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http://elar.urfu.ru/handle/10995/112115
Название: | Mechanochemical Activation Effect on Technogenic Iron Oxide Reduction Kinetics |
Авторы: | Sheshukov, O. Mikheenkov, M. Vedmid, L. Egiazaryan, D. |
Дата публикации: | 2022 |
Издатель: | MDPI MDPI AG |
Библиографическое описание: | Mechanochemical Activation Effect on Technogenic Iron Oxide Reduction Kinetics / O. Sheshukov, M. Mikheenkov, L. Vedmid et al. // Materials. — 2022. — Vol. 15. — Iss. 1. — 320. |
Аннотация: | understanding the reaction kinetics of iron oxide reduction by carbon is a key task of the theory of metallurgical processes. One of the understudied features of the reaction kinetics of iron oxide solid-phase reduction by carbon is the discrepancy between the reacting substances’ small contact area and the process’s high rate. A convincing theoretical and experimental explanation of this effect has not yet been obtained. The data obtained earlier show that an increase in the scale of the briquetting pressure from 0 to 300 MPa increases the degree of its metallization during heating two-fold, and the metallization temperature decreases by more than 40◦C. Therefore, it was assumed that these effects during heating are a consequence of the mechanochemical activation (MCA) of iron oxides in the scale during its pressing. This paper presents the results of experimental studies on the influence of two types of scale MCA (grinding and pressing) on iron oxide reduction. The study of the MCA effect on the reaction kinetics of scale iron oxide reduction by carbon is a promising way to assess the criteria for scale phase composition changes under external factors. The presented results indicate a decrease in the amount of trivalent iron oxide (Fe2O3 ) after the MCA and an increase in the amount of one-and-a-half oxide (Fe3O4 ) and bivalent iron oxide (FeO). The obtained experimental data show that the initial stage of iron oxide reduction, consisting in the transition from higher iron oxides to lower ones, is possible at room temperature without carbon presence. © 2022 by the authors. Licensee MDPI, Basel, Switzerland. |
Ключевые слова: | DEFECTS OF THE CRYSTAL LATTICE DIFFUSION IRON OXIDES KINETICS MECHANOCHEMICAL ACTIVATION RECOVERY SCALE ASSOCIATION REACTIONS CARBON CHEMICAL ACTIVATION CRYSTAL STRUCTURE HEMATITE MAGNETITE METAL RECOVERY METALLIZING REACTION KINETICS ACTIVATION EFFECT DEFECT OF THE CRYSTAL LATTICE IRON OXIDES REDUCTIONS MECHANO-CHEMICAL ACTIVATION METALLISATION METALLURGICAL PROCESS PRESSUNG REDUCTION KINETICS SCALE SOLID PHASIS KINETICS |
URI: | http://elar.urfu.ru/handle/10995/112115 |
Условия доступа: | info:eu-repo/semantics/openAccess |
Идентификатор РИНЦ: | 47552130 |
Идентификатор SCOPUS: | 85122148535 |
Идентификатор WOS: | 000742976300001 |
Идентификатор PURE: | 29214376 |
ISSN: | 1996-1944 |
DOI: | 10.3390/ma15010320 |
Сведения о поддержке: | Funding: This research was funded by RFBR, grant number 18-29-24064\19. |
Располагается в коллекциях: | Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC |
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Файл | Описание | Размер | Формат | |
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2-s2.0-85122148535.pdf | 5,48 MB | Adobe PDF | Просмотреть/Открыть |
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