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dc.contributor.authorOrdinartsev, D. P.en
dc.contributor.authorPechishcheva, N. V.en
dc.contributor.authorEstemirova, S. Kh.en
dc.contributor.authorKim, A. V.en
dc.contributor.authorSterkhov, E. V.en
dc.contributor.authorPetrova, S. A.en
dc.contributor.authorShilenko, G. A.en
dc.date.accessioned2025-02-25T10:52:11Z-
dc.date.available2025-02-25T10:52:11Z-
dc.date.issued2024-
dc.identifier.citationOrdinartsev, D. P., Pechishcheva, N. V., Estemirova, S., Kim, A. V., Sterkhov, E. V., Petrova, S. A., & Shilenko, G. A. (2024). COMPOSITE SORBENT BASED ON FE3O4 WITH FE(N2H4)XCLY FOR THE REMOVAL OF CHROMIUM(VI) FROM WASTEWATER. Nanosystems: Physics, Chemistry, Mathematics, 15(4), 510-519. https://doi.org/10.17586/2220-8054-2024-15-4-510-519apa_pure
dc.identifier.issn2220-8054-
dc.identifier.otherFinal2
dc.identifier.otherAll Open Access; Gold Open Access3
dc.identifier.otherhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85203514148&doi=10.17586%2f2220-8054-2024-15-4-510-519&partnerID=40&md5=90b81d405bcc70cdfd9135e4a89379141
dc.identifier.otherhttps://nanojournal.ifmo.ru/en/wp-content/uploads/2024/08/NPCM154P510-519.pdfpdf
dc.identifier.urihttp://elar.urfu.ru/handle/10995/141690-
dc.description.abstractThe paper presents a methodology for the synthesis of iron complex with hydrazine hydrate Fe(N2H4)xCly. The Fe(N2H4)xCly complex was investigated by X-ray phase analysis and scanning electron microscopy. Upon hydrolysis, the Fe(N2H4)xCly complex forms a composite sorbent, which is Fe3O4 in a shell of Fe(N2H4)xCly complex. The composite sorbent can be used to treat wastewater from Cr(VI) ions and is effective in the pH range of 2 to 12. Based on the adsorption and electrokinetic potential data, a conclusion about the nature of the terminal groups of the adsorbent was made, a scheme of the structure of its electrical double layer and the adsorption mechanism were proposed. Depending on the conditions, Cr(VI) can be adsorbed on the composite sorbent or reduced to Cr(III). The efficiency of the composite sorbent in the removal of Cr(VI) ions was tested on a sample of real wastewater. © Ordinartsev D.P., Pechishcheva N.V., Estemirova S.Kh., Kim A.V., Sterkhov E.V., Petrova S.A., Shilenko G.A., 2024.en
dc.description.sponsorshipMinistry of Education and Science of the Russian Federation, Minobrnauka, (122080100074-1)en
dc.description.sponsorshipABSTRACT The paper presents a methodology for the synthesis of iron complex with hydrazine hydrate Fe(N2H4)xCly. The Fe(N2H4)xCly complex was investigated by X-ray phase analysis and scanning electron microscopy. Upon hydrolysis, the Fe(N2H4)xCly complex forms a composite sorbent, which is Fe3O4 in a shell of Fe(N2H4)xCly complex. The composite sorbent can be used to treat wastewater from Cr(VI) ions and is effective in the pH range of 2 to 12. Based on the adsorption and electrokinetic potential data, a conclusion about the nature of the terminal groups of the adsorbent was made, a scheme of the structure of its electrical double layer and the adsorption mechanism were proposed. Depending on the conditions, Cr(VI) can be adsorbed on the composite sorbent or reduced to Cr(III). The efficiency of the composite sorbent in the removal of Cr(VI) ions was tested on a sample of real wastewater. KEYWORDS Iron complex with hydrazine, magnetite sol, chromium adsorption, heavy metals, adsorption isotherms. ACKNOWLEDGEMENTS The work was carried out according to the state assignment of IMET UB RAS using equipment of Collaborative usage centre \u201CUral-M\u201D and with the support of the Ministry of Science and Higher Education of the Russian Federation (Ural Federal University Program of Development within the Priority-2030 Program), project No. 122080100074-1. FOR CITATION Ordinartsev D.P., Pechishcheva N.V., Estemirova S.Kh., Kim A.V., Sterkhov E.V., Petrova S.A., Shilenko G.A. Composite sorbent based on Fe3O4 with Fe(N2H4)xCly for the removal of Chromium(VI) from wastewater. Nanosystems: Phys. Chem. Math., 2024, 15 (4), 510\u2013519.en
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.publisherITMO Universityen
