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dc.contributor.authorPakalniškis, A.en
dc.contributor.authorAlikin, D. O.en
dc.contributor.authorTurygin, A. P.en
dc.contributor.authorZhaludkevich, A. L.en
dc.contributor.authorSilibin, M. V.en
dc.contributor.authorZhaludkevich, D. V.en
dc.contributor.authorNiaura, G.en
dc.contributor.authorZarkov, A.en
dc.contributor.authorSkaudžius, R.en
dc.contributor.authorKarpinsky, D. V.en
dc.contributor.authorKareiva, A.en
dc.date.accessioned2022-05-12T08:28:44Z-
dc.date.available2022-05-12T08:28:44Z-
dc.date.issued2022-
dc.identifier.citationCrystal Structure and Concentration-Driven Phase Transitions in Lu(1−x)ScxFeO3 (0 ≤ x ≤ 1) Prepared by the Sol–Gel Method / A. Pakalniškis, D. O. Alikin, A. P. Turygin et al. // Materials. — 2022. — Vol. 15. — Iss. 3. — 1048.en
dc.identifier.issn1996-1944-
dc.identifier.otherAll Open Access, Gold, Green3
dc.identifier.urihttp://elar.urfu.ru/handle/10995/112110-
dc.description.abstractThe structural state and crystal structure of Lu(1−x)ScxFeO3 (0 ≤ x ≤ 1) compounds prepared by a chemical route based on a modified sol–gel method were investigated using X-ray diffraction, Raman spectroscopy, as well as scanning electron microscopy. It was observed that chemical doping with Sc ions led to a structural phase transition from the orthorhombic structure to the hexagonal structure via a wide two-phase concentration region of 0.1 < x < 0.45. An increase in scandium content above 80 mole% led to the stabilization of the non-perovskite bixbyite phase specific for the compound ScFeO3 . The concentration stability of the different structural phases, as well as grain morphology, were studied depending on the chemical composition and synthesis conditions. Based on the data obtained for the analyzed samples, a composition-dependent phase diagram was constructed. © 2022 by the authors. Licensee MDPI, Basel, Switzerland.en
dc.description.sponsorshipFunding: This project received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No 778070—TransFerr— H2020-MSCA-RISE-2017. G.N. gratefully acknowledges the Center of Spectroscopic Characterization of Materials and Electronic/Molecular Processes (SPECTROVERSUM Infrastructure) for use of Raman spectrometer. A.L.Z. and A.P.T. acknowledge BRFFR (project № T21RM-040) and RFBR (project № 20-52-04011) respectively. M.V.S. acknowledges Ministry of Science and Higher Education of the Russian Federation within the framework of state support for the creation and development of World-Class Research Centers “Digital biodesign and personalized healthcare” № 075-15-2020-926. D.A. acknowledges the project CICECO-Aveiro Institute of Materials, UIDB/50011/2020 & UIDP/50011/2020, financed by national funds through the FCT/MEC and when appropriate co-financed by FEDER under the PT2020 Partnership Agreement.en
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.publisherMDPIen1
dc.publisherMDPI AGen
dc.rightsinfo:eu-repo/semantics/openAccessen
dc.sourceMater.2
dc.sourceMaterialsen
dc.subjectLUFEO3en
dc.subjectPHASE TRANSITIONSen
dc.subjectSOLID SOLUTIONSen
dc.subjectSTRUCTURAL PHASE STABILITYen
dc.subjectX-RAY DIFFRACTIONen
dc.subjectCHEMICAL STABILITYen
dc.subjectCRYSTAL STRUCTUREen
dc.subjectIRON COMPOUNDSen
dc.subjectLUTETIUM COMPOUNDSen
dc.subjectPEROVSKITEen
dc.subjectPHASE DIAGRAMSen
dc.subjectSCANNING ELECTRON MICROSCOPYen
dc.subjectSOLSen
dc.subjectCHEMICAL DOPINGen
dc.subjectCHEMICAL ROUTESen
dc.subjectCRYSTALS STRUCTURESen
dc.subjectMODIFIED SOL-GEL METHODen
