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dc.contributor.authorThauer, E.en
dc.contributor.authorZakharova, G. S.en
dc.contributor.authorAndreikov, E. I.en
dc.contributor.authorAdam, V.en
dc.contributor.authorWegener, S. A.en
dc.contributor.authorNölke, J. -H.en
dc.contributor.authorSinger, L.en
dc.contributor.authorOttmann, A.en
dc.contributor.authorAsyuda, A.en
dc.contributor.authorZharnikov, M.en
dc.contributor.authorKiselkov, D. M.en
dc.contributor.authorZhu, Q.en
dc.contributor.authorPuzyrev, I. S.en
dc.contributor.authorPodval’naya, N. V.en
dc.contributor.authorKlingeler, R.en
dc.date.accessioned2021-08-31T15:06:17Z-
dc.date.available2021-08-31T15:06:17Z-
dc.date.issued2021-
dc.identifier.citationNovel synthesis and electrochemical investigations of ZnO/C composites for lithium-ion batteries / E. Thauer, G. S. Zakharova, E. I. Andreikov, et al. — DOI 10.1007/s10853-021-06125-4 // Journal of Materials Science. — 2021. — Vol. 56. — Iss. 23. — P. 13227-13242.en
dc.identifier.issn222461-
dc.identifier.otherFinal2
dc.identifier.otherAll Open Access, Hybrid Gold3
dc.identifier.otherhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85105630780&doi=10.1007%2fs10853-021-06125-4&partnerID=40&md5=d9a7717371df720f555241d7748173cd
dc.identifier.otherhttps://link.springer.com/content/pdf/10.1007/s10853-021-06125-4.pdfm
dc.identifier.urihttp://elar.urfu.ru/handle/10995/102922-
dc.description.abstractFor the first time, ZnO/C composites were synthesized using zinc glycerolate as a precursor through one-step calcination under a nitrogen atmosphere. The effect of the heat treatment conditions on the structure, composition, morphology as well as on the electrochemical properties regarding application in lithium-ion batteries are investigated. The products obtained by calcination of the precursor in nitrogen at 400—800 °C consist of zinc oxide nanoparticles and amorphous carbon that is in-situ generated from organic components of the glycerolate precursor. When used as anode material for lithium-ion batteries, the as-prepared ZnO/C composite synthesized at a calcination temperature of 700 °C delivers initial discharge and charge capacities of 1061 and 671 mAh g−1 at a current rate of 100 mA g−1 and hence 1.5 times more than bare ZnO, which reaches only 749/439 mAh g−1. The native carbon improves the conductivity, allowing efficient electronic conductivity and Li-ion diffusion. By means of ex-situ XRD studies a two-step storage mechanism is proven. © 2021, The Author(s).en
dc.description.sponsorshipThis work was supported by the Deutsche Forschungsgemeinschaft through projects KL1824/12-1 and KL 1824/14-1. G.Z. acknowledges support of the state order via the Ministry of Science and Higher Education of Russia (No AAAA-A19-119031890025-9). E.T. acknowledges support by the BMWi through project 03ET6095C (HiKoMat). The authors thank I. Glass for experimental support.en
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.publisherSpringeren
dc.rightsinfo:eu-repo/semantics/openAccessen
dc.sourceJ Mater Sci2
dc.sourceJournal of Materials Scienceen
dc.subjectAMORPHOUS CARBONen
dc.subjectANODESen
dc.subjectCALCINATIONen
dc.subjectELECTRIC DISCHARGESen
dc.subjectHEAT TREATMENTen
dc.subjectII-VI SEMICONDUCTORSen
dc.subjectIONSen
dc.subjectNITROGENen
dc.subjectOXIDE MINERALSen
dc.subjectZINC OXIDEen
dc.subjectZNO NANOPARTICLESen
dc.subjectANODE MATERIAL FOR LITHIUM ION BATTERIESen
dc.subjectCALCINATION TEMPERATUREen
dc.subjectELECTROCHEMICAL INVESTIGATIONSen
dc.subjectELECTRONIC CONDUCTIVITYen
dc.subjectHEAT TREATMENT CONDITIONSen
dc.subjectNITROGEN ATMOSPHERESen
