Please use this identifier to cite or link to this item: http://hdl.handle.net/10995/102674
Title: A Rare Example of Discrete Lanthanide–Lithium Tetrakis-β-Diketonates: Synthesis, Structures, and Luminescence Properties
Authors: Kudyakova, Y. S.
Slepukhin, P. A.
Valova, M. S.
Burgart, Y. V.
Saloutin, V. I.
Bazhin, D. N.
Issue Date: 2020
Publisher: Pleiades Publishing
Citation: A Rare Example of Discrete Lanthanide–Lithium Tetrakis-β-Diketonates: Synthesis, Structures, and Luminescence Properties / Y. S. Kudyakova, P. A. Slepukhin, M. S. Valova, et al. — DOI 10.1134/S1070328420070027 // Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya. — 2020. — Vol. 46. — Iss. 8. — P. 545-552.
Abstract: Abstract: The reactions of functionalized lithium CF3-β-diketonate (LiL) with europium(III) and terbium(III) chlorides in acetonitrile afford heterobimetallic complexes with the general formula [LiL-nL4(H2O)](CH3CN) (Ln = Eu (IIIa) and Tb (IIIb)). It is found that Ln–Li tetrakis-β-diketonates can also be prepared by the crystallization from acetonitrile of the previously synthesized complexes [(LnL3)(LiL)(MeOH)] (I) and [(LnL3)(LiL)(H2O)] (II). For the first time, the single crystals of the compounds in a series of Ln–Li tetrakis-β-diketonates are characterized by X-ray diffraction analysis (CIF files CCDC nos. 1973632 (IIIa) and 1973633 (IIIb)). The photoluminescence properties of the synthesized heterometallic complexes in the solid state are studied. © 2020, Pleiades Publishing, Ltd.
Keywords: LANTHANIDES
LUMINESCENCE
X-RAY DIFFRACTION ANALYSIS
Β-DIKETONATES
ACETONITRILE
CHLORINE COMPOUNDS
EUROPIUM COMPOUNDS
LITHIUM
LITHIUM METALLOGRAPHY
LUMINESCENCE
SYNTHESIS (CHEMICAL)
TIME SERIES ANALYSIS
X RAY POWDER DIFFRACTION
BETA-DIKETONATES
EUROPIUMS (III)
FUNCTIONALIZED
GENERAL FORMULAS
HETERO BIMETALLIC COMPLEXES
HETEROMETALLIC COMPLEXES
LUMINESCENCE PROPERTIES
PHOTOLUMINESCENCE PROPERTIES
TERBIUM COMPOUNDS
URI: http://hdl.handle.net/10995/102674
Access: info:eu-repo/semantics/openAccess
SCOPUS ID: 85089199666
PURE ID: 13680678
d0434286-ab94-4253-a9fe-73b2001d8d6b
ISSN: 10703284
DOI: 10.1134/S1070328420070027
metadata.dc.description.sponsorship: This work was supported by the Russian Foundation for Basic Research (project no. 18-33-20124), Council for Grants of President of the Russian Federation (grant no. MK-1453.2019.3), and basic themes of the Russian Academy of Sciences (state registration nos. AAAA-A19-119011790132-7 and AAAA-A19-119012490006-1).
Appears in Collections:Научные публикации, проиндексированные в SCOPUS и WoS CC

Files in This Item:
File Description SizeFormat 
2-s2.0-85089199666.pdf1,75 MBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.