Please use this identifier to cite or link to this item: http://hdl.handle.net/10995/101451
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dc.contributor.authorRempel, S. V.en
dc.contributor.authorRempel, A. A.en
dc.contributor.authorValeeva, A. A.en
dc.date.accessioned2021-08-31T14:57:24Z-
dc.date.available2021-08-31T14:57:24Z-
dc.date.issued2020-
dc.identifier.citationRempel S. V. Effect of Stoichiometry and Ordering on the Microstructure of Titanium Monoxide TiOy / S. V. Rempel, A. A. Rempel, A. A. Valeeva. — DOI 10.1021/acsomega.0c03122 // ACS Omega. — 2020. — Vol. 5. — Iss. 35. — P. 22513-22519.en
dc.identifier.issn24701343-
dc.identifier.otherFinal2
dc.identifier.otherAll Open Access, Bronze3
dc.identifier.otherhttps://www.scopus.com/inward/record.uri?eid=2-s2.0-85090998277&doi=10.1021%2facsomega.0c03122&partnerID=40&md5=d83f636f4498176ee90661ae4fe91ae8
dc.identifier.otherhttps://pubs.acs.org/doi/pdf/10.1021/acsomega.0c03122m
dc.identifier.urihttp://hdl.handle.net/10995/101451-
dc.description.abstractThe structure of titanium monoxide TiOy with different stoichiometries and long-range order degrees was studied by using X-ray diffraction, electron backscatter diffraction, Raman spectroscopy, and electron microscopy methods. It was established that the composition of the phases formed in annealed TiOy depends on the titanium monoxide stoichiometry. A new phase precipitation mechanism is proposed. The migration of vacancies in dislocations and their accumulation on grain boundaries play an important role in the formation of new phases. The stoichiometry of quenched titanium monoxide (TiOy) was found to affect the intensity of the peak associated with the vibrational mode of the Ti-O bond in Raman spectra. Copyright © 2020 American Chemical Society.en
dc.description.sponsorshipThe authors are grateful to M. V. Lukashova (Demonstration laboratory TESCAN, St. Petersburg) for her assistance in carrying out the research. The reported study was funded by RFBR according to the research project no. 19-03-00051a.en
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.publisherAmerican Chemical Societyen
dc.rightsinfo:eu-repo/semantics/openAccessen
dc.sourceACS Omega2
dc.sourceACS Omegaen
dc.titleEffect of Stoichiometry and Ordering on the Microstructure of Titanium Monoxide TiOyen
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1021/acsomega.0c03122-
dc.identifier.scopus85090998277-
local.contributor.employeeRempel, S.V., Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91, Pervomaiskaya Str, Ekaterinburg, 620990, Russian Federation, Ural Federal University, 19, Mira Str, Ekaterinburg, 620002, Russian Federation
local.contributor.employeeRempel, A.A., Ural Federal University, 19, Mira Str, Ekaterinburg, 620002, Russian Federation, Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences, Amundsena St., 101, Ekaterinburg, 620016, Russian Federation
local.contributor.employeeValeeva, A.A., Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91, Pervomaiskaya Str, Ekaterinburg, 620990, Russian Federation, Ural Federal University, 19, Mira Str, Ekaterinburg, 620002, Russian Federation
local.description.firstpage22513-
local.description.lastpage22519-
local.issue35-
local.volume5-
local.contributor.departmentInstitute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91, Pervomaiskaya Str, Ekaterinburg, 620990, Russian Federation
local.contributor.departmentUral Federal University, 19, Mira Str, Ekaterinburg, 620002, Russian Federation
local.contributor.departmentInstitute of Metallurgy of the Ural Branch of the Russian Academy of Sciences, Amundsena St., 101, Ekaterinburg, 620016, Russian Federation
local.identifier.pure13931139-
local.identifier.eid2-s2.0-85090998277-
local.fund.rffi19-03-00051-
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