Please use this identifier to cite or link to this item: http://hdl.handle.net/10995/74004
Title: Leaching kinetics of sulfides from refractory gold concentrates by nitric acid
Authors: Rogozhnikov, D. A.
Shoppert, A. A.
Dizer, O. A.
Karimov, K. A.
Rusalev, R. E.
Issue Date: 2019
Publisher: MDPI AG
Citation: Leaching kinetics of sulfides from refractory gold concentrates by nitric acid / D. A. Rogozhnikov, A. A. Shoppert, O. A. Dizer, et al. // Metals. — 2019. — Vol. 9. — Iss. 4. — 465. — DOI: 10.3390/met9040465.
Abstract: The processing of refractory gold-containing concentrates by hydrometallurgical methods is becoming increasingly important due to the depletion of rich and easily extracted mineral resources, as well as due to the need to reduce harmful emissions from metallurgy, especially given the high content of arsenic in the ores. This paper describes the investigation of the kinetics of HNO3 leaching of sulfide gold-containing concentrates of the Yenisei ridge (Yakutia, Russia). The effect of temperature (70–85 °C), the initial concentration of HNO3 (10–40%) and the content of sulfur in the concentrate (8.22–22.44%) on the iron recovery into the solution was studied. It has been shown that increasing the content of S in the concentrate from 8.22 to 22.44% leads to an average of 45% increase in the iron recovery across the entire range temperatures and concentrations of HNO3 per one hour of leaching. The leaching kinetics of the studied types of concentrates correlates well with the new shrinking core model, which indicates that the reaction is regulated by interfacial diffusion and diffusion through the product layer. Elemental S is found on the surface of the solid leach residue, as confirmed by XRD and SEM/EDS analysis. The apparent activation energy is 60.276 kJ/mol. The semi-empirical expression describing the reaction rate under the studied conditions can be written as follows: 1/3ln(1 - X) + [(1 - X)-1/3 - 1] = 87.811(HNO3)0.837(S)2.948e-60276/RT·t. © 2019 by the authors. Licensee MDPI, Basel, Switzerland.
Keywords: ARSENIC
ARSENOPYRITE
KINETICS
NITRIC ACID
PYRITE
REDUCING HARMFUL EMISSIONS
REFRACTORY GOLD CONCENTRATE
RESOURCES DEPLETION
SHRINKING CORE MODEL
URI: http://hdl.handle.net/10995/74004
metadata.dc.rights: cc-by
SCOPUS ID: 85066998327
WOS ID: 000467637000082
PURE ID: 9830529
ISSN: 2075-4701
DOI: 10.3390/met9040465
metadata.dc.description.sponsorship: Funding: The research was funded by the Russian Science Foundation, grant number 18-19-00186. The SEM/EDS and microprobe analysis were funded by State Assignment, grant number 11.4797.2017/8.9.
RSCF project card: 18-19-00186
Appears in Collections:Научные публикации, проиндексированные в SCOPUS и WoS CC

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