Effect of Stoichiometry and Ordering on the Microstructure of Titanium Monoxide TiOy

Rempel, S. V.; Rempel, A. A.; Valeeva, A. A.

doi:10.1021/acsomega.0c03122

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Поле DC	Значение	Язык
dc.contributor.author	Rempel, S. V.	en
dc.contributor.author	Rempel, A. A.	en
dc.contributor.author	Valeeva, A. A.	en
dc.date.accessioned	2021-08-31T14:57:24Z	-
dc.date.available	2021-08-31T14:57:24Z	-
dc.date.issued	2020	-
dc.identifier.citation	Rempel S. V. Effect of Stoichiometry and Ordering on the Microstructure of Titanium Monoxide TiOy / S. V. Rempel, A. A. Rempel, A. A. Valeeva. — DOI 10.1021/acsomega.0c03122 // ACS Omega. — 2020. — Vol. 5. — Iss. 35. — P. 22513-22519.	en
dc.identifier.issn	24701343	-
dc.identifier.other	Final	2
dc.identifier.other	All Open Access, Bronze	3
dc.identifier.other	https://www.scopus.com/inward/record.uri?eid=2-s2.0-85090998277&doi=10.1021%2facsomega.0c03122&partnerID=40&md5=d83f636f4498176ee90661ae4fe91ae8
dc.identifier.other	https://pubs.acs.org/doi/pdf/10.1021/acsomega.0c03122	m
dc.identifier.uri	http://elar.urfu.ru/handle/10995/101451	-
dc.description.abstract	The structure of titanium monoxide TiOy with different stoichiometries and long-range order degrees was studied by using X-ray diffraction, electron backscatter diffraction, Raman spectroscopy, and electron microscopy methods. It was established that the composition of the phases formed in annealed TiOy depends on the titanium monoxide stoichiometry. A new phase precipitation mechanism is proposed. The migration of vacancies in dislocations and their accumulation on grain boundaries play an important role in the formation of new phases. The stoichiometry of quenched titanium monoxide (TiOy) was found to affect the intensity of the peak associated with the vibrational mode of the Ti-O bond in Raman spectra. Copyright © 2020 American Chemical Society.	en
dc.description.sponsorship	The authors are grateful to M. V. Lukashova (Demonstration laboratory TESCAN, St. Petersburg) for her assistance in carrying out the research. The reported study was funded by RFBR according to the research project no. 19-03-00051a.	en
dc.format.mimetype	application/pdf	en
dc.language.iso	en	en
dc.publisher	American Chemical Society	en
dc.rights	info:eu-repo/semantics/openAccess	en
dc.source	ACS Omega	2
dc.source	ACS Omega	en
dc.title	Effect of Stoichiometry and Ordering on the Microstructure of Titanium Monoxide TiOy	en
dc.type	Article	en
dc.type	info:eu-repo/semantics/article	en
dc.type	info:eu-repo/semantics/publishedVersion	en
dc.identifier.doi	10.1021/acsomega.0c03122	-
dc.identifier.scopus	85090998277	-
local.contributor.employee	Rempel, S.V., Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91, Pervomaiskaya Str, Ekaterinburg, 620990, Russian Federation, Ural Federal University, 19, Mira Str, Ekaterinburg, 620002, Russian Federation
local.contributor.employee	Rempel, A.A., Ural Federal University, 19, Mira Str, Ekaterinburg, 620002, Russian Federation, Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences, Amundsena St., 101, Ekaterinburg, 620016, Russian Federation
local.contributor.employee	Valeeva, A.A., Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91, Pervomaiskaya Str, Ekaterinburg, 620990, Russian Federation, Ural Federal University, 19, Mira Str, Ekaterinburg, 620002, Russian Federation
local.description.firstpage	22513	-
local.description.lastpage	22519	-
local.issue	35	-
local.volume	5	-
local.contributor.department	Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, 91, Pervomaiskaya Str, Ekaterinburg, 620990, Russian Federation
local.contributor.department	Ural Federal University, 19, Mira Str, Ekaterinburg, 620002, Russian Federation
local.contributor.department	Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences, Amundsena St., 101, Ekaterinburg, 620016, Russian Federation
local.identifier.pure	13931139	-
local.identifier.eid	2-s2.0-85090998277	-
local.fund.rffi	19-03-00051	-
Располагается в коллекциях:	Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC

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