dc.subjectORTHORHOMBIC STRUCTURESen
dc.subjectSOL- GEL METHODSen
dc.subjectSTRUCTURAL PHASE STABILITYen
dc.subjectSTRUCTURAL PHASE TRANSITIONen
dc.subjectSTRUCTURAL STATEen
dc.subjectX- RAY DIFFRACTIONSen
dc.subjectX RAY DIFFRACTIONen
dc.titleCrystal Structure and Concentration-Driven Phase Transitions in Lu(1−x)ScxFeO3 (0 ≤ x ≤ 1) Prepared by the Sol–Gel Methoden
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.3390/ma15031048-
dc.identifier.scopus85123626086-
local.contributor.employeePakalniškis, A., Institute of Chemistry, Vilnius University, Naugarduko 24, Vilnius, LT-03225, Lithuania; Alikin, D.O., School of Natural Sciences and Mathematics, Ural Federal University, Ekaterinburg, 620000, Russian Federation, Department of Physics & CICECO—Aveiro Institute of Materials, University of Aveiro, Aveiro, 3810-193, Portugal; Turygin, A.P., School of Natural Sciences and Mathematics, Ural Federal University, Ekaterinburg, 620000, Russian Federation; Zhaludkevich, A.L., Scientific-Practical Materials Research Centre of NAS of Belarus, Minsk, 220072, Belarus; Silibin, M.V., Institute of Advanced Materials and Technologies, National Research University of Electronic Technology “MIET”, Moscow, 124498, Russian Federation, Institute for Bionic Technologies and Engineering, I.M. Sechenov First Moscow State Medical University, Moscow, 119991, Russian Federation; Zhaludkevich, D.V., Scientific-Practical Materials Research Centre of NAS of Belarus, Minsk, 220072, Belarus; Niaura, G., Department of Organic Chemistry, Center for Physical Sciences and Technology (FTMC), Sauletekio Ave. 3, Vilnius, LT-10257, Lithuania; Zarkov, A., Institute of Chemistry, Vilnius University, Naugarduko 24, Vilnius, LT-03225, Lithuania; Skaudžius, R., Institute of Chemistry, Vilnius University, Naugarduko 24, Vilnius, LT-03225, Lithuania; Karpinsky, D.V., Scientific-Practical Materials Research Centre of NAS of Belarus, Minsk, 220072, Belarus, Department of Materials Science and Physical Chemistry of Materials, South Ural State University, Av. Lenina, 76, Chelyabinsk, 454080, Russian Federation; Kareiva, A., Institute of Chemistry, Vilnius University, Naugarduko 24, Vilnius, LT-03225, Lithuaniaen
local.issue3-
local.volume15-
dc.identifier.wos000754807300001-
local.contributor.departmentInstitute of Chemistry, Vilnius University, Naugarduko 24, Vilnius, LT-03225, Lithuania; School of Natural Sciences and Mathematics, Ural Federal University, Ekaterinburg, 620000, Russian Federation; Department of Physics & CICECO—Aveiro Institute of Materials, University of Aveiro, Aveiro, 3810-193, Portugal; Scientific-Practical Materials Research Centre of NAS of Belarus, Minsk, 220072, Belarus; Institute of Advanced Materials and Technologies, National Research University of Electronic Technology “MIET”, Moscow, 124498, Russian Federation; Institute for Bionic Technologies and Engineering, I.M. Sechenov First Moscow State Medical University, Moscow, 119991, Russian Federation; Department of Organic Chemistry, Center for Physical Sciences and Technology (FTMC), Sauletekio Ave. 3, Vilnius, LT-10257, Lithuania; Department of Materials Science and Physical Chemistry of Materials, South Ural State University, Av. Lenina, 76, Chelyabinsk, 454080, Russian Federationen
local.identifier.pure29559060-
local.description.order1048-
local.identifier.eid2-s2.0-85123626086-
local.fund.cordisH2020: 778070-
local.fund.rffi20-52-04011-
local.identifier.wosWOS:000754807300001-
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