Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на этот ресурс: http://elar.urfu.ru/handle/10995/102955
Полная запись метаданных
Поле DCЗначениеЯзык
dc.contributor.authorSteinbrecher, M.en
dc.contributor.authorVan, Weerdenburg, W. M. J.en
dc.contributor.authorWalraven, E. F.en
dc.contributor.authorVan, Mullekom, N. P. E.en
dc.contributor.authorGerritsen, J. W.en
dc.contributor.authorNatterer, F. D.en
dc.contributor.authorBadrtdinov, D. I.en
dc.contributor.authorRudenko, A. N.en
dc.contributor.authorMazurenko, V. V.en
dc.contributor.authorKatsnelson, M. I.en
dc.contributor.authorVan, Der, Avoird, A.en
dc.contributor.authorGroenenboom, G. C.en
dc.contributor.authorKhajetoorians, A. A.en
dc.date.accessioned2021-08-31T15:06:35Z-
dc.date.available2021-08-31T15:06:35Z-
dc.date.issued2021-
dc.identifier.citationQuantifying the interplay between fine structure and geometry of an individual molecule on a surface / M. Steinbrecher, W. M. J. Van Weerdenburg, E. F. Walraven, et al. — DOI 10.1103/PhysRevB.103.155405 // Physical Review B. — 2021. — Vol. 103. — Iss. 15. — 155405.en
dc.identifier.issn24699950-
dc.identifier.otherFinal2
dc.identifier.otherAll Open Access, Green3
dc.identifier.otherhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85104467813&doi=10.1103%2fPhysRevB.103.155405&partnerID=40&md5=b00b4c7af9d81fa07ca53e73c0c0abc2
dc.identifier.otherhttp://arxiv.org/pdf/2007.01928m
dc.identifier.urihttp://elar.urfu.ru/handle/10995/102955-
dc.description.abstractThe pathway toward the tailored synthesis of materials starts with precise characterization of the conformational properties and dynamics of individual molecules. Electron spin resonance (ESR)-based scanning tunneling microscopy can potentially address molecular structure with unprecedented resolution. Here, we determine the fine structure and geometry of an individual titanium-hydride molecule, utilizing a combination of a newly developed millikelvin ESR scanning tunneling microscope in a vector magnetic field and ab initio approaches. We demonstrate a strikingly large anisotropy of the g tensor, unusual for a spin doublet ground state, resulting from a nontrivial orbital angular momentum stemming from the molecular ground state. We quantify the relationship between the resultant fine structure, hindered rotational modes, and orbital excitations. Our model system provides avenues to determine the structure and dynamics of individual molecules. © 2021 American Physical Society.en
dc.description.sponsorshipWe acknowledge funding from the Dutch Research Council (NWO), and the Vidi Project “Manipulating the interplay between superconductivity and chiral magnetism at the single-atom level” with Project No. 680-47-534. This project has received funding from the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation program (SPINAPSE: Grant Agreement No. 818399). F.D.N. thanks the Swiss National Science Foundation for financial support under Grant No. PP00P2_176866. The work of D.I.B., A.N.R. and V.V.M. was supported by Act 211 Government of the Russian Federation Contract No. 02.A03.21.0006.en
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.publisherAmerican Physical Societyen
dc.rightsinfo:eu-repo/semantics/openAccessen
dc.sourcePhys. Rev. B2
dc.sourcePhysical Review Ben
dc.subjectATOMIC PHYSICSen
dc.subjectELECTRON SPIN RESONANCE SPECTROSCOPYen
dc.subjectELECTROSPINNINGen
dc.subjectGROUND STATEen
dc.subjectMAGNETIC MOMENTSen
dc.subjectMOLECULESen
dc.subjectSCANNING TUNNELING MICROSCOPYen
dc.subjectTITANIUM COMPOUNDSen
dc.subjectTITANIUM METALLOGRAPHYen
dc.subjectAB INITIO APPROACHen
dc.subjectCONFORMATIONAL PROPERTIESen
