Please use this identifier to cite or link to this item: http://hdl.handle.net/10995/75673
Title: Polyfluoroalkylated 2-ethoxymethylene- 3-oxo esters: Synthesis and chemical properties overview
Authors: Saloutin, V. I.
Kudyakova, Y. S.
Goryaeva, M. V.
Burgart, Y. V.
Chupakhin, O. N.
Issue Date: 2017
Publisher: Walter de Gruyter GmbH
Citation: Polyfluoroalkylated 2-ethoxymethylene- 3-oxo esters: Synthesis and chemical properties overview / V. I. Saloutin, Y. S. Kudyakova, M. V. Goryaeva et al. // Pure and Applied Chemistry. — 2017. — Vol. 89. — Iss. 8. — P. 1209-1222.
Abstract: The review focuses on the synthesis and chemical properties of polyfluoroalkylated 2-ethoxymethylene-3-oxo esters. The scope and peculiarities of their use as organic reagents in reactions with various N-, C-, O-, mono- and dinucleophiles are discussed in detail. The high reactivity of such derivatives is employed in the construction of enaminoketone, arene and heterocycle frameworks. Particular attention is paid to applications of these building blocks as chemicals for fine organic synthesis, bioactive compounds and metal complexes synthesis. © 2017 IUPAC & De Gruyter.
Keywords: 2-ETHOXYMETHYLENE-3-OXO ESTERS
CONDENSATION
FLUORINATED BUILDING BLOCKS
HETEROCYCLES
MENDELEEV XX
OPEN-CHAIN LIGANDS
TAUTOMERIZATION
TRANSITION METAL COMPLEXES
CHEMICAL PROPERTIES
CONDENSATION
ESTERS
METAL COMPLEXES
ORGANIC CHEMICALS
TRANSITION METAL COMPOUNDS
TRANSITION METALS
BUILDING BLOCKES
HETEROCYCLES
MENDELEEV XX
OPEN CHAIN
TAUTOMERIZATIONS
SYNTHESIS (CHEMICAL)
URI: http://hdl.handle.net/10995/75673
Access: info:eu-repo/semantics/openAccess
SCOPUS ID: 85024915168
WOS ID: 000410090000016
PURE ID: 1973485
ISSN: 0033-4545
DOI: 10.1515/pac-2016-1015
metadata.dc.description.sponsorship: The authors gratefully acknowledge Russian Foundation for Basic Research (grant no. 16-33-60048 mol-a-dk) and the State Program for Supporting of Leading Scientific Schools of the Russian Federation (grant no. NSh-8922.2016.3) for financial support.
Appears in Collections:Научные публикации, проиндексированные в SCOPUS и WoS CC

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