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dc.contributor.authorVolkovich, V. A.en
dc.contributor.authorVasin, B. D.en
dc.contributor.authorGriffiths, T. R.en
dc.date.accessioned2019-07-22T06:45:42Z-
dc.date.available2019-07-22T06:45:42Z-
dc.date.issued2010-
dc.identifier.citationVolkovich V. A. Electrochemical and spectroscopic properties of technetium in fused alkali metal chlorides / V. A. Volkovich, B. D. Vasin, T. R. Griffiths // ECS Transactions. — 2010. — Vol. 33. — Iss. 7. — P. 381-390.en
dc.identifier.issn1938-5862-
dc.identifier.otherhttp://ecst.ecsdl.org/content/33/7/381.full.pdfpdf
dc.identifier.other!!!good_DOI
dc.identifier.otherhttp://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=79952639197m
dc.identifier.other8274130f-caea-47f6-95aa-9e2c6f3d0e1dpure_uuid
dc.identifier.urihttp://elar.urfu.ru/handle/10995/75214-
dc.description.abstractThe behavior of metallic technetium in chloride melts was studied for the first time. The experiments were conducted in NaCl-2CsCl eutectic melt at 550 °C using high temperature electronic absorption spectroscopy, cyclic voltammetry and chronopotentiometry. The anodic dissolution of Tc results in the formation of a mixture of Tc(IV) and a lower oxidation state species. Cyclic voltammograms of technetium-containing melts show two cathodic and two associated anodic peaks. One pair is around -0.35 V vs. Ag/AgCl reference electrode and is associated with the deposition of Tc metal. ©The Electrochemical Society.en
dc.description.sponsorshipPhysical and Analytical Electrochemistry;Electrodeposition;Energy Technologyen
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.rightsinfo:eu-repo/semantics/openAccessen
dc.sourceECS Transactionsen
dc.subjectAG/AGCLen
dc.subjectALKALI METAL CHLORIDESen
dc.subjectANODIC DISSOLUTIONen
dc.subjectANODIC PEAKSen
dc.subjectCHLORIDE MELTen
dc.subjectCHRONOPOTENTIOMETRYen
dc.subjectCYCLIC VOLTAMMOGRAMSen
dc.subjectEUTECTIC MELTen
dc.subjectHIGH-TEMPERATURE ELECTRONICSen
dc.subjectOXIDATION STATEen
dc.subjectREFERENCE ELECTRODESen
dc.subjectSPECTROSCOPIC PROPERTYen
dc.subjectABSORPTION SPECTROSCOPYen
dc.subjectALKALI METALSen
dc.subjectANODIC OXIDATIONen
dc.subjectCYCLIC VOLTAMMETRYen
dc.subjectDISSOLUTIONen
dc.subjectELECTROCHEMICAL ELECTRODESen
dc.subjectELECTROCHEMICAL PROPERTIESen
dc.subjectFUSED SALTSen
dc.subjectSODIUM CHLORIDEen
dc.subjectTECHNETIUMen
dc.subjectIONIC LIQUIDSen
dc.titleElectrochemical and spectroscopic properties of technetium in fused alkali metal chloridesen
dc.typeConference Paperen
dc.typeinfo:eu-repo/semantics/conferenceObjecten
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.conference.name17th International Symposium on Molten Salts and Ionic Liquids - 218th ECS Meetingen
dc.conference.date10 October 2010 through 15 October 2010-
dc.identifier.doi10.1149/1.3484796-
dc.identifier.scopus79952639197-
local.affiliationDepartment of Rare Metals and Nanomaterials, Ural State Technical University-UPI, Ekaterinburg, 620002, Russian Federationen
local.affiliationRedston Trevor Consulting, Ltd., Leeds, LS17 8RF, United Kingdomen
local.contributor.employeeВолкович Владимир Анатольевичru
local.contributor.employeeВасин Борис Дмитриевичru
local.description.firstpage381-
local.description.lastpage390-
local.issue7-
local.volume33-
dc.identifier.wos000313618000040-
local.identifier.pure9050064-
local.identifier.eid2-s2.0-79952639197-
local.identifier.wosWOS:000313618000040-
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