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dc.contributor.authorKamenetskih, A. S.en
dc.contributor.authorKukharenko, A. I.en
dc.contributor.authorKurmaev, E. Z.en
dc.contributor.authorSkorikov, N. A.en
dc.contributor.authorGavrilov, N. V.en
dc.contributor.authorCholakh, S. O.en
dc.contributor.authorChukin, A. V.en
dc.contributor.authorZainullina, V. M.en
dc.contributor.authorKorotin, M. A.en
dc.date.accessioned2021-08-31T15:03:18Z-
dc.date.available2021-08-31T15:03:18Z-
dc.date.issued2015-
dc.identifier.citationCharacterization of TiAlSiON coatings deposited by plasma enhanced magnetron sputtering: XRD, XPS, and DFT studies / A. S. Kamenetskih, A. I. Kukharenko, E. Z. Kurmaev, et al. — DOI 10.1016/j.surfcoat.2015.08.007 // Surface and Coatings Technology. — 2015. — Vol. 278. — P. 87-91.en
dc.identifier.issn2578972-
dc.identifier.otherFinal2
dc.identifier.otherAll Open Access, Green3
dc.identifier.otherhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-84941670773&doi=10.1016%2fj.surfcoat.2015.08.007&partnerID=40&md5=038f9c7b83ff1bce87bc0ef41149cf10
dc.identifier.otherhttps://elar.urfu.ru/bitstream/10995/99267/1/fti_2016_219.pdfm
dc.identifier.urihttp://elar.urfu.ru/handle/10995/102355-
dc.description.abstractThe results of characterization of TiAlSiON hard coatings deposited on ferric-chromium AISI 430 stainless steel by plasma enhanced magnetron sputtering are presented. The coating with maximum hardness (of 43GPa) was obtained at the following optimal values of elemental concentrations: Si ~5at.%, Al ~15at.%, and Ti ~27at.%. The value of gaseous mixture (Ar-N2) pressure was of 0.13Pa and the value of partial pressure of oxygen (O2) was 1.3·10-3Pa. The X-ray diffraction (XRD) measurements showed the presence of Ti(Al)N. High-energy resolved XPS spectra of core levels revealed the formation of Ti-N, Ti-O-N, Si-N and Al-O-N bonds. Comparison of XPS valence band spectra with specially performed density functional theory calculations for disordered Ti0.5Al0.5N1-xOx (0≤x≤0.3) phases demonstrated that a Ti(Al)OxNy phase is formed on the surface of AISI430 steel upon the plasma enhanced magnetron sputtering, which can provide a good combination of high hardness and additional oxidation resistance of this material. © 2015 Elsevier B.V.en
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.publisherElsevieren
dc.rightsinfo:eu-repo/semantics/openAccessen
dc.sourceSurf. Coat. Technol.2
dc.sourceSurface and Coatings Technologyen
dc.subjectDENSITY FUNCTIONAL THEORYen
dc.subjectELECTRONIC STRUCTUREen
dc.subjectMAGNETRON SPUTTERINGen
dc.subjectTIALON COATINGSen
dc.subjectX-RAY PHOTOELECTRON SPECTRAen
dc.subjectALUMINUMen
dc.subjectALUMINUM COATINGSen
dc.subjectELECTRONIC STRUCTUREen
dc.subjectHARD COATINGSen
dc.subjectHARDNESSen
dc.subjectMAGNETRON SPUTTERINGen
dc.subjectPHOTOELECTRON SPECTROSCOPYen
dc.subjectSTAINLESS STEELen
dc.subjectTITANIUMen
dc.subjectX RAY DIFFRACTIONen
dc.subjectX RAY PHOTOELECTRON SPECTROSCOPYen
dc.subjectAISI-430 STAINLESS STEELSen
dc.subjectELEMENTAL CONCENTRATIONSen
dc.subjectGASEOUS MIXTUREen
dc.subjectMAXIMUM HARDNESSen
dc.subjectPARTIAL PRESSURE OF OXYGENen
dc.subjectPLASMA ENHANCED MAGNETRON SPUTTERINGen
dc.subjectVALENCE BAND SPECTRAen
dc.subjectX RAY PHOTOELECTRON SPECTRAen
dc.subjectDENSITY FUNCTIONAL THEORYen
dc.titleCharacterization of TiAlSiON coatings deposited by plasma enhanced magnetron sputtering: XRD, XPS, and DFT studiesen
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1016/j.surfcoat.2015.08.007-
dc.identifier.scopus84941670773-
local.contributor.employeeKamenetskih, A.S., Institute of Electrophysics, Russian Academy of Sciences, Ural Branch, Amundsen Street 106, Yekaterinburg, 620016, Russian Federation
local.contributor.employeeKukharenko, A.I., M.N. Mikheev Institute of Metal Physics of the Ural Branch of Russian Academy of Sciences, S. Kovalevskoi Street 18, Yekaterinburg, 620990, Russian Federation, Ural Federal University, Mira Street 19, Yekaterinburg, 620002, Russian Federation
local.contributor.employeeKurmaev, E.Z., M.N. Mikheev Institute of Metal Physics of the Ural Branch of Russian Academy of Sciences, S. Kovalevskoi Street 18, Yekaterinburg, 620990, Russian Federation, Ural Federal University, Mira Street 19, Yekaterinburg, 620002, Russian Federation
local.contributor.employeeSkorikov, N.A., M.N. Mikheev Institute of Metal Physics of the Ural Branch of Russian Academy of Sciences, S. Kovalevskoi Street 18, Yekaterinburg, 620990, Russian Federation
local.contributor.employeeGavrilov, N.V., Institute of Electrophysics, Russian Academy of Sciences, Ural Branch, Amundsen Street 106, Yekaterinburg, 620016, Russian Federation
local.contributor.employeeCholakh, S.O., Ural Federal University, Mira Street 19, Yekaterinburg, 620002, Russian Federation
local.contributor.employeeChukin, A.V., Ural Federal University, Mira Street 19, Yekaterinburg, 620002, Russian Federation
local.contributor.employeeZainullina, V.M., M.N. Mikheev Institute of Metal Physics of the Ural Branch of Russian Academy of Sciences, S. Kovalevskoi Street 18, Yekaterinburg, 620990, Russian Federation, Institute of Solid State Chemistry, Russian Academy of Sciences, Ural Branch, Pervomajskaya Street 91, Yekaterinburg, 620990, Russian Federation
local.contributor.employeeKorotin, M.A., M.N. Mikheev Institute of Metal Physics of the Ural Branch of Russian Academy of Sciences, S. Kovalevskoi Street 18, Yekaterinburg, 620990, Russian Federation
local.description.firstpage87-
local.description.lastpage91-
local.volume278-
dc.identifier.wos000361934800012-
local.contributor.departmentInstitute of Electrophysics, Russian Academy of Sciences, Ural Branch, Amundsen Street 106, Yekaterinburg, 620016, Russian Federation
local.contributor.departmentM.N. Mikheev Institute of Metal Physics of the Ural Branch of Russian Academy of Sciences, S. Kovalevskoi Street 18, Yekaterinburg, 620990, Russian Federation
local.contributor.departmentUral Federal University, Mira Street 19, Yekaterinburg, 620002, Russian Federation
local.contributor.departmentInstitute of Solid State Chemistry, Russian Academy of Sciences, Ural Branch, Pervomajskaya Street 91, Yekaterinburg, 620990, Russian Federation
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local.identifier.pure289406-
local.identifier.eid2-s2.0-84941670773-
local.identifier.wosWOS:000361934800012-
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