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http://elar.urfu.ru/handle/10995/75679
Название: | Double perovskites REBaCo2-xMxO6-δ (RE=La, Pr, Nd, Eu, Gd, Y; M=Fe, Mn) as energy-related materials: An overview |
Авторы: | Tsvetkov, D. S. Ivanov, I. L. Malyshkin, D. A. Sednev, A. L. Sereda, V. V. Zuev, A. Y. |
Дата публикации: | 2019 |
Издатель: | De Gruyter |
Библиографическое описание: | Double perovskites REBaCo2-xMxO6-δ (RE=La, Pr, Nd, Eu, Gd, Y; M=Fe, Mn) as energy-related materials: An overview / D. S. Tsvetkov, I. L. Ivanov, D. A. Malyshkin et al. // Pure and Applied Chemistry. — 2019. — Vol. 91. — Iss. 6. — P. 923-940. |
Аннотация: | This work, based on the experimental and theoretical research carried out by the authors during the last decade, presents an overview of formation, stability and defect thermodynamics, crystal structure, oxygen nonstoichiometry, chemical strain and transport properties of the double perovskites REBaCo2-xMxO6-δ (RE = La, Pr, Nd, Eu, Gd, Y; M = Fe, Mn). These mixed-conducting oxides are widely regarded as promising materials for various energy conversion and storage devices. Attention is focused on (i) thermodynamics of formation and disordering, oxygen nonstoichiometry, crystal and defect structure of the double perovskites REBaCo2-xMxO6-δ, as well as their thermodynamic stability and the homogeneity ranges of solid solutions, (ii) their overall conductivity and Seebeck coefficient as functions of temperature and oxygen partial pressure and (iii) the anisotropic chemical strain of their crystal lattice. The relationships between the peculiarities of the defect structure and related properties of the double perovskites are analysed. © 2019 IUPAC and De Gruyter. |
Ключевые слова: | DEFECT STRUCTURE DEFECT THERMODYNAMICS DOUBLE PEROVSKITES ELECTRODE HTMC-XVI MEMBRANE MIXED CONDUCTOR CHEMICAL STABILITY DEFECT STRUCTURES DEFECTS ELECTRODES ENERGY CONVERSION MEMBRANES OXYGEN PEROVSKITE THERMODYNAMICS VIRTUAL STORAGE DOUBLE PEROVSKITES ENERGY CONVERSION AND STORAGES HTMC-16 MIXED CONDUCTING OXIDES MIXED CONDUCTORS OXYGEN NON-STOICHIOMETRY OXYGEN PARTIAL PRESSURE THERMODYNAMICS OF FORMATIONS CRYSTAL STRUCTURE |
URI: | http://elar.urfu.ru/handle/10995/75679 |
Условия доступа: | info:eu-repo/semantics/openAccess cc-by-nc-nd hybrid |
Идентификатор SCOPUS: | 85066394797 |
Идентификатор WOS: | 000471262400005 |
Идентификатор PURE: | 10029859 |
ISSN: | 0033-4545 |
DOI: | 10.1515/pac-2018-1103 |
Сведения о поддержке: | This work was supported by Russian Foundation for Basic Research, Funder Id: Http://dx.doi.org/10.13039/501100002261 (Grant No. 18-33-20243\18). |
Располагается в коллекциях: | Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC |
Файлы этого ресурса:
Файл | Описание | Размер | Формат | |
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2-s2.0-85066394797.pdf | 1,78 MB | Adobe PDF | Просмотреть/Открыть |
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