.subjectRING CONTRACTIONen
dc.subjectRING EXPANSIONen
dc.subjectCYCLOPENTANONESen
dc.subjectLACTAMSen
dc.subjectEXOCYCLIC-β-ENAMINONESen
dc.titleHypervalent Iodine(III) promoted ring-rearrangement strategies in conformationally rigid ring systemsen
dc.typeConference Paperen
dc.typeinfo:eu-repo/semantics/conferenceObjecten
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.conference.nameМеждународная научно-практическая конференция «Актуальные вопросы органической химии и биотехнологии»ru
dc.conference.nameInternational Scientific Conference “Actual Problems of Organic Chemistry and Biotechnology”en
dc.conference.date18.11.2020-21.11.2020-
local.description.firstpage62-
local.description.lastpage63-
local.fund.rsf19-73-10144-
local.fund.rffi18-03-00715-
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