Please use this identifier to cite or link to this item: http://hdl.handle.net/10995/101927
Full metadata record
DC FieldValueLanguage
dc.contributor.authorChakraborty, G. N.en
dc.contributor.authorDe A.en
dc.contributor.authorMahato, S.en
dc.contributor.authorSantra, S.en
dc.contributor.authorV. , Zyryanov, G.en
dc.contributor.authorMajee, A.en
dc.date.accessioned2021-08-31T15:00:41Z-
dc.date.available2021-08-31T15:00:41Z-
dc.date.issued2018-
dc.identifier.citationAn Efficient Synthesis of Oxazolidines by Tandem Ring-Opening / Closing Reaction of Ts-Aziridine Using Formic Acid / N. Chakraborty Ghosal, A. De, S. Mahato, et al. — DOI 10.1002/slct.201802657 // ChemistrySelect. — 2018. — Vol. 3. — Iss. 37. — P. 10509-10514.en
dc.identifier.issn23656549-
dc.identifier.otherFinal2
dc.identifier.otherAll Open Access, Green3
dc.identifier.otherhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85054570865&doi=10.1002%2fslct.201802657&partnerID=40&md5=811a5ff77de3c027dcbccd5b7f6c1d8b
dc.identifier.otherhttps://elar.urfu.ru/bitstream/10995/76492/1/978-5-7996-2691-4_151.pdfm
dc.identifier.urihttp://hdl.handle.net/10995/101927-
dc.description.abstractSynthesis of oxazolidines has been reported from aziridines by the reaction with formic acid and formaldehyde in neat conditions. We have also observed a regio-selective nucleophilic ring opening of aziridines by HCOOH under same conditions in absence of formaldehyde where the HCOO− ion acts as a nucleophile. In this present method formic acid is not acting as reducing agent as classical organic reactions. The formic acid initially activates the aziridines whereas the formate group generated from formic acid acts as a nucleophile itself instead of the source of hydride ion affording the nucleophilic ring opening products. The synthesized formate ester was successfully hydrolyzed to the corresponding hydroxyl compound which is the key building block for the synthesis of heterocycles. Operational simplicity, mild and neat reaction conditions, broad substrates scope, good yields and uses of less expensive reagents are the notable advantages of the present procedures. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheimen
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.publisherWiley-Blackwellen
dc.rightsinfo:eu-repo/semantics/openAccessen
dc.sourceChemistrySelect2
dc.sourceChemistrySelecten
dc.subjectAZIRIDINESen
dc.subjectFORMALDEHYDEen
dc.subjectFORMIC ACIDen
dc.subjectNEATen
dc.subjectOXAZOLIDINESen
dc.subjectRING-CLOSINGen
dc.subjectRING-OPENINGen
dc.titleAn Efficient Synthesis of Oxazolidines by Tandem Ring-Opening / Closing Reaction of Ts-Aziridine Using Formic Aciden
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1002/slct.201802657-
dc.identifier.scopus85054570865-
local.contributor.employeeChakraborty Ghosal, N., Department of Chemistry, Visva-Bharati (A Central University), Santiniketan, 731235, India
local.contributor.employeeDe A., Department of Chemistry, Visva-Bharati (A Central University), Santiniketan, 731235, India
local.contributor.employeeMahato, S., Department of Chemistry, Visva-Bharati (A Central University), Santiniketan, 731235, India
local.contributor.employeeSantra, S., Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University, 19 Mira Street, Yekaterinburg, 620002, Russian Federation
local.contributor.employeeV. Zyryanov, G., Department of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University, 19 Mira Street, Yekaterinburg, 620002, Russian Federation, I. Ya. Postovskiy Institute of Organic Synthesis, Ural Division of the Russian Academy of Sciences, 22 S. Kovalevskoy Street, Yekaterinburg, 620219, Russian Federation
local.contributor.employeeMajee, A., Department of Chemistry, Visva-Bharati (A Central University), Santiniketan, 731235, India
local.description.firstpage10509-
local.description.lastpage10514-
local.issue37-
local.volume3-
local.contributor.departmentDepartment of Chemistry, Visva-Bharati (A Central University), Santiniketan, 731235, India
local.contributor.departmentDepartment of Organic and Biomolecular Chemistry, Chemical Engineering Institute, Ural Federal University, 19 Mira Street, Yekaterinburg, 620002, Russian Federation
local.contributor.departmentI. Ya. Postovskiy Institute of Organic Synthesis, Ural Division of the Russian Academy of Sciences, 22 S. Kovalevskoy Street, Yekaterinburg, 620219, Russian Federation
local.identifier.pure8158889-
local.identifier.eid2-s2.0-85054570865-
Appears in Collections:Научные публикации, проиндексированные в SCOPUS и WoS CC

Files in This Item:
File Description SizeFormat 
2-s2.0-85054570865.pdf92,2 kBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.