Elimination of Vacancies in Titanium Monoxide under High Pressure in Combination with High Temperature

Valeeva, A. A.; Rempel, A. A.; Pfitzner, A.

doi:10.1007/s00706-015-1452-5

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Поле DC	Значение	Язык
dc.contributor.author	Valeeva, A. A.	en
dc.contributor.author	Rempel, A. A.	en
dc.contributor.author	Pfitzner, A.	en
dc.date.accessioned	2022-05-12T08:30:44Z	-
dc.date.available	2022-05-12T08:30:44Z	-
dc.date.issued	2015	-
dc.identifier.citation	Valeeva A. A. Elimination of Vacancies in Titanium Monoxide under High Pressure in Combination with High Temperature / A. A. Valeeva, A. A. Rempel, A. Pfitzner // Monatshefte fur Chemie. — 2015. — Vol. 146. — Iss. 8. — P. 1205-1209.	en
dc.identifier.issn	0026-9247	-
dc.identifier.other	All Open Access, Green	3
dc.identifier.uri	http://elar.urfu.ru/handle/10995/112217	-
dc.description.abstract	The material design with controlled structure was performed on titanium monoxide with structural vacancies on both sublattices. The polycrystalline powder of disordered titanium monoxide TiO0.98 with B1 structure was subjected to high pressures up to 60 kbar and high temperatures up to 2273 K. The X-ray powder diffraction of as-prepared and treated powders revealed cubic single-phase crystals. The lattice constant of this phase increased from 417.6(3) to 418.5(3) pm due to decreasing vacancy concentration on the titanium sublattice from 13.3 to 8.5 at.% after a highest pressure-highest temperature treatment for 1 h. Graphical abstract: [Figure not available: see fulltext.] © 2015 Springer-Verlag Wien.	en
dc.description.sponsorship	We are grateful to Dr. M. Andratschke, F. Rau, and U. Schiessl for their help during the experiments. This work was financially supported by the AvH Foundation, RFBR Nos. 14-03-00869 and 15-03-00453.	en
dc.format.mimetype	application/pdf	en
dc.language.iso	en	en
dc.publisher	Springer-Verlag Wien	en1
dc.publisher	Springer Science and Business Media LLC	en
dc.rights	info:eu-repo/semantics/openAccess	en
dc.source	Monatsh. Chem.	2
dc.source	Monatshefte fur Chemie	en
dc.subject	NON-STOICHIOMETRY	en
dc.subject	STRUCTURAL VACANCY	en
dc.subject	VACANCY ELIMINATION	en
dc.subject	XRD	en
dc.title	Elimination of Vacancies in Titanium Monoxide under High Pressure in Combination with High Temperature	en
dc.type	Article	en
dc.type	info:eu-repo/semantics/article	en
dc.type	info:eu-repo/semantics/submittedVersion	en
dc.identifier.doi	10.1007/s00706-015-1452-5	-
dc.identifier.scopus	84927534488	-
local.contributor.employee	Valeeva, A.A., Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, Pervomaiskaya 91, Ekaterinburg, 620990, Russian Federation, Ural Federal University Named after the First President of Russia B.N. Yeltsin, Mira 19, Ekaterinburg, 620002, Russian Federation; Rempel, A.A., Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, Pervomaiskaya 91, Ekaterinburg, 620990, Russian Federation, Ural Federal University Named after the First President of Russia B.N. Yeltsin, Mira 19, Ekaterinburg, 620002, Russian Federation; Pfitzner, A., Institute of Inorganic Chemistry, Regensburg University, Universitätsstr. 31, Regensburg, 93040, Germany	en
local.description.firstpage	1205	-
local.description.lastpage	1209	-
local.issue	8	-
local.volume	146	-
dc.identifier.wos	000358163800002	-
local.contributor.department	Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, Pervomaiskaya 91, Ekaterinburg, 620990, Russian Federation; Ural Federal University Named after the First President of Russia B.N. Yeltsin, Mira 19, Ekaterinburg, 620002, Russian Federation; Institute of Inorganic Chemistry, Regensburg University, Universitätsstr. 31, Regensburg, 93040, Germany	en
local.identifier.pure	431163	-
local.identifier.eid	2-s2.0-84927534488	-
local.fund.rffi	14-03-00869	-
local.fund.rffi	15-03-00453	-
local.identifier.wos	WOS:000358163800002	-
Располагается в коллекциях:	Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC

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