Please use this identifier to cite or link to this item: http://hdl.handle.net/10995/102409
Title: Electrochemical properties of molybdenum in alkali chloride melts
Authors: Ivanov, A. B.
Volkovich, V. A.
Likhachev, P. Yu.
Kamalov, R. V.
Issue Date: 2014
Publisher: Electrochemical Society Inc.
Citation: Electrochemical properties of molybdenum in alkali chloride melts / A. B. Ivanov, V. A. Volkovich, P. Yu. Likhachev, et al. — DOI 10.1149/06404.0377ecst // ECS Transactions. — 2014. — Vol. 64. — Iss. 4. — P. 377-387.
Abstract: Behavior of molybdenum was studied in individual fused alkali chlorides and their mixtures employing electrochemical and spectroscopic techniques. Formal standard electrode potentials of molybdenum and thermodynamics of molybdenum chloride were obtained in molten LiCl, NaCl, KCl, RbCl, CsCl at 1123 K, NaCl- CsCl eutectic at 793-1023 K, NaCl-KCl equimolar mixture at 973- 1123 K, LiCl-KCl-CsCl eutectic at 633-1173 K. Diffusion coefficients of molybdenum ions were determined in LiCl-KCl- CsCl eutectic melt. Electronic absorption spectra of Mo(III) ions were measured in individual salts and their mixtures and spectroscopic parameters of MoCl6 3- complex ions determined. Copyright © 2014 by The Electrochemical Society. All rights reserved.
Keywords: ABSORPTION SPECTROSCOPY
CESIUM ALLOYS
CHLORINE COMPOUNDS
DIFFUSION
EUTECTICS
FUSED SALTS
IONS
METAL IONS
MIXTURES
MOLYBDENUM
MOLYBDENUM COMPOUNDS
SALTS
THERMODYNAMICS
ALKALI CHLORIDE MELTS
ALKALI CHLORIDES
ELECTRONIC ABSORPTION SPECTRA
EQUIMOLAR MIXTURES
MOLYBDENUM IONS
SPECTROSCOPIC PARAMETERS
SPECTROSCOPIC TECHNIQUE
STANDARD ELECTRODE POTENTIAL
IONIC LIQUIDS
URI: http://hdl.handle.net/10995/102409
Access: info:eu-repo/semantics/openAccess
SCOPUS ID: 84921372999
PURE ID: 379083
4f2b2544-271a-4475-908a-43b4fcd9c170
ISSN: 19385862
ISBN: 9781623321819
DOI: 10.1149/06404.0377ecst
Appears in Collections:Научные публикации, проиндексированные в SCOPUS и WoS CC

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