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|Title:||Palladium(II)-catalyzed oxidative C-H/C-H coupling and eliminative S N H reactions in direct functionalization of imidazole oxides with indoles|
|Authors:||Varaksin, Mikhail V.|
Utepova, Irina A.
Chupakhin, Oleg N.
Charushin, Valery N.
|Citation:||Palladium(II)-catalyzed oxidative C-H/C-H coupling and eliminative S N H reactions in direct functionalization of imidazole oxides with indoles / Mikhail V. Varaksin, Irina A. Utepova, Oleg N. Chupakhin, Valery N. Charushin // Journal of Organic Chemistry. — 2012. — Vol. 77. — № 20. — P. 9087-9093.|
|Abstract:||Two novel synthetic approaches to realize the direct C(sp2)-H bond functionalization in cyclic nitrones are reported. Palladium(II)-catalyzed oxidative C-C coupling of 2,2-dialkyl-4-phenyl-2H-imidazole 1-oxides with indoles was shown to result in the formation of 5-indolyl-3-yl derivatives, while nucleophilic substitution of hydrogen (SNH) at C(5) of the same imidazole system was found to afford the corresponding deoxygenated compounds. © 2012 American Chemical Society.|
|Appears in Collections:||Научные публикации, проиндексированные в SCOPUS и WoS CC|
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