Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на этот ресурс:
http://elar.urfu.ru/handle/10995/141502
Название: | Core-shell nanogels: the effects of morphology, electro- and magnetostatic interactions |
Авторы: | Dobroserdova, A. B. Minina, E. S. Sánchez, P. A. Likos, C. N. Kantorovich, S. S. |
Дата публикации: | 2024 |
Издатель: | Royal Society of Chemistry |
Библиографическое описание: | Dobroserdova, A., Minina, E., Sánchez, P., Likos, C., & Kantorovich, S. (2024). Core–shell nanogels: the effects of morphology, electro- and magnetostatic interactions. Soft Matter, 20(39), 7797-7810. https://doi.org/10.1039/D4SM00450G |
Аннотация: | We study the influence of core-shell morphology on the structural characteristics of nanogels. Using computer simulations, we examine three different types of systems, distinguished by their intermonomer interactions: those with excluded volume only; those with charged monomers and excluded volume; and those with excluded volume combined with a certain number of magnetised nanoparticles incorporated within the nanogel. We observe that if the polymers in the shell are short and dense, they tend to penetrate the core. This effect of backfolding is enhanced in charged nanogels, regardless of whether all monomers are charged, or only the core or shell ones. The presence of an experimentally available amount of magnetic nanoparticles in a gel, on the one hand, does not lead to any significant morphological changes. On the other hand, the morphology of the nanogel with magnetic particles has an impact on its magnetic susceptibility. Particular growth of the magnetic response is observed if a long shell of a nanogel is functionalised. © 2024 The Royal Society of Chemistry. |
Ключевые слова: | MAGNETIC SUSCEPTIBILITY MAGNETOSTATICS MONOMERS MORPHOLOGY NANOMAGNETICS NANOSTRUCTURED MATERIALS SHELLS (STRUCTURES) MAGNETIC NANOPARTICLE MONOMER NANOGEL NANOPARTICLE POLYMER CHARGED MONOMERS CORE SHELL CORE-SHELL MORPHOLOGIES EXCLUDED VOLUME INTERMONOMERS MAGNETIC PARTICLE MAGNETOSTATICS INTERACTIONS MORPHOLOGICAL CHANGES NANOGELS STRUCTURAL CHARACTERISTICS ARTICLE COMPUTER SIMULATION HUMAN MAGNETISM MORPHOLOGY PHARMACEUTICS NANOGELS |
URI: | http://elar.urfu.ru/handle/10995/141502 |
Условия доступа: | info:eu-repo/semantics/openAccess cc-by-nc |
Идентификатор SCOPUS: | 85198999638 |
Идентификатор WOS: | 001269510100001 |
Идентификатор PURE: | 64640340 |
ISSN: | 1744-683X 1744-6848 |
DOI: | 10.1039/d4sm00450g |
Сведения о поддержке: | Ural Federal University cluster; Russian Science Foundation, RSF, (19-72-10033) The research was supported by the Russian Science Foundation (project 19-72-10033). Computer simulations were performed at the Vienna Scientific Cluster and the Ural Federal University cluster. |
Карточка проекта РНФ: | Osterreichischen Akademie der Wissenschaften, OAW; OeAW; UrFU Program of Development M. R. acknowledges funding from the Austrian Academy of Science (OeAW) and the Vienna Doctoral School of Physics (VDS-P). We thank Dr R. Weeber and Dr E. Pyanzina for fruitful discussions. Partial research funding from UrFU Program of Development within the Priority-2030 Program is gratefully acknowledged. |
Располагается в коллекциях: | Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC |
Файлы этого ресурса:
Файл | Описание | Размер | Формат | |
---|---|---|---|---|
2-s2.0-85198999638.pdf | 3,31 MB | Adobe PDF | Просмотреть/Открыть |
Все ресурсы в архиве электронных ресурсов защищены авторским правом, все права сохранены.