1. Электронный научный архив УрФУ
  2. 00. Общеуниверситетские коллекции
  3. Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC
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dc.contributor.authorSmirnova, K. A.en
dc.contributor.authorEdilova, Y. O.en
dc.contributor.authorKiskin, M. A.en
dc.contributor.authorBogomyakov, A. S.en
dc.contributor.authorKudyakova, Y. S.en
dc.contributor.authorValova, M. S.en
dc.contributor.authorRomanenko, G. V.en
dc.contributor.authorSlepukhin, P. A.en
dc.contributor.authorSaloutin, V. I.en
dc.contributor.authorBazhin, D. N.en
dc.date.accessioned2024-04-05T16:25:50Z-
dc.date.available2024-04-05T16:25:50Z-
dc.date.issued2023-
dc.identifier.citationSmirnova, KA, Edilova , YO, Kiskin, MA, Bogomyakov, AS, Kudyakova, YS, Valova , MS, Romanenko, GV, Slepukhin, PA, Saloutin, VI & Bazhin, DN 2023, 'Perfluoroalkyl Chain Length Effect on Crystal Packing and [LnO8] Coordination Geometry in Lanthanide-Lithium β-Diketonates: Luminescence and Single-Ion Magnet Behavior', International Journal of Molecular Sciences, Том. 24, № 11, 9778. https://doi.org/10.3390/ijms24119778harvard_pure
dc.identifier.citationSmirnova, K. A., Edilova , Y. O., Kiskin, M. A., Bogomyakov, A. S., Kudyakova, Y. S., Valova , M. S., Romanenko, G. V., Slepukhin, P. A., Saloutin, V. I., & Bazhin, D. N. (2023). Perfluoroalkyl Chain Length Effect on Crystal Packing and [LnO8] Coordination Geometry in Lanthanide-Lithium β-Diketonates: Luminescence and Single-Ion Magnet Behavior. International Journal of Molecular Sciences, 24(11), [9778]. https://doi.org/10.3390/ijms24119778apa_pure
dc.identifier.issn1661-6596-
dc.identifier.otherFinal2
dc.identifier.otherAll Open Access, Gold, Green3
dc.identifier.otherhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85161879357&doi=10.3390%2fijms24119778&partnerID=40&md5=23c41e58dd96a458f090a3fb54416f711
dc.identifier.otherhttps://www.mdpi.com/1422-0067/24/11/9778/pdf?version=1686045544pdf
dc.identifier.urihttp://elar.urfu.ru/handle/10995/130558-
dc.description.abstractFunctionalized perfluoroalkyl lithium β-diketonates (LiL) react with lanthanide(III) salts (Ln = Eu, Gd, Tb, Dy) in methanol to give heterobimetallic Ln-Li complexes of general formula [(LnL3)(LiL)(MeOH)]. The length of fluoroalkyl substituent in ligand was found to affect the crystal packing of complexes. Photoluminescent and magnetic properties of heterobimetallic β-diketonates in the solid state are reported. The effect of the geometry of the [LnO8] coordination environment of heterometallic β-diketonates on the luminescent properties (quantum yields, phosphorescence lifetimes for Eu, Tb, Dy complexes) and single-ion magnet behavior (Ueff for Dy complexes) is revealed. © 2023 by the authors.en
dc.description.sponsorshipRussian Academy of Sciences, РАН: AAAA-A19-119011790132-7en
dc.description.sponsorshipThis work carried out in the framework of the basic theme of the Russian Academy of Sciences (state registration № AAAA-A19-119011790132-7).en
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.publisherMultidisciplinary Digital Publishing Institute (MDPI)en
dc.rightsinfo:eu-repo/semantics/openAccessen
dc.rightscc-byother
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/unpaywall
dc.sourceInternational Journal of Molecular Sciences2
dc.sourceInternational Journal of Molecular Sciencesen
dc.subjectCRYSTAL PACKINGen
dc.subjectLANTHANIDEen
dc.subjectLUMINESCENCEen
dc.subjectSINGLE-ION MAGNETen
dc.subjectΒ-DIKETONATESen
dc.subjectKETONE DERIVATIVEen
dc.subjectLANTHANIDEen
dc.subjectLITHIUMen
dc.subjectFLUOROCARBONen
dc.subjectLITHIUMen
dc.subjectARTICLEen
dc.subjectCONTROLLED STUDYen
dc.subjectCRYSTALen
dc.subjectGEOMETRYen
dc.subjectLUMINESCENCEen
dc.subjectPHOSPHORESCENCEen
dc.subjectQUANTUM CHEMISTRYen
dc.subjectCHEMISTRYen
dc.subjectLUMINESCENCEen
dc.subjectFLUOROCARBONSen
dc.subjectLANTHANOID SERIES ELEMENTSen
dc.subjectLITHIUMen
dc.subjectLUMINESCENCEen
dc.subjectMAGNETSen
dc.titlePerfluoroalkyl Chain Length Effect on Crystal Packing and [LnO8] Coordination Geometry in Lanthanide-Lithium β-Diketonates: Luminescence and Single-Ion Magnet Behavioren
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.type|info:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.3390/ijms24119778-
dc.identifier.scopus85161879357-
local.contributor.employeeSmirnova, K.A., International Tomography Center, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, 630090, Russian Federationen
local.contributor.employeeEdilova, Y.O., Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Yekaterinburg, 620137, Russian Federationen
local.contributor.employeeKiskin, M.A., N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russian Federationen
local.contributor.employeeBogomyakov, A.S., International Tomography Center, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, 630090, Russian Federationen
local.contributor.employeeKudyakova, Y.S., Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Yekaterinburg, 620137, Russian Federationen
local.contributor.employeeValova, M.S., Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Yekaterinburg, 620137, Russian Federationen
local.contributor.employeeRomanenko, G.V., International Tomography Center, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, 630090, Russian Federationen
local.contributor.employeeSlepukhin, P.A., Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Yekaterinburg, 620137, Russian Federationen
local.contributor.employeeSaloutin, V.I., Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Yekaterinburg, 620137, Russian Federationen
local.contributor.employeeBazhin, D.N., Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Yekaterinburg, 620137, Russian Federation, Department of Organic and Biomolecular Chemistry, Ural Federal University Named after the First President of Russia B.N. Eltsin, Ekaterinburg, 620002, Russian Federationen
local.issue11-
local.volume24-
dc.identifier.wos001006406500001-
local.contributor.departmentInternational Tomography Center, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, 630090, Russian Federationen
local.contributor.departmentPostovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Yekaterinburg, 620137, Russian Federationen
local.contributor.departmentN.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russian Federationen
local.contributor.departmentDepartment of Organic and Biomolecular Chemistry, Ural Federal University Named after the First President of Russia B.N. Eltsin, Ekaterinburg, 620002, Russian Federationen
local.identifier.pure40601608-
local.description.order9778-
local.identifier.eid2-s2.0-85161879357-
local.identifier.wosWOS:001006406500001-
local.identifier.pmid37298728-
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