Please use this identifier to cite or link to this item: http://hdl.handle.net/10995/102666
Title: Thermodynamics, solubility and the separation of uranium from cerium in molten In/3LiCl-2KCl system
Authors: Xu, M.
Smolenski, V.
Liu, Q.
Novoselova, A.
Jiang, K.
Yu, J.
Liu, J.
Chen, R.
Zhang, H.
Zhang, M.
Wang, J.
Issue Date: 2020
Publisher: IOP Publishing Ltd
Citation: Thermodynamics, solubility and the separation of uranium from cerium in molten In/3LiCl-2KCl system / M. Xu, V. Smolenski, Q. Liu, et al. — DOI 10.1149/1945-7111/abb7f2 // Journal of the Electrochemical Society. — 2020. — Vol. 167. — Iss. 13. — 136506.
Abstract: The purpose of this work is to study the electrochemical behavior of uranium and cerium in fused In/3LiCl-2KCl system in the temperature range of 723-823 K by open-circuit potentiometry. The apparent electrode potential of Ce3+/Ce (U4+/U) couples and apparent standard potential of Ce-In (U-In) alloys vs AgCl/Ag reference electrode were established. The principal thermodynamic properties, activity and solubility of cerium and uranium were determined. The separation factor of uranium/cerium couple on liquid indium electrode was calculated. The experimental results have been shown that a lower temperature should be more effective for the separation uranium from cerium. © 2020 The Electrochemical Society ("ECS").
Keywords: BINARY ALLOYS
CERIUM
CERIUM ALLOYS
ELECTRODES
INDIUM ALLOYS
SEPARATION
SILVER ALLOYS
SILVER HALIDES
SOLUBILITY
THERMODYNAMICS
ELECTROCHEMICAL BEHAVIORS
ELECTRODE POTENTIALS
LIQUID INDIUM
LOWER TEMPERATURES
REFERENCE ELECTRODES
SEPARATION FACTORS
STANDARD POTENTIAL
TEMPERATURE RANGE
URANIUM ALLOYS
URI: http://hdl.handle.net/10995/102666
Access: info:eu-repo/semantics/openAccess
SCOPUS ID: 85092439262
PURE ID: 14127323
d118e0b8-0450-4b8a-8934-05e53d6014b5
ISSN: 134651
DOI: 10.1149/1945-7111/abb7f2
Appears in Collections:Научные публикации, проиндексированные в SCOPUS и WoS CC

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