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  3. Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC
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dc.contributor.authorLyapustin, D. N.en
dc.contributor.authorUlomsky, E. N.en
dc.contributor.authorBalyakin, I. A.en
dc.contributor.authorShchepochkin, A. V.en
dc.contributor.authorRusinov, V. L.en
dc.contributor.authorChupakhin, O. N.en
dc.date.accessioned2022-05-12T08:30:43Z-
dc.date.available2022-05-12T08:30:43Z-
dc.date.issued2021-
dc.identifier.citationOxidative Aromatization of 4,7-dihydro-6-nitroazolo[1,5-a] Pyrimidines: Synthetic Possibilities and Limitations, Mechanism of Destruction, and the Theoretical and Experimental Substantiation / D. N. Lyapustin, E. N. Ulomsky, I. A. Balyakin et al. // Molecules. — 2021. — Vol. 26. — Iss. 16. — 4719.en
dc.identifier.issn1420-3049-
dc.identifier.otherAll Open Access, Gold, Green3
dc.identifier.urihttp://elar.urfu.ru/handle/10995/112214-
dc.description.abstractThe reaction tolerance of the multicomponent process between 3-aminoazoles, 1-morpholino2-nitroalkenes, and aldehydes was studied. The main patterns of this reaction have been established. Conditions for the oxidation of 4,7-dihydro-6-nitroazolo[1,5-a]pyrimidines were selected. Previous claims that the 4,7-dihydro-6-nitroazolo[1,5-a]pyrimidines could not be aromatised have now been refuted. Compounds with an electron-donor substituent at position seven undergo decomposition during oxidation. The phenomenon was explained based on experimental data, electro-chemical experiment, and quantum-chemical calculation. The mechanism of oxidative degradation has been proposed. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.en
dc.description.sponsorshipFunding: The synthetic part was supported by the Ministry of Science and Higher Education of the Russian Federation, State Contract no FEUZ-2020-0058 (H687.42B.223/20). The electrochemical research and the quantum chemical calculations was funded by Russian Foundation for Basic Research (RFBR), project number 20-03-00814.en
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.publisherMDPI AGen1
dc.publisherMDPI AGen
dc.rightsinfo:eu-repo/semantics/openAccessen
dc.sourceMolecules2
dc.sourceMoleculesen
dc.subjectAZOLO[1,5-A]PYRIMIDINESen
dc.subjectMULTICOMPONENT REACTIONSen
dc.subjectNITRO COMPOUNDSen
dc.subjectNITRO-SYNTHONSen
dc.subjectOXIDATIONen
dc.subjectOXIDATIVE DESTRUCTIONen
dc.subjectSYNTHESIS OF HETEROCYCLESen
dc.titleOxidative Aromatization of 4,7-dihydro-6-nitroazolo[1,5-a] Pyrimidines: Synthetic Possibilities and Limitations, Mechanism of Destruction, and the Theoretical and Experimental Substantiationen
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.identifier.rsi46985470-
dc.identifier.doi10.3390/molecules26164719-
dc.identifier.scopus85112029923-
local.contributor.employeeLyapustin, D.N., Department of Organic and Biomolecular Chemistry, Ural Federal University, Mira St. 19, Ekaterinburg, 620002, Russian Federation; Ulomsky, E.N., Department of Organic and Biomolecular Chemistry, Ural Federal University, Mira St. 19, Ekaterinburg, 620002, Russian Federation, Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, S. Kovalevskaya Str., Ekaterinburg, 22, 620041, Russian Federation; Balyakin, I.A., NANOTECH Centre, Ural Federal University, Ekaterinburg, 620002, Russian Federation, Institute of Metallurgy, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, 620016, Russian Federation; Shchepochkin, A.V., Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, S. Kovalevskaya Str., Ekaterinburg, 22, 620041, Russian Federation; Rusinov, V.L., Department of Organic and Biomolecular Chemistry, Ural Federal University, Mira St. 19, Ekaterinburg, 620002, Russian Federation, Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, S. Kovalevskaya Str., Ekaterinburg, 22, 620041, Russian Federation; Chupakhin, O.N., Department of Organic and Biomolecular Chemistry, Ural Federal University, Mira St. 19, Ekaterinburg, 620002, Russian Federation, Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, S. Kovalevskaya Str., Ekaterinburg, 22, 620041, Russian Federationen
local.issue16-
local.volume26-
dc.identifier.wos000689880300001-
local.contributor.departmentDepartment of Organic and Biomolecular Chemistry, Ural Federal University, Mira St. 19, Ekaterinburg, 620002, Russian Federation; Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, S. Kovalevskaya Str., Ekaterinburg, 22, 620041, Russian Federation; NANOTECH Centre, Ural Federal University, Ekaterinburg, 620002, Russian Federation; Institute of Metallurgy, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, 620016, Russian Federationen
local.identifier.pure22979922-
local.description.order4719-
local.identifier.eid2-s2.0-85112029923-
local.fund.rffi20-03-00814-
local.identifier.wosWOS:000689880300001-
local.fund.feuzFEUZ-2020-0058-
local.identifier.pmid34443304-
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