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Поле DC | Значение | Язык |
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dc.contributor.author | Fedin, V. V. | en |
dc.contributor.author | Usachev, S. A. | en |
dc.contributor.author | Obydennov, D. L. | en |
dc.contributor.author | Sosnovskikh, V. Y. | en |
dc.date.accessioned | 2024-04-08T11:06:36Z | - |
dc.date.available | 2024-04-08T11:06:36Z | - |
dc.date.issued | 2022 | - |
dc.identifier.citation | Fedin, VV, Usachev, SA, Obydennov, DL & Sosnovskikh, VY 2022, 'Reactions of Trifluorotriacetic Acid Lactone and Hexafluorodehydroacetic Acid with Amines: Synthesis of Trifluoromethylated 4-Pyridones and Aminoenones', Molecules, Том. 27, № 20, 7098. https://doi.org/10.3390/molecules27207098 | harvard_pure |
dc.identifier.citation | Fedin, V. V., Usachev, S. A., Obydennov, D. L., & Sosnovskikh, V. Y. (2022). Reactions of Trifluorotriacetic Acid Lactone and Hexafluorodehydroacetic Acid with Amines: Synthesis of Trifluoromethylated 4-Pyridones and Aminoenones. Molecules, 27(20), [7098]. https://doi.org/10.3390/molecules27207098 | apa_pure |
dc.identifier.issn | 1420-3049 | - |
dc.identifier.other | Final | 2 |
dc.identifier.other | All Open Access; Gold Open Access; Green Open Access | 3 |
dc.identifier.other | https://www.mdpi.com/1420-3049/27/20/7098/pdf?version=1666692709 | 1 |
dc.identifier.other | https://www.mdpi.com/1420-3049/27/20/7098/pdf?version=1666692709 | |
dc.identifier.uri | http://elar.urfu.ru/handle/10995/131320 | - |
dc.description.abstract | Dehydroacetic acid and triacetic acid lactone are known to be versatile substrates for the synthesis of a variety of azaheterocycles. However, their fluorinated analogs were poorly described in the literature. In the present work, we have investigated reactions of trifluorotriacetic acid lactone and hexafluorodehydroacetic acid with primary amines, phenylenediamine, and phenylhydrazine. While hexafluorodehydroacetic acid reacted the same way as non-fluorinated analog giving 2,6-bis(trifluoromethyl)-4-pyridones, trifluorotriacetic acid lactone had different regioselectivity of nucleophilic attack compared to the parent structure, and corresponding 3-amino-6,6,6-trifluoro-5-oxohex-3-eneamides were formed as the products. In the case of binucleophiles, further cyclization took place, forming corresponding benzodiazepine and pyrazoles. The obtained 2,6-bis(trifluoromethyl)-4-pyridones were able to react with active methylene compounds giving fluorinated merocyanine dyes. © 2022 by the authors. | en |
dc.description.sponsorship | Russian Science Foundation, RSF, (18-13-00186) | en |
dc.description.sponsorship | This research was funded by the Russian Science Foundation, grant number 18-13-00186 (https://rscf.ru/project/18-13-00186/ accessed on 18 October 2022). | en |
dc.format.mimetype | application/pdf | en |
dc.language.iso | en | en |
dc.publisher | MDPI | en |
dc.relation | info:eu-repo/grantAgreement/RSF//18-13-00186 | en |
dc.rights | info:eu-repo/semantics/openAccess | en |
dc.rights | cc-by | other |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | unpaywall |
dc.source | Molecules | 2 |
dc.source | Molecules | en |
dc.subject | 4-HYDROXY-2-PYRONE | en |
dc.subject | 4-PYRIDONE | en |
dc.subject | AMINOENONE | en |
dc.subject | REGIOSELECTIVE REACTIONS | en |
dc.subject | TRIFLUOROMETHYLATED HETEROCYCLES | en |
dc.subject | ACIDS | en |
dc.subject | AMINES | en |
dc.subject | BENZODIAZEPINES | en |
dc.subject | COLORING AGENTS | en |
dc.subject | LACTONES | en |
dc.subject | PHENYLENEDIAMINES | en |
dc.subject | PHENYLHYDRAZINES | en |
dc.subject | PYRAZOLES | en |
dc.subject | PYRIDONES | en |
dc.subject | 4-PYRIDONE | en |
dc.subject | ACID | en |
dc.subject | AMINE | en |
dc.subject | BENZODIAZEPINE DERIVATIVE | en |
dc.subject | COLORING AGENT | en |
dc.subject | DIPYRONE | en |
dc.subject | LACTONE | en |
dc.subject | PHENYLENEDIAMINE DERIVATIVE | en |
dc.subject | PHENYLHYDRAZINE DERIVATIVE | en |
dc.subject | PYRAZOLE DERIVATIVE | en |
dc.title | Reactions of Trifluorotriacetic Acid Lactone and Hexafluorodehydroacetic Acid with Amines: Synthesis of Trifluoromethylated 4-Pyridones and Aminoenones | en |
dc.type | Article | en |
dc.type | info:eu-repo/semantics/article | en |
dc.type | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.3390/molecules27207098 | - |
dc.identifier.scopus | 85140796209 | - |
local.contributor.employee | Fedin V.V., Institute of Natural Sciences and Mathematics, Ural Federal University, 51 Lenina Ave., Ekaterinburg, 620000, Russian Federation | en |
local.contributor.employee | Usachev S.A., Institute of Natural Sciences and Mathematics, Ural Federal University, 51 Lenina Ave., Ekaterinburg, 620000, Russian Federation | en |
local.contributor.employee | Obydennov D.L., Institute of Natural Sciences and Mathematics, Ural Federal University, 51 Lenina Ave., Ekaterinburg, 620000, Russian Federation | en |
local.contributor.employee | Sosnovskikh V.Y., Institute of Natural Sciences and Mathematics, Ural Federal University, 51 Lenina Ave., Ekaterinburg, 620000, Russian Federation | en |
local.issue | 20 | - |
local.volume | 27 | - |
dc.identifier.wos | 000873058000001 | - |
local.contributor.department | Institute of Natural Sciences and Mathematics, Ural Federal University, 51 Lenina Ave., Ekaterinburg, 620000, Russian Federation | en |
local.identifier.pure | 31572232 | - |
local.identifier.pure | f08fa5c3-4b8b-4c71-b4e6-2c0c8e51c848 | uuid |
local.description.order | 7098 | - |
local.identifier.eid | 2-s2.0-85140796209 | - |
local.fund.rsf | 18-13-00186 | - |
local.identifier.wos | WOS:000873058000001 | - |
local.identifier.pmid | 36296691 | - |
Располагается в коллекциях: | Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC |
Файлы этого ресурса:
Файл | Описание | Размер | Формат | |
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2-s2.0-85140796209.pdf | 2,62 MB | Adobe PDF | Просмотреть/Открыть |
Лицензия на ресурс: Лицензия Creative Commons