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dc.contributor.authorBoukhvalov, D. W.en
dc.contributor.authorCheng, J.en
dc.contributor.authorD'Olimpio, G.en
dc.contributor.authorBocquet, F. C.en
dc.contributor.authorKuo, C. -N.en
dc.contributor.authorSarkar, A. B.en
dc.contributor.authorGhosh, B.en
dc.contributor.authorVobornik, I.en
dc.contributor.authorFujii, J.en
dc.contributor.authorHsu, K.en
dc.contributor.authorWang, L. -M.en
dc.contributor.authorAzulay, O.en
dc.contributor.authorDaptary, G. N.en
dc.contributor.authorNaveh, D.en
dc.contributor.authorLue, C. S.en
dc.contributor.authorVorokhta, M.en
dc.contributor.authorAgarwal, A.en
dc.contributor.authorZhang, L.en
dc.contributor.authorPolitano, A.en
dc.date.accessioned2022-10-19T05:22:34Z-
dc.date.available2022-10-19T05:22:34Z-
dc.date.issued2021-
dc.identifier.citationUnveiling the Mechanisms Ruling the Efficient Hydrogen Evolution Reaction with Mitrofanovite Pt3Te4 / D. W. Boukhvalov, J. Cheng, G. D'Olimpio et al. // Journal of Physical Chemistry Letters. — 2021. — P. 8627-8636.en
dc.identifier.issn19487185-
dc.identifier.otherhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85115169066&doi=10.1021%2facs.jpclett.1c01261&partnerID=40&md5=c037dad1d95ddc03905ebd1a3a934b45link
dc.identifier.urihttp://elar.urfu.ru/handle/10995/118125-
dc.description.abstractBy means of electrocatalytic tests, surface-science techniques and density functional theory, we unveil the physicochemical mechanisms ruling the electrocatalytic activity of recently discovered mitrofanovite (Pt3Te4) mineral. Mitrofanovite represents a very promising electrocatalyst candidate for energy-related applications, with a reduction of costs by 47% compared to pure Pt and superior robustness to CO poisoning. We show that Pt3Te4 is a weak topological metal with the Z2 invariant, exhibiting electrical conductivity (∼4 × 106 S/m) comparable with pure Pt. In hydrogen evolution reaction (HER), the electrode based on bulk Pt3Te4 shows a very small overpotential of 46 mV at 10 mA cm-2 and a Tafel slope of 36-49 mV dec-1 associated with the Volmer-Heyrovsky mechanism. The outstanding ambient stability of Pt3Te4 also provides durability of the electrode and long-term stability of its efficient catalytic performances. © 2021 American Chemical Society.en
dc.description.sponsorshipDeutsche Forschungsgemeinschaft, DFG: SFB 1083; National Natural Science Foundation of China, NSFC: 21775078, 22075159, tsqn202103058; Ministry of Education and Science of the Russian Federation, Minobrnauka: FEUZ-2020-0060en
dc.description.sponsorshipL.Z. acknowledges funding by the National Natural Science Foundation of China (Nos. 21775078 and 22075159) and Taishan Scholar Program (No. tsqn202103058). F.C.B. acknowledges funding by the DFG through the SFB 1083 Structure and Dynamics of Internal Interfaces (Project A 12). D.W.B. acknowledged support Ministry of Science and Higher Education of the Russian Federation (through the basic part of the government mandate, Project No. FEUZ-2020-0060) and Jiangsu Innovative and Entrepreneurial Talents Project. I.V. and J.F. thank NFFA-Trieste.en
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.publisherAmerican Chemical Societyen
dc.rightsinfo:eu-repo/semantics/openAccessen
dc.sourceJournal of Physical Chemistry Lettersen
dc.subjectDENSITY FUNCTIONAL THEORYen
dc.subjectELECTROCATALYSTSen
dc.subjectELECTRODESen
dc.subjectHYDROGENen
dc.subjectAMBIENT STABILITYen
dc.subjectCATALYTIC PERFORMANCEen
dc.subjectELECTRICAL CONDUCTIVITYen
dc.subjectELECTROCATALYTICen
dc.subjectELECTROCATALYTIC ACTIVITYen
dc.subjectLONG TERM STABILITYen
dc.subjectPHYSICO-CHEMICAL MECHANISMSen
dc.subjectSURFACE SCIENCE TECHNIQUESen
dc.subjectHYDROGEN EVOLUTION REACTIONen
dc.titleUnveiling the Mechanisms Ruling the Efficient Hydrogen Evolution Reaction with Mitrofanovite Pt3Te4en
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.identifier.rsi47093721-
dc.identifier.doi10.1021/acs.jpclett.1c01261-
dc.identifier.scopus85115169066-
local.contributor.employeeBoukhvalov, D.W., College of Science, Institute of Materials Physics and Chemistry, Nanjing Forestry University, Nanjing, 210037, China, Theoretical Physics and Applied Mathematics Department, Ural Federal University, Mira Street 19, Ekaterinburg, 620002, Russian Federationen
local.contributor.employeeCheng, J., College of Chemistry and Chemical Engineering, Qingdao University, Shandong, Qingdao, 266071, Chinaen
local.contributor.employeeD'Olimpio, G., INSTM, Department of Physical and Chemical Sciences, University of l'Aquila, via Vetoio, (AQ), L'Aquila, 67100, Italyen