dc.rightsinfo:eu-repo/semantics/openAccessen
dc.sourceNanosystems: Physics, Chemistry, Mathematics2
dc.sourceNanosystems: Physics, Chemistry, Mathematicsen
dc.subjectADSORPTION ISOTHERMSen
dc.subjectCHROMIUM ADSORPTIONen
dc.subjectHEAVY METALSen
dc.subjectIRON COMPLEX WITH HYDRAZINEen
dc.subjectMAGNETITE SOLen
dc.titleComposite sorbent based on Fe3O4 with Fe(N2H4)xCly for the removal of Chromium(VI) from wastewateren
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.identifier.rsi69035661-
dc.identifier.doi10.17586/2220-8054-2024-15-4-510-519-
dc.identifier.scopus85203514148-
local.contributor.employeeOrdinartsev D.P., Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences, Yekaterinburg, Russian Federationen
local.contributor.employeePechishcheva N.V., Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences, Yekaterinburg, Russian Federation, Ural Federal University named after the First President of Russia B. N. Yeltsin, Yekaterinburg, Russian Federationen
local.contributor.employeeEstemirova S.Kh., Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences, Yekaterinburg, Russian Federationen
local.contributor.employeeKim A.V., Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences, Yekaterinburg, Russian Federation, Ural Federal University named after the First President of Russia B. N. Yeltsin, Yekaterinburg, Russian Federationen
local.contributor.employeeSterkhov E.V., Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences, Yekaterinburg, Russian Federationen
local.contributor.employeePetrova S.A., Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences, Yekaterinburg, Russian Federationen
local.contributor.employeeShilenko G.A., Ural Federal University named after the First President of Russia B. N. Yeltsin, Yekaterinburg, Russian Federationen
local.description.firstpage510
local.description.lastpage519
local.issue4-
local.volume15-
dc.identifier.wos001306013200009-
local.contributor.departmentInstitute of Metallurgy of the Ural Branch of the Russian Academy of Sciences, Yekaterinburg, Russian Federationen
local.contributor.departmentUral Federal University named after the First President of Russia B. N. Yeltsin, Yekaterinburg, Russian Federationen
local.identifier.pure62798595-
local.identifier.eid2-s2.0-85203514148-
local.fund.rsfMinistry of Education and Science of the Russian Federation, Minobrnauka, (122080100074-1)
local.fund.rsfABSTRACT The paper presents a methodology for the synthesis of iron complex with hydrazine hydrate Fe(N2H4)xCly. The Fe(N2H4)xCly complex was investigated by X-ray phase analysis and scanning electron microscopy. Upon hydrolysis, the Fe(N2H4)xCly complex forms a composite sorbent, which is Fe3O4 in a shell of Fe(N2H4)xCly complex. The composite sorbent can be used to treat wastewater from Cr(VI) ions and is effective in the pH range of 2 to 12. Based on the adsorption and electrokinetic potential data, a conclusion about the nature of the terminal groups of the adsorbent was made, a scheme of the structure of its electrical double layer and the adsorption mechanism were proposed. Depending on the conditions, Cr(VI) can be adsorbed on the composite sorbent or reduced to Cr(III). The efficiency of the composite sorbent in the removal of Cr(VI) ions was tested on a sample of real wastewater. KEYWORDS Iron complex with hydrazine, magnetite sol, chromium adsorption, heavy metals, adsorption isotherms. ACKNOWLEDGEMENTS The work was carried out according to the state assignment of IMET UB RAS using equipment of Collaborative usage centre \u201CUral-M\u201D and with the support of the Ministry of Science and Higher Education of the Russian Federation (Ural Federal University Program of Development within the Priority-2030 Program), project No. 122080100074-1. FOR CITATION Ordinartsev D.P., Pechishcheva N.V., Estemirova S.Kh., Kim A.V., Sterkhov E.V., Petrova S.A., Shilenko G.A. Composite sorbent based on Fe3O4 with Fe(N2H4)xCly for the removal of Chromium(VI) from wastewater. Nanosystems: Phys. Chem. Math., 2024, 15 (4), 510\u2013519.
local.identifier.wosWOS:001306013200009-
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