Синтез, строение и свойства кислородно-ионных проводников на основе низкосимметричных молибдатов висмута Bi13-xAxMo5-yByO34±δ (A - Mn, Ba; B - V, W)

Abstract

Substitution in Bi13Mo5O34± δ is possible in the position of molybdenum and isolated bismuth atoms. The formulas of substitutional solid solutions look like 13 5 34 Bi A Mo B O x x y y The paper discusses the research of the availability and property measurement of oxygenic ionic conductors based on bismuth molibdates with a double substitution (A: Ba, Mn and B: V, W). The samples have been synthesized with the use of standard ceramic technologies. ThephasecompositionhasbeenmonitoredbyXRD.