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dc.contributor.authorVolkovich, V. A.en
dc.contributor.authorRyzhov, A. A.en
dc.contributor.authorIvanov, A. B.en
dc.contributor.authorShchetinskiy, A. V.en
dc.contributor.authorMaltsev, D. S.en
dc.date.accessioned2022-10-19T05:24:24Z-
dc.date.available2022-10-19T05:24:24Z-
dc.date.issued2021-
dc.identifier.citationReaction of Oxygen with Solutions of Neodymium Chloride in Alkali Chloride Melts: A Spectroscopy and Kinetics Study / V. A. Volkovich, A. A. Ryzhov, A. B. Ivanov et al. // Journal of the Electrochemical Society. — 2021. — Vol. 168. — Iss. 4. — 46513.en
dc.identifier.issn134651-
dc.identifier.otherhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85105763312&doi=10.1149%2f1945-7111%2fabf5a5&partnerID=40&md5=83be21b9a3c10cd5fd2a6fd20fcfaae7link
dc.identifier.urihttp://elar.urfu.ru/handle/10995/118313-
dc.description.abstractReaction of oxygen with solutions of neodymium chloride in LiCl and 3LiCl-2KCl melts was studied at 450 C-750 C. The reaction resulted in the formation of neodymium oxychloride and the effect of temperature, amount of oxygen passed through the melt (oxygen-to-neodymium molar ratio), gas phase composition (O2, O2-H2O, Ar-O2, Ar-O2-H2O) on the course of the reaction were considered. Size of particles comprising solid precipitates formed in the melt was determined. High temperature electronic absorption spectroscopy was used to determine kinetic parameters of the reaction (reaction rates, rate constants, temperature coefficients). The activation energy of the reaction was evaluated. © 2021 The Author(s). Published on behalf of The Electrochemical Society by IOP Publishing Limited.en
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.publisherIOP Publishing Ltden
dc.rightsinfo:eu-repo/semantics/openAccessen
dc.sourceJournal of the Electrochemical Societyen
dc.subjectABSORPTION SPECTROSCOPYen
dc.subjectACTIVATION ENERGYen
dc.subjectCHEMICAL ANALYSISen
dc.subjectCHLORINE COMPOUNDSen
dc.subjectLITHIUM COMPOUNDSen
dc.subjectMOLAR RATIOen
dc.subjectNEODYMIUM COMPOUNDSen
dc.subjectRATE CONSTANTSen
dc.subjectALKALI CHLORIDE MELTSen
dc.subjectEFFECT OF TEMPERATUREen
dc.subjectGAS PHASE COMPOSITIONen
dc.subjectHIGH-TEMPERATURE ELECTRONICSen
dc.subjectKINETICS STUDIESen
dc.subjectOXYCHLORIDESen
dc.subjectTEMPERATURE COEFFICIENTen
dc.subjectPOTASSIUM COMPOUNDSen
dc.titleReaction of Oxygen with Solutions of Neodymium Chloride in Alkali Chloride Melts: A Spectroscopy and Kinetics Studyen
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.identifier.rsi46069523-
dc.identifier.doi10.1149/1945-7111/abf5a5-
dc.identifier.scopus85105763312-
local.contributor.employeeVolkovich, V.A., Department of Rare Metals and Nanomaterials, Institute of Physics and Technology, Ural Federal University, Ekaterinburg, 620002, Russian Federationen
local.contributor.employeeRyzhov, A.A., Department of Physical and Chemical Methods of Analysis, Institute of Physics and Technology, Ural Federal University, Ekaterinburg, 620002, Russian Federationen
local.contributor.employeeIvanov, A.B., Department of Rare Metals and Nanomaterials, Institute of Physics and Technology, Ural Federal University, Ekaterinburg, 620002, Russian Federationen
local.contributor.employeeShchetinskiy, A.V., Department of Rare Metals and Nanomaterials, Institute of Physics and Technology, Ural Federal University, Ekaterinburg, 620002, Russian Federationen
local.contributor.employeeMaltsev, D.S., Department of Rare Metals and Nanomaterials, Institute of Physics and Technology, Ural Federal University, Ekaterinburg, 620002, Russian Federation, Department of Chemistry, University of Tennessee, Knoxville, TN 37996, United Statesen
local.issue4-
local.volume168-
dc.identifier.wos000642177500001-
local.contributor.departmentDepartment of Rare Metals and Nanomaterials, Institute of Physics and Technology, Ural Federal University, Ekaterinburg, 620002, Russian Federationen
local.contributor.departmentDepartment of Physical and Chemical Methods of Analysis, Institute of Physics and Technology, Ural Federal University, Ekaterinburg, 620002, Russian Federationen
local.contributor.departmentDepartment of Chemistry, University of Tennessee, Knoxville, TN 37996, United Statesen
local.identifier.pure21871244-
local.description.order46513-
local.identifier.eid2-s2.0-85105763312-
local.identifier.wosWOS:000642177500001-
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