Please use this identifier to cite or link to this item: http://hdl.handle.net/10995/112205
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dc.contributor.authorBodrikov, I. V.en
dc.contributor.authorTitov, E. Y.en
dc.contributor.authorVorotyntsev, A. V.en
dc.contributor.authorPryakhina, V. I.en
dc.contributor.authorTitov, D. Y.en
dc.date.accessioned2022-05-12T08:30:27Z-
dc.date.available2022-05-12T08:30:27Z-
dc.date.issued2022-
dc.identifier.citationSynthesis of Decorated Carbon Structures with Encapsulated Components by Low-Voltage Electric Discharge Treatment / I. V. Bodrikov, E. Y. Titov, A. V. Vorotyntsev et al. — DOI 10.1007/s00355-015-0939-7 // High Energy Chemistry. — 2022. — Vol. 56. — Iss. 1. — P. 60-69.en
dc.identifier.issn0018-1439-
dc.identifier.otherAll Open Access, Hybrid Gold3
dc.identifier.urihttp://hdl.handle.net/10995/112205-
dc.description.abstractAbstract: Polycondensation of complexes of chloromethanes with triphenylphosphine by the action of low-voltage electric discharges in the liquid phase gives nanosized solid products. The elemental composition involving the generation of element distribution maps (scanning electron microscopy–energy dispersive X‑ray spectroscopy mapping) and the component composition (by direct evolved gas analysis–mass spectrometry) of the solid products have been studied. The elemental and component compositions of the result-ing structures vary widely depending on the chlorine content in the substrate and on the amount of triphenylphosphine taken. Thermal desorption analysis revealed abnormal behavior of HCl and benzene present in the solid products. In thermal desorption spectra, these components appear at an uncharacteristically high temperature. The observed anomaly in the behavior of HCl is due to HCl binding into a complex of the solid anion HCI-2 with triphenyl(chloromethyl)phosphonium chloride, which requires a relatively high temperature (up to 800 K) to decompose. The abnormal behavior of benzene is associated with its encapsulated state in nanostructures. The appearance of benzene begins at 650 K and continues up to temperatures above 1300 K. © 2022, The Author(s).en
dc.description.sponsorshipThe work was carried out with the equipment of the "Modern Nanotechnologies" Ural Shared-Use Center at the Ural Federal University. The study was supported by the Russian Foundation for Basic Research, project no. 18-29-24008.en
dc.format.mimetypeapplication/pdfen
dc.language.isoenen
dc.publisherPleiades journalsen1
dc.publisherPleiades Publishing Ltden
dc.rightsinfo:eu-repo/semantics/openAccessen
dc.sourceHigh Energy Chem.2
dc.sourceHigh Energy Chemistryen
dc.subjectDICHLOROMETHANEen
dc.subjectLOW-VOLTAGE DISCHARGESen
dc.subjectNONTHERMAL PLASMAen
dc.subjectTETRACHLOROMETHANEen
dc.subjectTRICHLOROMETHANEen
dc.subjectTRIPHENYLPHOSPHINEen
dc.titleSynthesis of Decorated Carbon Structures with Encapsulated Components by Low-Voltage Electric Discharge Treatmenten
dc.typeArticleen
dc.typeinfo:eu-repo/semantics/articleen
dc.typeinfo:eu-repo/semantics/publishedVersionen
dc.identifier.doi10.1007/s00355-015-0939-7-
dc.identifier.scopus85126205345-
local.contributor.employeeBodrikov, I.V., Nizhny Novgorod State Technical University, Nizhny Novgorod, 603950, Russian Federation; Titov, E.Y., Nizhny Novgorod State Technical University, Nizhny Novgorod, 603950, Russian Federation; Vorotyntsev, A.V., Nizhny Novgorod State Technical University, Nizhny Novgorod, 603950, Russian Federation; Pryakhina, V.I., Ural Federal University, Yekaterinburg, 620002, Russian Federation; Titov, D.Y., Nizhny Novgorod State Technical University, Nizhny Novgorod, 603950, Russian Federationen
local.description.firstpage60-
local.description.lastpage69-
local.issue1-
local.volume56-
local.contributor.departmentNizhny Novgorod State Technical University, Nizhny Novgorod, 603950, Russian Federation; Ural Federal University, Yekaterinburg, 620002, Russian Federationen
local.identifier.eid2-s2.0-85126205345-
local.fund.rffi18-29-24008
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