MnO2-Mediated Oxidative Cyclization of “Formal” Schiff’s Bases: Easy Access to Diverse Naphthofuro-Annulated Triazines

Fatykhov, R. F.; Khalymbadzha, I. A.; Sharapov, A. D.; Potapova, A. P.; Mochulskaya, N. N.; Tsmokalyuk, A. N.; Ivoilova, A. V.; Mozharovskaia, P. N.; Santra, S.; Chupakhin, O. N.

doi:10.3390/molecules27207105

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Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Fatykhov, R. F.	en
dc.contributor.author	Khalymbadzha, I. A.	en
dc.contributor.author	Sharapov, A. D.	en
dc.contributor.author	Potapova, A. P.	en
dc.contributor.author	Mochulskaya, N. N.	en
dc.contributor.author	Tsmokalyuk, A. N.	en
dc.contributor.author	Ivoilova, A. V.	en
dc.contributor.author	Mozharovskaia, P. N.	en
dc.contributor.author	Santra, S.	en
dc.contributor.author	Chupakhin, O. N.	en
dc.date.accessioned	2024-04-08T11:06:36Z	-
dc.date.available	2024-04-08T11:06:36Z	-
dc.date.issued	2022	-
dc.identifier.citation	Fatykhov, RF, Khalymbadzha, IA, Sharapov, AD, Potapova, AP, Mochulskaya, NN, Tsmokalyuk, AN, Ivoilova, AV, Mozharovskaia, PN, Santra, S & Chupakhin, ON 2022, 'MnO2-Mediated Oxidative Cyclization of “Formal” Schiff’s Bases: Easy Access to Diverse Naphthofuro-Annulated Triazines', Molecules, Том. 27, № 20, 7105. https://doi.org/10.3390/molecules27207105	harvard_pure
dc.identifier.citation	Fatykhov, R. F., Khalymbadzha, I. A., Sharapov, A. D., Potapova, A. P., Mochulskaya, N. N., Tsmokalyuk, A. N., Ivoilova, A. V., Mozharovskaia, P. N., Santra, S., & Chupakhin, O. N. (2022). MnO2-Mediated Oxidative Cyclization of “Formal” Schiff’s Bases: Easy Access to Diverse Naphthofuro-Annulated Triazines. Molecules, 27(20), [7105]. https://doi.org/10.3390/molecules27207105	apa_pure
dc.identifier.issn	1420-3049	-
dc.identifier.other	Final	2
dc.identifier.other	All Open Access; Gold Open Access; Green Open Access	3
dc.identifier.other	https://www.mdpi.com/1420-3049/27/20/7105/pdf?version=1666333720	1
dc.identifier.other	https://www.mdpi.com/1420-3049/27/20/7105/pdf?version=1666333720	pdf
dc.identifier.uri	http://elar.urfu.ru/handle/10995/131319	-
dc.description.abstract	A different type of MnO2-induced oxidative cyclization of dihydrotriazines has been developed. These dihydrotriazines are considered as a “formal” Schiff’s base. This method provided easy access to naphthofuro-fused triazine via the C-C/C-O oxidative coupling reaction. The reaction sequence comprised the nucleophilic addition of 2-naphthol or phenol to 1,2,4-triazine, followed by oxidative cyclization. The scope and limitations of this novel coupling reaction have been investigated. Further application of the synthesized compound has been demonstrated by synthesizing carbazole-substituted benzofuro-fused triazines. The scalability of the reaction was demonstrated at a 40 mmol load. The mechanistic study strongly suggests that this reaction proceeds through the formation of an O-coordinated manganese complex. © 2022 by the authors.	en
dc.description.sponsorship	Russian Science Foundation, RSF, (21-13-00304)	en
dc.description.sponsorship	Council on grants of the President of the Russian Federation	en
dc.description.sponsorship	This research was funded by the Russian Scientific Foundation (Grant #21-13-00304, synthesis of compounds 4) and the Council on Grants of the President of the Russian Federation (Ref. #NSh- 1223.2022.1.3, synthesis of the starting compounds 1 and DFT studies).	en
dc.format.mimetype	application/pdf	en
dc.language.iso	en	en
dc.publisher	MDPI	en
dc.relation	info:eu-repo/grantAgreement/RSF//21-13-00304	en
dc.rights	info:eu-repo/semantics/openAccess	en
dc.rights	cc-by	other
dc.rights.uri	https://creativecommons.org/licenses/by/4.0/	unpaywall
dc.source	Molecules	2
dc.source	Molecules	en
dc.subject	1,2,4-TRIAZINE	en
dc.subject	CROSS-COUPLING	en
dc.subject	MANGANESE(IV) OXIDE	en
dc.subject	OXIDATIVE CYCLIZATION	en
dc.subject	PHENOLS	en
dc.title	MnO2-Mediated Oxidative Cyclization of “Formal” Schiff’s Bases: Easy Access to Diverse Naphthofuro-Annulated Triazines	en
dc.type	Article	en
dc.type	info:eu-repo/semantics/article	en
dc.type	info:eu-repo/semantics/publishedVersion	en
dc.identifier.doi	10.3390/molecules27207105	-
dc.identifier.scopus	85140774223	-
local.contributor.employee	Fatykhov R.F., Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University, 19 Mira Str., Ekaterinburg, 620002, Russian Federation	en
local.contributor.employee	Khalymbadzha I.A., Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University, 19 Mira Str., Ekaterinburg, 620002, Russian Federation, Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 S. Kovalevskaya Str, Ekaterinburg, 620990, Russian Federation	en
local.contributor.employee	Sharapov A.D., Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University, 19 Mira Str., Ekaterinburg, 620002, Russian Federation	en
local.contributor.employee	Potapova A.P., Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University, 19 Mira Str., Ekaterinburg, 620002, Russian Federation	en
local.contributor.employee	Mochulskaya N.N., Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University, 19 Mira Str., Ekaterinburg, 620002, Russian Federation	en
local.contributor.employee	Tsmokalyuk A.N., Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University, 19 Mira Str., Ekaterinburg, 620002, Russian Federation	en
local.contributor.employee	Ivoilova A.V., Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University, 19 Mira Str., Ekaterinburg, 620002, Russian Federation	en
local.contributor.employee	Mozharovskaia P.N., Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University, 19 Mira Str., Ekaterinburg, 620002, Russian Federation	en
local.contributor.employee	Santra S., Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University, 19 Mira Str., Ekaterinburg, 620002, Russian Federation	en
local.contributor.employee	Chupakhin O.N., Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University, 19 Mira Str., Ekaterinburg, 620002, Russian Federation, Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 S. Kovalevskaya Str, Ekaterinburg, 620990, Russian Federation	en
local.issue	20	-
local.volume	27	-
dc.identifier.wos	000875267500001	-
local.contributor.department	Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University, 19 Mira Str., Ekaterinburg, 620002, Russian Federation	en
local.contributor.department	Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 S. Kovalevskaya Str, Ekaterinburg, 620990, Russian Federation	en
local.identifier.pure	31572406	-
local.identifier.pure	d2296287-4e6f-4ff0-bd49-0fcfe3cb521b	uuid
local.description.order	7105	-
local.identifier.eid	2-s2.0-85140774223	-
local.fund.rsf	21-13-00304	-
local.identifier.wos	WOS:000875267500001	-
Располагается в коллекциях:	Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC

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