Please use this identifier to cite or link to this item: http://hdl.handle.net/10995/111975
Title: Physical Characterization and Crystallization Kinetics of Amorphous BiSe Chalcogenide Glasses
Authors: Ahmad, M.
Aly, K. A.
Dahshan, A.
Saddeek, Y.
Zakaly, H. M. H.
Elnaeim, A. M. A.
Ene, A.
Issue Date: 2022
Publisher: Elsevier Editora Ltda
Elsevier BV
Citation: Physical Characterization and Crystallization Kinetics of Amorphous BiSe Chalcogenide Glasses / M. Ahmad, K. A. Aly, A. Dahshan et al. // Journal of Materials Research and Technology. — 2022. — Vol. 16. — P. 1114-1121.
Abstract: The influence of Bi concentration on the thermal parameters viz temperatures of glass transition (Tgl) and crystallization (Tpc) of binary BixSe100-x glasses were studied experimentally. The activation energy of glass transition (EGl) has been estimated as the averaged value deduced based on Kissenger's relationship and its approximation. On the other hand, Afify and Aly methods help one to estimate the crystallization activation energy (Epc), the frequency factor (k0) and the order of reaction (n) with no approximation. The observed increase in EGl and Epc values resulted from increasing both Tgl and Tpc with increasing of the Bi content. The Lasocka relationship can describe the heating rate dependence of Tgl and Tpc. A good correlation between Tgl and Tpc was investigated. The attained results were discussed according to the distribution of the chemical bonds, the main coordination number (Nr), average heats of atomization (Hs), the mean bond energy (Es), the cohesive energy (CE), and the overall average bond energy (<E>) for BixSe100-x glasses. © 2021 The Author(s).
Keywords: AVRAMI'S EXPONENT
DSC
THERMAL ANALYSIS
XRD
ACTIVATION ENERGY
BISMUTH COMPOUNDS
BOND STRENGTH (CHEMICAL)
CRYSTALLIZATION KINETICS
GLASS
SELENIUM COMPOUNDS
THERMOANALYSIS
X RAY DIFFRACTION
ACTIVATION ENERGY E
AVRAMI EXPONENT
BOND ENERGIES
CHALCOGENIDE GLASS
CRYSTALLIZATION ACTIVATION ENERGY
DSC
FREQUENCY FACTORS
PHYSICAL CHARACTERIZATION
THERMAL PARAMETERS
XRD
GLASS TRANSITION
URI: http://hdl.handle.net/10995/111975
Access: info:eu-repo/semantics/openAccess
SCOPUS ID: 85121920997
PURE ID: 29211517
ISSN: 2238-7854
metadata.dc.description.sponsorship: The work of Antoaneta Ene and the APC were financed by Dunarea de Jos University of Galati, Romania, through the internal grant with contract no. RF 3621/2021.The authors express their gratitude to the Deanship of Scientific Research, Majmaah University, Saudi Arabia, for funding this research work under Grant (R-2021-303).
Appears in Collections:Научные публикации, проиндексированные в SCOPUS и WoS CC

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