dc.subjectDOUBLET GROUND STATEen
dc.subjectMOLECULAR GROUND STATEen
dc.subjectORBITAL ANGULAR MOMENTUMen
dc.subjectORBITAL EXCITATIONSen
dc.subjectSTRUCTURE AND DYNAMICSen
dc.subjectVECTOR MAGNETIC FIELDSen
dc.subjectSYNTHESIS (CHEMICAL)en
dc.titleQuantifying the interplay between fine structure and geometry of an individual molecule on a surfaceen
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1103/PhysRevB.103.155405-
dc.identifier.scopus85104467813-
local.contributor.employeeSteinbrecher, M., Institute for Molecules and Materials, Radboud University, Nijmegen, 6525 AJ, Netherlands
local.contributor.employeeVan Weerdenburg, W.M.J., Institute for Molecules and Materials, Radboud University, Nijmegen, 6525 AJ, Netherlands
local.contributor.employeeWalraven, E.F., Institute for Molecules and Materials, Radboud University, Nijmegen, 6525 AJ, Netherlands
local.contributor.employeeVan Mullekom, N.P.E., Institute for Molecules and Materials, Radboud University, Nijmegen, 6525 AJ, Netherlands
local.contributor.employeeGerritsen, J.W., Institute for Molecules and Materials, Radboud University, Nijmegen, 6525 AJ, Netherlands
local.contributor.employeeNatterer, F.D., Department of Physics, University of Zurich, Zurich, 8057, Switzerland
local.contributor.employeeBadrtdinov, D.I., Institute for Molecules and Materials, Radboud University, Nijmegen, 6525 AJ, Netherlands, Theoretical Physics and Applied Mathematics Department, Ural Federal University, Ekaterinburg, 620002, Russian Federation
local.contributor.employeeRudenko, A.N., Institute for Molecules and Materials, Radboud University, Nijmegen, 6525 AJ, Netherlands, Theoretical Physics and Applied Mathematics Department, Ural Federal University, Ekaterinburg, 620002, Russian Federation, School of Physics and Technology, Wuhan University, Wuhan, 430072, China
local.contributor.employeeMazurenko, V.V., Theoretical Physics and Applied Mathematics Department, Ural Federal University, Ekaterinburg, 620002, Russian Federation
local.contributor.employeeKatsnelson, M.I., Institute for Molecules and Materials, Radboud University, Nijmegen, 6525 AJ, Netherlands, Theoretical Physics and Applied Mathematics Department, Ural Federal University, Ekaterinburg, 620002, Russian Federation
local.contributor.employeeVan Der Avoird, A., Institute for Molecules and Materials, Radboud University, Nijmegen, 6525 AJ, Netherlands
local.contributor.employeeGroenenboom, G.C., Institute for Molecules and Materials, Radboud University, Nijmegen, 6525 AJ, Netherlands
local.contributor.employeeKhajetoorians, A.A., Institute for Molecules and Materials, Radboud University, Nijmegen, 6525 AJ, Netherlands
local.issue15-
local.volume103-
local.contributor.departmentInstitute for Molecules and Materials, Radboud University, Nijmegen, 6525 AJ, Netherlands
local.contributor.departmentDepartment of Physics, University of Zurich, Zurich, 8057, Switzerland
local.contributor.departmentTheoretical Physics and Applied Mathematics Department, Ural Federal University, Ekaterinburg, 620002, Russian Federation
local.contributor.departmentSchool of Physics and Technology, Wuhan University, Wuhan, 430072, China
local.identifier.pure21870723-
local.identifier.pure5a0bec6a-d5d7-4de6-a84e-15d01ee6ce24uuid
local.description.order155405-
local.identifier.eid2-s2.0-85104467813-
local.fund.cordis81839-
Располагается в коллекциях:Научные публикации, проиндексированные в SCOPUS и WoS CC

Файлы этого ресурса:
Файл Описание РазмерФормат 
2-s2.0-85104467813.pdf5,76 MBAdobe PDFПросмотреть/Открыть


Все ресурсы в архиве электронных ресурсов защищены авторским правом, все права сохранены.