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dc.contributor.authorNikonov, I. L.en
dc.contributor.authorSadieva, L. K.en
dc.contributor.authorSavchuk, M. I.en
dc.contributor.authorStarnovskaya, E. S.en
dc.contributor.authorKopchuk, D. S.en
dc.contributor.authorKovalev, I. S.en
dc.contributor.authorKim, G. A.en
dc.contributor.authorChupakhin, O. N.en
dc.date.accessioned2022-01-18T07:08:15Z-
dc.date.available2022-01-18T07:08:15Z-
dc.date.issued2021-12-
dc.identifier.citationNew naphtho[1,8-ef]perimidines: synthesis, fluorescence studies and application for detection of nitroanalytes / I. L. Nikonov, L. K. Sadieva, M. I. Savchuk, E. S. Starnovskaya, D. S. Kopchuk, I. S. Kovalev, G. A. Kim, O. N. Chupakhin // Chimica Techno Acta. — 2021. — Vol. 8, No. 4. — № 20218416.en
dc.identifier.issn2411-1414online
dc.identifier.urihttp://elar.urfu.ru/handle/10995/107400-
dc.descriptionReceived: 15.12.2021. Revised: 20.12.2021. Accepted: 20.12.2021. Available online: 24.12.2021.en
dc.description.abstractA rational approach to the synthesis of substituted naphtho[1,8-ef]perimidines based on SN H methodology and cyclization reaction in the series of condensed azines with naphthalene substituents was presented. Photophysical properties of the obtained fluorophores were studied, in particular, green fluorescence in the 485–536 nm range with quantum yield up to 32.4% was detected. HOMO-LUMO energy values and distributions for the new compounds were calculated by the DFT method in comparison with nitroanalytes and perylene. Based on the data obtained, as well as on the results of fluorescence titration, the possibility of using the new diazaperylenes as potential chemosensors for the visual detection of nitrocontaining explosives was shown.en
dc.description.sponsorshipThis work was supported by Grants Council of the Presi-dent of the Russian Federation № NSh-2700.2020.3.en
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.publisherУральский федеральный университетru
dc.publisherUral Federal Universityen
dc.relation.ispartofChimica Techno Acta. 2021. Vol. 8. № 4en
dc.subjectNAPHTHO[1,8-EF]PERIMIDINESen
dc.subjectFLUORESCENCEen
dc.subjectSENSORen
dc.subjectEXPLOSIVESen
dc.titleNew naphtho[1,8-ef]perimidines: synthesis, fluorescence studies and application for detection of nitroanalytesen
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.identifier.rsihttps://www.elibrary.ru/item.asp?id=47569644-
dc.identifier.doi10.15826/chimtech.2021.8.4.16-
local.contributor.studentSavchuk, Мaria I.en
local.contributor.employeeNikonov, Igor L.en
local.contributor.employeeSadieva, Leila K.en
local.contributor.employeeStarnovskaya, Ekaterina S.en
local.contributor.employeeKopchuk, Dmitry S.en
local.contributor.employeeKovalev, Igor S.en
local.contributor.employeeChupakhin, Oleg N.en
local.contributor.employeeНиконов, Игорь Леонидовичru
local.contributor.employeeСадиева, Лейла Керим Кызыru
local.contributor.employeeСтарновская, Екатерина Сергеевнаru
local.contributor.employeeКопчук, Дмитрий Сергеевичru
local.contributor.employeeКовалев, Игорь Сергеевичru
local.contributor.employeeЧупахин, Олег Николаевичru
local.description.order№ 20218416-
local.contributorNikonov, Igor L.en
local.contributorSavchuk, Maria I.en
local.contributorStarnovskaya, Ekaterina S.en
local.contributorKopchuk, Dmitry S.en
local.contributorKim, Grigory A.en
local.contributorChupakhin, Oleg N.en
Располагается в коллекциях:Chimica Techno Acta

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