Efficiency threshold of carbon layer growth in Li4Ti5O12/C composites

Abstract

The core-shell morphology study is crucial for composite materials, comprised of a low conductive core with a highly conductive thin carbon shell. The study analyzed carbon morphology evolution for the two series of Li4Ti5O12/C samples with carbon content increasing from 0.9 to 5.6 wt%. The conventional X-Ray Photoelectron Spectroscopy (XPS) study allowed us to conclude about the efficiency threshold of carbon layer growth over lithium titanate core for two carbon deposition methods - both sucrose and acetylene decompositions. Although the carbon layer thickness is increasing with carbon concentration growth in LTO/C composites, the efficiency of carbon coverage was shown to decrease with the threshold carbon concentrations about 1-2%. The chemical bonding analysis based on the same XPS data was used for C@LTO interface characterization. The proposed approach can be used for optimization of producing different composites with core-shell structure (carbon-based composites, materials with protective layers, and materials with gradient core-shell structure). © The Author(s) 2018. Published by ECS.