local.contributor.employeeBocquet, F.C., Peter Grünberg Institut (PGI-3), Forschungszentrum Jülich, Jülich, 52425, Germany, Jülich Aachen Research Alliance (JARA), Fundamentals of Future Information Technology, Jülich, 52425, Germanyen
local.contributor.employeeKuo, C.-N., Department of Physics, National Cheng Kung University, 1 Ta-Hsueh Road, Tainan, 70101, Taiwanen
local.contributor.employeeSarkar, A.B., Department of Physics, Indian Institute of Technology Kanpur, Kanpur, 208016, Indiaen
local.contributor.employeeGhosh, B., Department of Physics, Indian Institute of Technology Kanpur, Kanpur, 208016, Indiaen
local.contributor.employeeVobornik, I., CNR-IOM, TASC Laboratory, Area Science Park-Basovizza, Trieste, 34139, Italyen
local.contributor.employeeFujii, J., CNR-IOM, TASC Laboratory, Area Science Park-Basovizza, Trieste, 34139, Italyen
local.contributor.employeeHsu, K., Department of Physics, Graduate Institute of Applied Physics, National Taiwan University, Taipei, 10617, Taiwanen
local.contributor.employeeWang, L.-M., Department of Physics, Graduate Institute of Applied Physics, National Taiwan University, Taipei, 10617, Taiwanen
local.contributor.employeeAzulay, O., Faculty of Engineering, Institute of Nanotechnology, Bar-Ilan University, Ramat-Gan, 52900, Israelen
local.contributor.employeeDaptary, G.N., Department of Physics, Institure of Nanotechnology, Bar-Ilan University, Ramat-Gan, 52900, Israelen
local.contributor.employeeNaveh, D., Faculty of Engineering, Institute of Nanotechnology, Bar-Ilan University, Ramat-Gan, 52900, Israelen
local.contributor.employeeLue, C.S., Department of Physics, National Cheng Kung University, 1 Ta-Hsueh Road, Tainan, 70101, Taiwanen
local.contributor.employeeVorokhta, M., Charles University, V Holesovickǎch 2, Prague 8, Prague, 18000, Czech Republicen
local.contributor.employeeAgarwal, A., Department of Physics, Indian Institute of Technology Kanpur, Kanpur, 208016, Indiaen
local.contributor.employeeZhang, L., College of Chemistry and Chemical Engineering, Qingdao University, Shandong, Qingdao, 266071, Chinaen
local.contributor.employeePolitano, A., INSTM, Department of Physical and Chemical Sciences, University of l'Aquila, via Vetoio, (AQ), L'Aquila, 67100, Italy, CNR-IMM, Istituto per la Microelettronica e Microsistemi, VIII strada 5, Catania, I-95121, Italyen
local.description.firstpage8627-
local.description.lastpage8636-
dc.identifier.wos000696175700025-
local.contributor.departmentCollege of Science, Institute of Materials Physics and Chemistry, Nanjing Forestry University, Nanjing, 210037, Chinaen
local.contributor.departmentTheoretical Physics and Applied Mathematics Department, Ural Federal University, Mira Street 19, Ekaterinburg, 620002, Russian Federationen
local.contributor.departmentCollege of Chemistry and Chemical Engineering, Qingdao University, Shandong, Qingdao, 266071, Chinaen
local.contributor.departmentINSTM, Department of Physical and Chemical Sciences, University of l'Aquila, via Vetoio, (AQ), L'Aquila, 67100, Italyen
local.contributor.departmentPeter Grünberg Institut (PGI-3), Forschungszentrum Jülich, Jülich, 52425, Germanyen
local.contributor.departmentJülich Aachen Research Alliance (JARA), Fundamentals of Future Information Technology, Jülich, 52425, Germanyen
local.contributor.departmentDepartment of Physics, National Cheng Kung University, 1 Ta-Hsueh Road, Tainan, 70101, Taiwanen
local.contributor.departmentDepartment of Physics, Indian Institute of Technology Kanpur, Kanpur, 208016, Indiaen
local.contributor.departmentCNR-IOM, TASC Laboratory, Area Science Park-Basovizza, Trieste, 34139, Italyen
local.contributor.departmentDepartment of Physics, Graduate Institute of Applied Physics, National Taiwan University, Taipei, 10617, Taiwanen
local.contributor.departmentFaculty of Engineering, Institute of Nanotechnology, Bar-Ilan University, Ramat-Gan, 52900, Israelen
local.contributor.departmentDepartment of Physics, Institure of Nanotechnology, Bar-Ilan University, Ramat-Gan, 52900, Israelen
local.contributor.departmentCharles University, V Holesovickǎch 2, Prague 8, Prague, 18000, Czech Republicen
local.contributor.departmentCNR-IMM, Istituto per la Microelettronica e Microsistemi, VIII strada 5, Catania, I-95121, Italyen
local.identifier.pure23698936-
local.identifier.eid2-s2.0-85115169066-
local.identifier.wosWOS:000696175700025-
local.identifier.pmid34472339-
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