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dc.contributor.authorTolkacheva, A. S.en
dc.contributor.authorShkerin, S. N.en
dc.contributor.authorPetrova, S. A.en
dc.contributor.authorFedorova, O. M.en
dc.contributor.authorTitova, S. G.en
dc.contributor.authorLeonidov, I. I.en
dc.date.accessioned2022-07-18T12:59:03Z-
dc.date.available2022-07-18T12:59:03Z-
dc.date.issued2022-07-
dc.identifier.citationIn Situ Synthesis, Structural Chemistry and Vibrational Spectroscopy of Zn-doped Ca5Mg4(VO4)6 / A. S. Tolkacheva, S. N. Shkerin, S. A. Petrova, O. M. Fedorova, S. G. Titova, I. I. Leonidov // Chimica Techno Acta. — 2022. — Vol. 9, No. 2. — № 20229201.en
dc.identifier.issn2411-1414online
dc.identifier.urihttp://elar.urfu.ru/handle/10995/116227-
dc.descriptionWe are grateful to Dr. Olga G. Reznitskikh (ISSC UB RAS), Dr. Elena A. Sherstobitova (IMP UB RAS) and Dr. Nikolai I. Moskalenko (IHTE UB RAS) for technical assistance. The crystallographic and spectroscopic studies were carried out in the Shared Access Centers at IMET UB RAS and IHTE UB RAS, respectively.en
dc.descriptionReceived: 18.08.2021. Revised: 17.03.2022. Accepted: 17.03.2022. Available online: 23.03.2022.en
dc.description.abstractThe phase formation of the solid solution Ca5Mg4–xZnx(VO4)6 (0≤x≤4) was studied in situ using differential scanning calorimetry and hightemperature X-Ray powder diffraction (XRPD). XRPD analysis shows the appearance of unavoidable secondary pyrovanadate phases using conventional synthesis methods. The local structure of the solid solution was verified by vibrational spectroscopy. The analysis of the infrared and Raman spectroscopy data allows establishing the main features between vanadate garnets and their isostructural analogs among natural silicates.en
dc.description.sponsorshipThis study was funded by the Research Programs No. AAAA-A19-119020190042-7 and No. АААА-А19-119020190044-1 (IHTE UB RAS).en
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.publisherУральский федеральный университетru
dc.relation.ispartofChimica Techno Acta. 2022. Vol. 9. № 2en
dc.relation.haspartUral Federal Universityen
dc.subjectCRYSTAL STRUCTUREen
dc.subjectVIBRATIONAL SPECTROSCOPYen
dc.subjectX-RAY DIFFRACTIONen
dc.subjectCERAMICSen
dc.subjectDIFFERENTIAL SCANNING CALORIMETRYen
dc.subjectPYROVANADATEen
dc.subjectGARNETen
dc.titleIn Situ Synthesis, Structural Chemistry and Vibrational Spectroscopy of Zn-doped Ca5Mg4(VO4)6en
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.identifier.rsihttps://www.elibrary.ru/item.asp?id=49170458-
dc.identifier.doi10.15826/chimtech.2022.9.2.01-
local.issue2-
local.volume9-
local.contributorTolkacheva, Anna S.en
local.contributorShkerin, Sergey N.en
local.contributorPetrova, Sofya A.en
local.contributorFedorova, Olga M.en
local.contributorTitova, Svetlana G.en
local.contributorLeonidov, Ivan I.en
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