dc.subjectORGANIC COMPONENTSen
dc.subjectZINC OXIDE NANOPARTICLESen
dc.subjectLITHIUM-ION BATTERIESen
dc.titleNovel synthesis and electrochemical investigations of ZnO/C composites for lithium-ion batteriesen
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.identifier.rsi46053530-
dc.identifier.doi10.1007/s10853-021-06125-4-
dc.identifier.scopus85105630780-
local.contributor.employeeThauer, E., Kirchhoff Institute of Physics, Heidelberg University, Heidelberg, Germany
local.contributor.employeeZakharova, G.S., Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Yekaterinburg, Russian Federation, Ural Federal University, Yekaterinburg, Russian Federation
local.contributor.employeeAndreikov, E.I., I.Ya. Postovskii Institute of Organic Synthesis, Ural Division, Russian Academy of Sciences, Yekaterinburg, Russian Federation
local.contributor.employeeAdam, V., Kirchhoff Institute of Physics, Heidelberg University, Heidelberg, Germany
local.contributor.employeeWegener, S.A., Kirchhoff Institute of Physics, Heidelberg University, Heidelberg, Germany
local.contributor.employeeNölke, J.-H., Kirchhoff Institute of Physics, Heidelberg University, Heidelberg, Germany
local.contributor.employeeSinger, L., Kirchhoff Institute of Physics, Heidelberg University, Heidelberg, Germany
local.contributor.employeeOttmann, A., Kirchhoff Institute of Physics, Heidelberg University, Heidelberg, Germany
local.contributor.employeeAsyuda, A., Applied Physical Chemistry, Heidelberg University, Heidelberg, Germany
local.contributor.employeeZharnikov, M., Applied Physical Chemistry, Heidelberg University, Heidelberg, Germany
local.contributor.employeeKiselkov, D.M., Institute of Technical Chemistry, Ural Division, Russian Academy of Sciences, Perm, Russian Federation
local.contributor.employeeZhu, Q., School of Material Science and Engineering, Wuhan University of Technology, Wuhan, China
local.contributor.employeePuzyrev, I.S., I.Ya. Postovskii Institute of Organic Synthesis, Ural Division, Russian Academy of Sciences, Yekaterinburg, Russian Federation
local.contributor.employeePodval’naya, N.V., Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Yekaterinburg, Russian Federation
local.contributor.employeeKlingeler, R., Kirchhoff Institute of Physics, Heidelberg University, Heidelberg, Germany, Centre for Advanced Materials, Heidelberg University, Heidelberg, Germany
local.description.firstpage13227-
local.description.lastpage13242-
local.issue23-
local.volume56-
dc.identifier.wos000650098000002-
local.contributor.departmentKirchhoff Institute of Physics, Heidelberg University, Heidelberg, Germany
local.contributor.departmentInstitute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Yekaterinburg, Russian Federation
local.contributor.departmentUral Federal University, Yekaterinburg, Russian Federation
local.contributor.departmentI.Ya. Postovskii Institute of Organic Synthesis, Ural Division, Russian Academy of Sciences, Yekaterinburg, Russian Federation
local.contributor.departmentApplied Physical Chemistry, Heidelberg University, Heidelberg, Germany
local.contributor.departmentInstitute of Technical Chemistry, Ural Division, Russian Academy of Sciences, Perm, Russian Federation
local.contributor.departmentSchool of Material Science and Engineering, Wuhan University of Technology, Wuhan, China
local.contributor.departmentCentre for Advanced Materials, Heidelberg University, Heidelberg, Germany
local.identifier.pure21883388-
local.identifier.eid2-s2.0-85105630780-
local.identifier.wosWOS:000650098000002-
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