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dc.contributor.authorGolovachev, I. B.en
dc.contributor.authorMychinko, M. Y.en
dc.contributor.authorVolkova, N. E.en
dc.contributor.authorGavrilova, L. Y.en
dc.contributor.authorRaveau, B.en
dc.contributor.authorMaignan, A.en
dc.contributor.authorCherepanov, V. A.en
dc.date.accessioned2022-10-19T05:22:23Z-
dc.date.available2022-10-19T05:22:23Z-
dc.date.issued2021-
dc.identifier.citationEffect of cobalt content on the properties of quintuple perovskites Sm2Ba3Fe5-xCoxO15-δ / I. B. Golovachev, M. Y. Mychinko, N. E. Volkova et al. // Journal of Solid State Chemistry. — 2021. — Vol. 301. — 122324.en
dc.identifier.issn224596-
dc.identifier.otherhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85107835269&doi=10.1016%2fj.jssc.2021.122324&partnerID=40&md5=85c7a2717773e974bc900c4ac62ba19flink
dc.identifier.urihttp://elar.urfu.ru/handle/10995/118116-
dc.description.abstractQuintuple perovskites Sm2Ba3Fe5-xCoxO15-δ (x ​= ​0.5, 1.0 and 1.5) have been prepared by glycerin-nitrate technique in air. The phase purity was confirmed by XRD. Partial substitution of Co for Fe decreases the oxygen content and thus the mean oxidation state of 3d-metals. It also slightly decreases the thermal expansion coefficient of oxides. Positive value of the Seebeck coefficient confirmed p-type conductivity, though the thermopower decreases as the Co content increases. The temperature dependence of electrical conductivity reveals a maximum at 550–750°С. © 2021 Elsevier Inc.en
dc.description.sponsorshipRussian Foundation for Basic Research, РФФИ: 18-33-00822; Ministry of Education and Science of the Russian Federation, Minobrnauka: 075-15-2019-1924en
dc.description.sponsorshipThe work was financially supported in parts from the Ministry of Science and Higher Education of Russian Federation [Agreement No. 075-15-2019-1924 ] and Russian Foundation for Basic Research [project No 18-33-00822 ].en
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.publisherAcademic Press Inc.en
dc.rightsinfo:eu-repo/semantics/openAccessen
dc.sourceJournal of Solid State Chemistryen
dc.subjectELECTRICAL PROPERTIESen
dc.subjectMULTILAYER STRUCTUREen
dc.subjectSEMICONDUCTORSen
dc.subjectTHERMAL PROPERTIESen
dc.subjectBARIUM COMPOUNDSen
dc.subjectIRON COMPOUNDSen
dc.subjectPEROVSKITEen
dc.subjectSAMARIUM COMPOUNDSen
dc.subjectTEMPERATURE DISTRIBUTIONen
dc.subjectTHERMAL EXPANSIONen
dc.subjectCOBALT CONTENTen
dc.subjectELECTRICAL CONDUCTIVITYen
dc.subjectOXIDATION STATEen
dc.subjectP TYPE CONDUCTIVITYen
dc.subjectPARTIAL SUBSTITUTIONen
dc.subjectPOSITIVE VALUEen
dc.subjectTEMPERATURE DEPENDENCEen
dc.subjectTHERMAL EXPANSION COEFFICIENTSen
dc.subjectCOBALTen
dc.titleEffect of cobalt content on the properties of quintuple perovskites Sm2Ba3Fe5-xCoxO15-δen
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.identifier.rsi46812336-
dc.identifier.doi10.1016/j.jssc.2021.122324-
dc.identifier.scopus85107835269-
local.contributor.employeeGolovachev, I.B., Institute of Natural Science and Mathematics, Ural Federal University, Lenin Av., 51, Yekaterinburg, 620000, Russian Federationen
local.contributor.employeeMychinko, M.Y., Electron Microscopy for Materials Science (EMAT), University of Antwerp, Groenenborgerlaan 171, Antwerp, 2020, Belgiumen
local.contributor.employeeVolkova, N.E., Institute of Natural Science and Mathematics, Ural Federal University, Lenin Av., 51, Yekaterinburg, 620000, Russian Federationen
local.contributor.employeeGavrilova, L.Y., Institute of Natural Science and Mathematics, Ural Federal University, Lenin Av., 51, Yekaterinburg, 620000, Russian Federationen
local.contributor.employeeRaveau, B., Laboratoire CRISMAT, UMR 6508 Normandie Université, CNRS, ENSICAEN, UNICAEN, 6 bd du Maréchal Juin, CAEN Cedex 4, 14050, Franceen
local.contributor.employeeMaignan, A., Institute of Natural Science and Mathematics, Ural Federal University, Lenin Av., 51, Yekaterinburg, 620000, Russian Federation, Laboratoire CRISMAT, UMR 6508 Normandie Université, CNRS, ENSICAEN, UNICAEN, 6 bd du Maréchal Juin, CAEN Cedex 4, 14050, Franceen
local.contributor.employeeCherepanov, V.A., Institute of Natural Science and Mathematics, Ural Federal University, Lenin Av., 51, Yekaterinburg, 620000, Russian Federationen
local.volume301-
dc.identifier.wos000684543700028-
local.contributor.departmentInstitute of Natural Science and Mathematics, Ural Federal University, Lenin Av., 51, Yekaterinburg, 620000, Russian Federationen
local.contributor.departmentElectron Microscopy for Materials Science (EMAT), University of Antwerp, Groenenborgerlaan 171, Antwerp, 2020, Belgiumen
local.contributor.departmentLaboratoire CRISMAT, UMR 6508 Normandie Université, CNRS, ENSICAEN, UNICAEN, 6 bd du Maréchal Juin, CAEN Cedex 4, 14050, Franceen
local.identifier.pure22098655-
local.description.order122324-
local.identifier.eid2-s2.0-85107835269-
local.fund.rffi18-33-00822-
local.identifier.wosWOS:000684543700028-
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