Please use this identifier to cite or link to this item: http://elar.urfu.ru/handle/10995/75679
Title: Double perovskites REBaCo2-xMxO6-δ (RE=La, Pr, Nd, Eu, Gd, Y; M=Fe, Mn) as energy-related materials: An overview
Authors: Tsvetkov, D. S.
Ivanov, I. L.
Malyshkin, D. A.
Sednev, A. L.
Sereda, V. V.
Zuev, A. Y.
Issue Date: 2019
Publisher: De Gruyter
Citation: Double perovskites REBaCo2-xMxO6-δ (RE=La, Pr, Nd, Eu, Gd, Y; M=Fe, Mn) as energy-related materials: An overview / D. S. Tsvetkov, I. L. Ivanov, D. A. Malyshkin et al. // Pure and Applied Chemistry. — 2019. — Vol. 91. — Iss. 6. — P. 923-940.
Abstract: This work, based on the experimental and theoretical research carried out by the authors during the last decade, presents an overview of formation, stability and defect thermodynamics, crystal structure, oxygen nonstoichiometry, chemical strain and transport properties of the double perovskites REBaCo2-xMxO6-δ (RE = La, Pr, Nd, Eu, Gd, Y; M = Fe, Mn). These mixed-conducting oxides are widely regarded as promising materials for various energy conversion and storage devices. Attention is focused on (i) thermodynamics of formation and disordering, oxygen nonstoichiometry, crystal and defect structure of the double perovskites REBaCo2-xMxO6-δ, as well as their thermodynamic stability and the homogeneity ranges of solid solutions, (ii) their overall conductivity and Seebeck coefficient as functions of temperature and oxygen partial pressure and (iii) the anisotropic chemical strain of their crystal lattice. The relationships between the peculiarities of the defect structure and related properties of the double perovskites are analysed. © 2019 IUPAC and De Gruyter.
Keywords: DEFECT STRUCTURE
DEFECT THERMODYNAMICS
DOUBLE PEROVSKITES
ELECTRODE
HTMC-XVI
MEMBRANE
MIXED CONDUCTOR
CHEMICAL STABILITY
DEFECT STRUCTURES
DEFECTS
ELECTRODES
ENERGY CONVERSION
MEMBRANES
OXYGEN
PEROVSKITE
THERMODYNAMICS
VIRTUAL STORAGE
DOUBLE PEROVSKITES
ENERGY CONVERSION AND STORAGES
HTMC-16
MIXED CONDUCTING OXIDES
MIXED CONDUCTORS
OXYGEN NON-STOICHIOMETRY
OXYGEN PARTIAL PRESSURE
THERMODYNAMICS OF FORMATIONS
CRYSTAL STRUCTURE
URI: http://elar.urfu.ru/handle/10995/75679
Access: info:eu-repo/semantics/openAccess
cc-by-nc-nd
hybrid
SCOPUS ID: 85066394797
WOS ID: 000471262400005
PURE ID: 10029859
ISSN: 0033-4545
DOI: 10.1515/pac-2018-1103
metadata.dc.description.sponsorship: This work was supported by Russian Foundation for Basic Research, Funder Id: Http://dx.doi.org/10.13039/501100002261 (Grant No. 18-33-20243\18).
Appears in Collections:Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC

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