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Полная запись метаданных
Поле DC | Значение | Язык |
---|---|---|
dc.contributor.author | Nikolaev, A. | en |
dc.contributor.author | Suzdaltsev, A. | en |
dc.contributor.author | Pavlenko, O. | en |
dc.contributor.author | Zaikov, Y. | en |
dc.contributor.author | Tatyana, Kurennykh | en |
dc.contributor.author | Vykhodets, V. | en |
dc.date.accessioned | 2021-08-31T15:05:10Z | - |
dc.date.available | 2021-08-31T15:05:10Z | - |
dc.date.issued | 2021 | - |
dc.identifier.citation | Reduction of ZrO2during SNF Pyrochemical Reprocessing / A. Nikolaev, A. Suzdaltsev, O. Pavlenko, et al. — DOI 10.1149/1945-7111/abe8be // Journal of the Electrochemical Society. — 2021. — Vol. 168. — Iss. 3. — 036506. | en |
dc.identifier.issn | 134651 | - |
dc.identifier.other | Final | 2 |
dc.identifier.other | All Open Access, Hybrid Gold | 3 |
dc.identifier.other | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85103290568&doi=10.1149%2f1945-7111%2fabe8be&partnerID=40&md5=986a69ccfdebb42f3cd6a4f0adea3b1e | |
dc.identifier.uri | http://elar.urfu.ru/handle/10995/102738 | - |
dc.description.abstract | Reduction of ZrO2 by lithium during electrolysis of LiCl-KCl-Li2O melt at 650 C was studied using a set of physicochemical methods of analysis. Influence of ZrO2 in the space near a molybdenum cathode on the kinetics of the cathode process was established. Possible variations of the electrode reaction associated with the zirconium reduction were proposed. The appearance of ZrO2 in the cathode space resulted in consumption of reduced lithium and in increase in the potential relaxation time of the molybdenum cathode after cathode polarization. Long-term galvanic impulse electrolysis of LiCl-KCl-Li2O melt at 650 C was carried out using the molybdenum cathode which was immersed into the ZrO2 powder. According to the X-ray fluorescence analysis as well as the method of nuclear reactions the reduction product was presented by the ZrO2, Li2ZrO3, Zr3O phases. Additionally, by alloying the reduction product with tin, the ZrO2 reduction degree to metallic zirconium was estimated, which was close to zero. It was assumed that the main pathway for the appearance of the metallic zirconium in the ZrO2 reduction product during electrolysis of the LiCl-KCl-Li2O melt was direct electroreduction of dissolved zirconium in the melt. © 2021 The Author(s). Published on behalf of The Electrochemical Society by IOP Publishing Limited. | en |
dc.description.sponsorship | The work was carried out within the state assignment of Ministry of Sciences and Higher Education of Russian Federation (theme No AAAA-A16-116051110162-3). Nuclear reaction analysis was performed at the Institute of Metal Physics of the UB RAS within the state assignment of Ministry of Sciences and Higher Education of Russian Federation (theme Function No AAAA-A19-119012990095-0). Atomic emission analysis was conducted on the equipment of the Composition of Compounds the Shared Access Centre of the Institute of High Temperature Electrochemistry of the UB RAS. | en |
dc.format.mimetype | application/pdf | en |
dc.language.iso | en | en |
dc.publisher | IOP Publishing Ltd | en |
dc.rights | info:eu-repo/semantics/openAccess | en |
dc.source | J Electrochem Soc | 2 |
dc.source | Journal of the Electrochemical Society | en |
dc.subject | CATHODES | en |
dc.subject | CHLORINE COMPOUNDS | en |
dc.subject | ELECTROLYSIS | en |
dc.subject | ELECTROLYTIC REDUCTION | en |
dc.subject | FLUORESCENCE | en |
dc.subject | LITHIUM | en |
dc.subject | LITHIUM ALLOYS | en |
dc.subject | LITHIUM COMPOUNDS | en |
dc.subject | MOLYBDENUM | en |
dc.subject | NUCLEAR FUEL REPROCESSING | en |
dc.subject | NUCLEAR REACTIONS | en |
dc.subject | ZIRCALOY | en |
dc.subject | ZIRCONIA | en |
dc.subject | ZIRCONIUM | en |
dc.subject | CATHODE POLARIZATION | en |
dc.subject | ELECTRO REDUCTION | en |
dc.subject | ELECTRODE REACTIONS | en |
dc.subject | PHYSICOCHEMICAL METHODS | en |
dc.subject | POTENTIAL RELAXATION | en |
dc.subject | PYROCHEMICAL REPROCESSING | en |
dc.subject | REDUCTION PRODUCTS | en |
dc.subject | X RAY FLUORESCENCE ANALYSIS | en |
dc.subject | POTASSIUM COMPOUNDS | en |
dc.title | Reduction of ZrO2during SNF Pyrochemical Reprocessing | en |
dc.type | Article | en |
dc.type | info:eu-repo/semantics/article | en |
dc.type | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.rsi | 46770658 | - |
dc.identifier.doi | 10.1149/1945-7111/abe8be | - |
dc.identifier.scopus | 85103290568 | - |
local.contributor.employee | Nikolaev, A., Institute of High-Temperature Electrochemistry UB RAS, Yekaterinburg, 620137, Russian Federation, Ural Federal University, Yekaterinburg, 620002, Russian Federation | |
local.contributor.employee | Suzdaltsev, A., Institute of High-Temperature Electrochemistry UB RAS, Yekaterinburg, 620137, Russian Federation, Ural Federal University, Yekaterinburg, 620002, Russian Federation | |
local.contributor.employee | Pavlenko, O., Institute of High-Temperature Electrochemistry UB RAS, Yekaterinburg, 620137, Russian Federation, Ural Federal University, Yekaterinburg, 620002, Russian Federation | |
local.contributor.employee | Zaikov, Y., Institute of High-Temperature Electrochemistry UB RAS, Yekaterinburg, 620137, Russian Federation, Ural Federal University, Yekaterinburg, 620002, Russian Federation | |
local.contributor.employee | Tatyana Kurennykh, Institute of Metal Physics UB RAS, Yekaterinburg, 620108, Russian Federation | |
local.contributor.employee | Vykhodets, V., Institute of Metal Physics UB RAS, Yekaterinburg, 620108, Russian Federation | |
local.issue | 3 | - |
local.volume | 168 | - |
dc.identifier.wos | 000626528600001 | - |
local.contributor.department | Institute of High-Temperature Electrochemistry UB RAS, Yekaterinburg, 620137, Russian Federation | |
local.contributor.department | Ural Federal University, Yekaterinburg, 620002, Russian Federation | |
local.contributor.department | Institute of Metal Physics UB RAS, Yekaterinburg, 620108, Russian Federation | |
local.identifier.pure | 21182076 | - |
local.identifier.pure | 820972f3-f8a0-47d4-a973-192d33c8fc9c | uuid |
local.description.order | 036506 | - |
local.identifier.eid | 2-s2.0-85103290568 | - |
local.identifier.wos | WOS:000626528600001 | - |
Располагается в коллекциях: | Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC |
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2-s2.0-85103290568.pdf | 1,51 MB | Adobe PDF | Просмотреть/Открыть |
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