Please use this identifier to cite or link to this item: http://elar.urfu.ru/handle/10995/96941
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dc.contributor.authorNguyen, T. K.en
dc.contributor.authorTitov, G. D.en
dc.contributor.authorKinzhalov, M. A.en
dc.contributor.authorRostovskii, N. V.en
dc.date.accessioned2021-03-15T09:16:37Z-
dc.date.available2021-03-15T09:16:37Z-
dc.date.issued2020-
dc.identifier.citationVinyl azide strategy for the synthesis of tetrasubstituted pyrimidines / T. K. Nguyen, G. D. Titov, M. A. Kinzhalov, N. V. Rostovskii // Актуальные вопросы органической химии и биотехнологии : материалы очных докладов международной научной конференции (Екатеринбург, 18–21 ноября 2020 г.). — Екатеринбург : Издательство АМБ, 2020. — С. 184-185.ru
dc.identifier.isbn978-5-6045430-2-3-
dc.identifier.urihttp://elar.urfu.ru/handle/10995/96941-
dc.description.abstractIn our research group, a new preparative procedure for the synthesis of tetrasubstituted pyrimidine derivatives from α-azidocinnamates was developed. The synthesis consists of the following stages: (i) LED light induced dimerization of α-azidocinnamates to 1,3-diazabicyclo[3.1.0]hex-3-enes via formation of 2H-azirines, (ii) DBU-catalyzed isomerization of 1,3-diazabicyclo[3.1.0]hex-3-enes to 1,6-dihydropyrimidines, (iii) aromatization of 1,6-dihydropyrimidines using DDQ.en
dc.description.sponsorshipThis work was done under support of the RSF (grant 19-73-10090) using resources of the Magnetic Resonance Research Centre, Chemical Analysis and Materials Research Centre, Centre for X-ray Diffraction Studies of the Research Park of St. Petersburg State University.en
dc.format.mimetypeapplication/pdfen
dc.language.isoruen
dc.publisherИздательство АМБru
dc.relationinfo:eu-repo/grantAgreement/RSF//19-73-10090en
dc.relation.ispartofАктуальные вопросы органической химии и биотехнологии. — Екатеринбург, 2020ru
dc.subjectVINYL AZIDESen
dc.subjectPHOTOCATALYSISen
dc.subjectPYRIMIDINEen
dc.titleVinyl azide strategy for the synthesis of tetrasubstituted pyrimidinesen
dc.typeConference Paperen
dc.typeinfo:eu-repo/semantics/conferenceObjecten
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.conference.nameМеждународная научно-практическая конференция «Актуальные вопросы органической химии и биотехнологии»ru
dc.conference.nameInternational Scientific Conference “Actual Problems of Organic Chemistry and Biotechnology”en
dc.conference.date18.11.2020-21.11.2020-
local.description.firstpage184-
local.description.lastpage185-
local.fund.rsf19-73-10090-
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