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http://elar.urfu.ru/handle/10995/101338
Название: | The Transformation of Di- and Tri-chloromethane Induced By Low Voltage Discharge |
Авторы: | Bodrikov, I. V. Grinvald, L. I. Titov, E. Yu. Titov, D. Yu. Razov, E. N. |
Дата публикации: | 2020 |
Издатель: | Knowledge E |
Библиографическое описание: | Bodrikov, I. V., Grinvald, L. I., Titov, E. Yu., Titov, D. Yu., Razov, E. N. (2020). The Transformation of Di- and Tri-chloromethane Induced By Low Voltage Discharge. KnE Materials Science, 6(1), 401–408. https://doi.org/10.18502/kms.v6i1.8117 |
Аннотация: | This article is focused on the transformation of di- and trichloromethane by induced low-voltage discharges in the liquid phase. To generate discharges, a direct current source is used (capacitance 2200 μF, voltage 60 V). The products and probable intermediates of the CH2Cl2 and CHCl3 transformation were determined by the methods of thermodynamic modeling, FTIR spectroscopy and electron microscopy. Under the action of low-voltage discharges on the liquid substrates, needle fullerene- like structures are formed. In this case the gas phase consists mainly of hydrogen chloride. From the simulation of the nonequilibrium composition of particles and molecular systems it follows that in the course of induced reactions of CH2Cl2 and CHCl3 and geminal elimination of HCl molecules, predominantly carbene-type intermediates are generated. |
Ключевые слова: | DICHLOROMETHANE TRICHLOROMETHANE LOW TEMPERATURE PLASMA DISCHARGES IN THE LIQUID PHASE |
URI: | http://elar.urfu.ru/handle/10995/101338 |
Условия доступа: | Creative Commons Attribution License |
Текст лицензии: | https://creativecommons.org/licenses/by/4.0/ |
Конференция/семинар: | IV Congress “Fundamental Research and Applied Developing of Recycling and Utilization Processes of Technogenic Formations” (TECHNOGEN 2019) |
Дата конференции/семинара: | 18.06.2019-21.06.2019 |
Идентификатор РИНЦ: | 44730073 |
ISSN: | 2519-1438 |
DOI: | 10.18502/kms.v6i1.8117 |
Сведения о поддержке: | The reported study was funded by RFBR according to the research project No 18-29-24008. |
Источники: | IV Congress “Fundamental Research and Applied Developing of Recycling and Utilization Processes of Technogenic Formations” (TECHNOGEN 2019). — Ekaterinburg, 2020 |
Располагается в коллекциях: | Междисциплинарные конференции, семинары, сборники |
Файлы этого ресурса:
Файл | Описание | Размер | Формат | |
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technogen_2019_64.pdf | 1,87 MB | Adobe PDF | Просмотреть/Открыть |
Лицензия на ресурс: Лицензия Creative Commons