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dc.contributor.authorIvanov, I. L.en
dc.contributor.authorZakiryanov, P. O.en
dc.contributor.authorSereda, V. V.en
dc.contributor.authorMazurin, M. O.en
dc.contributor.authorMalyshkin, D. A.en
dc.contributor.authorZuev, A. Y.en
dc.contributor.authorTsvetkov, D. S.en
dc.date.accessioned2024-04-08T11:06:16Z-
dc.date.available2024-04-08T11:06:16Z-
dc.date.issued2022-
dc.identifier.citationIvanov, IL, Zakiryanov, PO, Sereda, VV, Mazurin, MO, Malyshkin, DA, Zuev, AY & Tsvetkov, DS 2022, 'Nonstoichiometry, Defect Chemistry and Oxygen Transport in Fe-Doped Layered Double Perovskite Cobaltite PrBaCo2−xFexO6−δ (x = 0–0.6) Membrane Materials', Membranes, Том. 12, № 12, 1200. https://doi.org/10.3390/membranes12121200harvard_pure
dc.identifier.citationIvanov, I. L., Zakiryanov, P. O., Sereda, V. V., Mazurin, M. O., Malyshkin, D. A., Zuev, A. Y., & Tsvetkov, D. S. (2022). Nonstoichiometry, Defect Chemistry and Oxygen Transport in Fe-Doped Layered Double Perovskite Cobaltite PrBaCo2−xFexO6−δ (x = 0–0.6) Membrane Materials. Membranes, 12(12), [1200]. https://doi.org/10.3390/membranes12121200apa_pure
dc.identifier.issn2077-0375-
dc.identifier.otherFinal2
dc.identifier.otherAll Open Access; Gold Open Access; Green Open Access3
dc.identifier.otherhttps://www.mdpi.com/2077-0375/12/12/1200/pdf?version=16698848501
dc.identifier.otherhttps://www.mdpi.com/2077-0375/12/12/1200/pdf?version=1669884850pdf
dc.identifier.urihttp://elar.urfu.ru/handle/10995/131301-
dc.description.abstractMixed conducting cobaltites PrBaCo2−xFexO6−δ (x = 0–0.6) with a double perovskite structure are promising materials for ceramic semi-permeable membranes for oxygen separation and purification due to their fast oxygen exchange and diffusion capability. Here, we report the results of the detailed study of an interplay between the defect chemistry, oxygen nonstoichiometry and oxygen transport in these materials as a function of iron doping. We show that doping leads to a systematic variation of both the thermodynamics of defect formation reactions and oxygen transport properties. Thus, iron doping can be used to optimize the performance of mixed conducting oxygen-permeable double perovskite membrane materials. © 2022 by the authors.en
dc.description.sponsorshipRussian Science Foundation, RSF, (22-23-00834)en
dc.description.sponsorshipThis work was supported by the Russian Science Foundation (grant No. 22-23-00834).en
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.publisherMDPIen
dc.relationinfo:eu-repo/grantAgreement/RSF//22-23-00834en
dc.rightsinfo:eu-repo/semantics/openAccessen
dc.rightscc-byother
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/unpaywall
dc.sourceMembranes2
dc.sourceMembranesen
dc.subjectACTIVATION ENERGYen
dc.subjectCHEMICAL DIFFUSIONen
dc.subjectDEFECT CHEMISTRYen
dc.subjectMIXED CONDUCTORen
dc.subjectPOINT DEFECTSen
dc.subjectSELF-DIFFUSIONen
dc.subjectSURFACE EXCHANGEen
dc.subjectCERAMIC MEMBRANESen
dc.subjectDIFFUSIONen
dc.subjectIRONen
dc.subjectOXYGENen
dc.subjectOXYGEN PERMEABLE MEMBRANESen
dc.subjectPEROVSKITEen
dc.subjectPOINT DEFECTSen
dc.subjectCHEMICAL DIFFUSIONen
dc.subjectDEFECT CHEMISTRYen
dc.subjectDOUBLE PEROVSKITESen
dc.subjectIRON DOPINGen
dc.subjectMEMBRANE MATERIALen
dc.subjectMIXED CONDUCTORSen
dc.subjectNON-STOICHIOMETRYen
dc.subjectOXYGEN TRANSPORTen
dc.subjectSELF-DIFFUSIONSen
dc.subjectSURFACE EXCHANGESen
dc.subjectACTIVATION ENERGYen
dc.titleNonstoichiometry, Defect Chemistry and Oxygen Transport in Fe-Doped Layered Double Perovskite Cobaltite PrBaCo2−xFexO6−δ (x = 0–0.6) Membrane Materialsen
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.3390/membranes12121200-
dc.identifier.scopus85144612409-
local.contributor.employeeIvanov I.L., Institute of Natural Sciences and Mathematics, Ural Federal University, 19 Mira St., Ekaterinburg, 620002, Russian Federationen
local.contributor.employeeZakiryanov P.O., Institute of Natural Sciences and Mathematics, Ural Federal University, 19 Mira St., Ekaterinburg, 620002, Russian Federationen
local.contributor.employeeSereda V.V., Institute of Natural Sciences and Mathematics, Ural Federal University, 19 Mira St., Ekaterinburg, 620002, Russian Federationen
local.contributor.employeeMazurin M.O., Institute of Natural Sciences and Mathematics, Ural Federal University, 19 Mira St., Ekaterinburg, 620002, Russian Federationen
local.contributor.employeeMalyshkin D.A., Institute of Natural Sciences and Mathematics, Ural Federal University, 19 Mira St., Ekaterinburg, 620002, Russian Federationen
local.contributor.employeeZuev A.Y., Institute of Natural Sciences and Mathematics, Ural Federal University, 19 Mira St., Ekaterinburg, 620002, Russian Federationen
local.contributor.employeeTsvetkov D.S., Institute of Natural Sciences and Mathematics, Ural Federal University, 19 Mira St., Ekaterinburg, 620002, Russian Federationen
local.issue12-
local.volume12-
dc.identifier.wos000902746000001-
local.contributor.departmentInstitute of Natural Sciences and Mathematics, Ural Federal University, 19 Mira St., Ekaterinburg, 620002, Russian Federationen
local.identifier.pure33228753-
local.identifier.pure15870a93-538c-45b8-8f40-36a685b9a0eauuid
local.description.order1200-
local.identifier.eid2-s2.0-85144612409-
local.fund.rsf22-23-00834-
local.identifier.wosWOS:000902746000001-
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