Please use this identifier to cite or link to this item: http://hdl.handle.net/10995/51453
Title: Synthesis of 1-amino-2,5-di(2-thienyl)benzenes as potential monomers for the preparation of hybrid polythiophene anionic sensors
Authors: Zyryanov, G. V.
Kovalev, I. S.
Egorov, I. N.
Rusinov, V. L.
Chupakhin, O. N.
Зырянов, Г. В.
Issue Date: 2012
Citation: Synthesis of 1-amino-2,5-di(2-thienyl)benzenes as potential monomers for the preparation of hybrid polythiophene anionic sensors / G. V. Zyryanov, I. S. Kovalev, I. N. Egorov, V. L. Rusinov, O. N. Chupakhin // Russian Chemical Bulletin. — 2012. — Vol. 61. — № 2. — P. 303-307.
Abstract: A convenient method for the synthesis of 1-amino-2,5-di(2-thienyl)benzenes was proposed. The method involves in situ generation of aryne intermediates from 1-halo-2,5-di-(2-thienyl)benzenes in the presence of strong bases followed by reactions of the arynes with polyfunctional primary and secondary amines. The products obtained in 75-85% yields are promising monomers for the preparation of polythiophene anionic sensors. Polymerization of dibrominated 1-piperidino-2,5-di(2-thienyl)benzene gave the corresponding poly[(bithiophenediyl)(phenylene)]. © 2012 Springer Science+Business Media New York.
Keywords: AMINATION
ARYNE
CROSS-COUPLING
POLY[(BITHIOPHENEDIYL)(PHENYLENE)]
URI: http://hdl.handle.net/10995/51453
https://elar.urfu.ru/handle/10995/51453
Access: info:eu-repo/semantics/restrictedAccess
SCOPUS ID: 84877079147
WOS ID: 000312068000011
PURE ID: 1093004
ISSN: 1066-5285
DOI: 10.1007/s11172-012-0042-5
Appears in Collections:Научные публикации, проиндексированные в SCOPUS и WoS CC

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