Please use this identifier to cite or link to this item: http://hdl.handle.net/10995/51231
Title: Palladium(II)-catalyzed oxidative C-H/C-H coupling and eliminative S N H reactions in direct functionalization of imidazole oxides with indoles
Authors: Varaksin, Mikhail V.
Utepova, Irina A.
Chupakhin, Oleg N.
Charushin, Valery N.
Issue Date: 2012
Citation: Palladium(II)-catalyzed oxidative C-H/C-H coupling and eliminative S N H reactions in direct functionalization of imidazole oxides with indoles / Mikhail V. Varaksin, Irina A. Utepova, Oleg N. Chupakhin, Valery N. Charushin // Journal of Organic Chemistry. — 2012. — Vol. 77. — № 20. — P. 9087-9093.
Abstract: Two novel synthetic approaches to realize the direct C(sp2)-H bond functionalization in cyclic nitrones are reported. Palladium(II)-catalyzed oxidative C-C coupling of 2,2-dialkyl-4-phenyl-2H-imidazole 1-oxides with indoles was shown to result in the formation of 5-indolyl-3-yl derivatives, while nucleophilic substitution of hydrogen (SNH) at C(5) of the same imidazole system was found to afford the corresponding deoxygenated compounds. © 2012 American Chemical Society.
URI: http://hdl.handle.net/10995/51231
https://elar.urfu.ru/handle/10995/51231
SCOPUS ID: 84867713515
WOS ID: 000309951700025
PURE ID: 1073324
ISSN: 0022-3263
1520-6904
DOI: 10.1021/jo301618b
Appears in Collections:Научные публикации, проиндексированные в SCOPUS и WoS CC

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