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Название: Cu(II) and Zn(II) metal ions’ sorption utilising halloysite nanotubes derivative
Авторы: Abu, El-Soad, A. M.
Kovaleva, E. G.
Galhoum, A. A.
Sayyed, M. I.
Cavallaro, G.
Lazzara, G.
Дата публикации: 2024
Издатель: Taylor and Francis Ltd.
Библиографическое описание: Abu el-Soad, A., Kovaleva, E., Galhoumb, A. A., Sayyed, M., Cavallaro, G., & Lazzara, G. (2024). Cu(II) and Zn(II) metal ions’ sorption utilising halloysite nanotubes derivative. International Journal of Environmental Analytical Chemistry, 104(20), 9474-9491. https://doi.org/10.1080/03067319.2023.2235282
Аннотация: Designing and developing clay-based adsorbents with a strong preference for removing copper and zinc metal ions, reduced cost, eco-friendliness, and good recyclability is a good strategy for water remediation. Herein, halloysite nanotubes (HNT) were activated by (3- chloropropyl) trimethoxy silane (CPTM) as a linker for polyethyleneimine to give HN-PEI. The hybrid organic/inorganic sorbent HN-PEI was analysed by Fourier-transform infrared spectroscopy, CHN/O (elemental analysis), scanning electron microscopy, textural properties (via the Brunauer–Emmett–Teller technique), X-ray diffraction, and thermogravimetry coupled with differential scanning calorimetry. The HN-PEI’s textural properties show a reduced specific surface of 10.92 m2/g and pore size of 18.2 nm compared to its Pristine HNT (65.33 m2/g) and pore size (⁓10.1 nm), respectively with a dominant mesoporous structure. The selectivity and sorption characteristics of the Cu(II) and Zn(II) metal ions were exploited, while HN-PEI exhibited a remarkable improvement in terms of removing these ions from the aqueous media. At pH 4.5, the sorption capacities for Cu(II) were 2.8 mmol g−1 and for Zn(II) were 1.8 mmol g−1, with equilibrium reached within 120 and 150 min, respectively. There was an acceptable fitting of the pseudo-second-order and Langmuir equations, and the experimental data enabled mono-layer chemisorption reactions. The sorption was exothermic and spontaneous. The sorbent HN-PEI shows high durability over multiple cycles, and after 3 cycles, the sorption/desorption efficacy decreased by less than 6% using HCl (1 M) for Cu(II) and H2SO4 (1.5 M) for Zn(II). According to the bi-system solution sorption test, KSC(Cu(II)/Zn(II)) was ⁓2.0. Finally, HN-PEI had excellent selectivity and efficiency for Cu(II), Pb(II), and Zn(II) ions, especially for Cu(II). © 2023 Informa UK Limited, trading as Taylor & Francis Group.
Ключевые слова: ADSORPTION
GRAFTING
HALLOYSITE NANOTUBES
WATER REMEDIATION
CHEMICALS REMOVAL (WATER TREATMENT)
CHLORINE COMPOUNDS
COPPER COMPOUNDS
DIFFERENTIAL SCANNING CALORIMETRY
FOURIER TRANSFORM INFRARED SPECTROSCOPY
KAOLINITE
LEAD COMPOUNDS
NANOTUBES
PORE SIZE
SCANNING ELECTRON MICROSCOPY
SORPTION
THERMOGRAVIMETRIC ANALYSIS
YARN
ZINC COMPOUNDS
COPPER AND ZINC
COPPER METAL
HALLOYSITE NANOTUBES
METAL IONS SORPTION
METALS IONS
RECYCLABILITY
REDUCED COST
TEXTURAL PROPERTIES
WATER REMEDIATION
ZINC METAL
METAL IONS
URI: http://elar.urfu.ru/handle/10995/141463
Условия доступа: info:eu-repo/semantics/openAccess
cc-by
Идентификатор SCOPUS: 85165288167
Идентификатор PURE: 67389549
ISSN: 0306-7319
1029-0397
DOI: 10.1080/03067319.2023.2235282
Сведения о поддержке: Government Council on Grants, Russian Federation; Russian Foundation for Basic Research, РФФИ, (17-03-00641, 18-29- 12129mk); Russian Foundation for Basic Research, РФФИ
Funding text 1: The work was supported by the\u00A0Government of the Russian Federation under RFBR grants Agreement [No 17-03-00641 and 18-29- 12129mk]. The research leading to these results received funding from the Government of the Russian Federation under RFBR grants Agreement No 17-03-00641 and 18-29- 12129mk. The researcher A.M. Abu El-Soad is funded by a scholarship under the Joint (Executive program between the Arab Republic of Egypt and the Russian Federation). This work is derived from the work presented in the doctoral thesis of A.M. Abu El-Soad.; Funding text 2: The research leading to these results received funding from the Government of the Russian Federation under RFBR grants Agreement No 17-03-00641 and 18-29- 12129mk. The researcher A.M. Abu El-Soad is funded by a scholarship under the Joint (Executive program between the Arab Republic of Egypt and the Russian Federation). This work is derived from the work presented in the doctoral thesis of A.M. Abu El-Soad.
Карточка проекта РНФ: Serbian Academy of Sciences and Arts, SASA; Ministry of Science, Technological Development and Innovations of the Republic of Serbia; 22-21-00650)
I. Dolinka was supported by the Personal grant F-121 of the Serbian Academy of Sciences and Arts, and, partially, by the Ministry of Science, Technological Development and Innovations of the Republic of Serbia. S. V. Gusev and M. V. Volkov were supported by the Russian Science Foundation (Grant No. 22-21-00650). The authors thank the anonymous referee for careful reading and Edmond W. H. Lee for valuable remarks.
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