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http://elar.urfu.ru/handle/10995/141568
Title: | Formation of yttrium oxalate phase filled by carbon clusters on the surface of yttrium oxide films |
Authors: | Boukhvalov, D. W. Zatsepin, D. A. Biryukov, D. Y. Shchapova, Y. V. Gavrilov, N. V. Zatsepin, A. F. |
Issue Date: | 2024 |
Publisher: | Elsevier Ltd |
Citation: | Boukhvalov, D., Zatsepin, D., Biryukov, D., Shchapova, Y., Gavrilov, N., & Zatsepin, A. (2024). Formation of yttrium oxalate phase filled by carbon clusters on the surface of yttrium oxide films. Materials Chemistry and Physics, 315, [128936]. https://doi.org/10.1016/j.matchemphys.2024.128936 |
Abstract: | In the current paper, we report the results of surface modification of cubic Y2O3 films employing carbon-ion implantation. The characterization results demonstrate the formation of a stable yttrium oxalate-based structure with cavities filled with carbon clusters. Theoretical simulations demonstrate that the incorporation of eighteen-atom carbon clusters into the cavities of Y2(C2O4)3 does not lead to valuable changes in the crystal structure of yttrium oxalate. X-ray diffraction and optical measurements demonstrate that the subsurface bulk area of cubic yttrium oxide remains unperturbed. The oxalate “skin” thickness with embedded carbon clusters is estimated to be approximately 10 nm. The prospective employing the method to manage optical properties and increase the biocompatibility of yttria and lanthanide oxides are discussed. © 2024 Elsevier B.V. |
Keywords: | BIOCOMPATIBILITY CARBON FILMS CRYSTAL ATOMIC STRUCTURE OPTICAL DATA PROCESSING OPTICAL PROPERTIES OXALIC ACID OXIDE FILMS 'CURRENT A-STABLE CARBON ION IMPLANTATION CRYSTALS STRUCTURES OPTICAL MEASUREMENT SIMULATION DEMONSTRATE SKIN THICKNESS SURFACE-MODIFICATION THEORETICAL SIMULATION X-RAY DIFFRACTION MEASUREMENTS YTTRIUM OXIDE |
URI: | http://elar.urfu.ru/handle/10995/141568 |
Access: | info:eu-repo/semantics/openAccess |
SCOPUS ID: | 85182735928 |
WOS ID: | 001170500800001 |
PURE ID: | 51601167 |
ISSN: | 0254-0584 |
DOI: | 10.1016/j.matchemphys.2024.128936 |
metadata.dc.description.sponsorship: | Ministry of Education and Science of the Russian Federation, Minobrnauka, (4.38); Ministry of Education and Science of the Russian Federation, Minobrnauka; Ministry of Science and Higher Education of the Russian Federation Funding text 1: The study was supported by the Ministry of Science and Higher Education of the Russian Federation (Ural Federal University Program of Development within the Priority-2030 Program, project 4.38).; Funding text 2: The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Anatoly Zatsepin reports financial support was provided by Ministry of Science and Higher Education of Russian Federation.The study was supported by the Ministry of Science and Higher Education of the Russian Federation (Ural Federal University Program of Development within the Priority-2030 Program, project 4.38). |
RSCF project card: | Ministry of Education and Science of the Russian Federation, Minobrnauka, (4.38); Ministry of Education and Science of the Russian Federation, Minobrnauka; Ministry of Science and Higher Education of the Russian Federation Funding text 1: The study was supported by the Ministry of Science and Higher Education of the Russian Federation (Ural Federal University Program of Development within the Priority-2030 Program, project 4.38).; Funding text 2: The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Anatoly Zatsepin reports financial support was provided by Ministry of Science and Higher Education of Russian Federation.The study was supported by the Ministry of Science and Higher Education of the Russian Federation (Ural Federal University Program of Development within the Priority-2030 Program, project 4.38). |
Appears in Collections: | Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC |
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