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http://elar.urfu.ru/handle/10995/75574
Название: | Increased as adsorption on maghemite-containing red mud prepared by the alkali fusion-leaching method |
Авторы: | Shoppert, A. A. Loginova, I. V. Rogozhnikov, D. A. Karimov, K. A. Chaikin, L. I. |
Дата публикации: | 2019 |
Издатель: | MDPI AG |
Библиографическое описание: | Increased as adsorption on maghemite-containing red mud prepared by the alkali fusion-leaching method / A. A. Shoppert, I. V. Loginova, D. A. Rogozhnikov et al. // Minerals. — 2019. — Vol. 9. — Iss. 1. — 60. |
Аннотация: | This study investigates the use of red muds as adsorbents for As (V) removal. Red mud is a waste that contains a large amount of iron oxides and hydroxides, which are excellent adsorbents of arsenic, especially those possessing magnetic properties and a large specific surface area. The purpose of the experiments was to study the possibility of obtaining an effective adsorbent by the direct extraction of alumina from bauxite using the caustic alkali fusion method and to compare the arsenic removal effectiveness and other properties of these red muds with industrial samples. Red muds were described using methods such as X-ray diffraction spectrometry (XRD), X-ray fluorescence spectrometry (XRF), SEM, vibrating sample magnetometry (VSM), and the Brunauer–Emmett–Teller (BET) method. The main iron-containing phase of the red muds obtained by fusing bauxite with caustic alkali is maghemite, which has a large specific surface area. The specific surface area of the obtained samples varied in the range of 6.1–54.9 m 2 /g. Arsenic adsorption experiments were carried out using five different types of red muds: industrial Bayer, industrial sintering, and red mud obtained through bauxite alkali fusion at 300, 500, and 700 ◦ C. The red muds obtained by fusing bauxite with caustic alkali at 300 and 500 ◦ C had the highest effectiveness removing arsenic; their As(V) uptake capacity was over 30 mg/g. © 2019 by the authors. Licensee MDPI, Basel, Switzerland. |
Ключевые слова: | ADSORPTION ALKALI FUSION-LEACHING ARSENATE BAUXITE MAGHEMITE MAGNETIC NANOPARTICLES RED MUD |
URI: | http://elar.urfu.ru/handle/10995/75574 |
Условия доступа: | info:eu-repo/semantics/openAccess |
Идентификатор SCOPUS: | 85061726722 |
Идентификатор WOS: | 000459736200059 |
Идентификатор PURE: | 9059325 |
ISSN: | 2075-163X |
DOI: | 10.3390/min9010060 |
Сведения о поддержке: | The study of the alkali fusion-leaching of bauxite was funded by State Assignment, grant number 10.7347.2017/8.9. The research of arsenic removal was funded by the Russian Science Foundation, grant number 18-19-00186. |
Карточка проекта РНФ: | 18-19-00186 |
Располагается в коллекциях: | Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC |
Файлы этого ресурса:
Файл | Описание | Размер | Формат | |
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10.3390-min9010060.pdf | 17,26 MB | Adobe PDF | Просмотреть/Открыть |
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