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Title: | Kinetic Resolution of Racemic 2-Aryloxy Propionyl Chlorides Using Enantiopure (S)-3,4-Dihydro-3-methyl-2H-[1,4]benzoxazines |
Authors: | Vakarov, S. A. Chulakov, E. N. Sadretdinova, L. S. Kodess, M. I. Ezhikova, M. A. Pervova, M. G. Ganebnykh, I. N. Levit, G. L. Krasnov, V. P. |
Issue Date: | 2020 |
Publisher: | Wiley-Blackwell |
Citation: | Kinetic Resolution of Racemic 2-Aryloxy Propionyl Chlorides Using Enantiopure (S)-3,4-Dihydro-3-methyl-2H-[1,4]benzoxazines / S. A. Vakarov, E. N. Chulakov, L. S. Sadretdinova, et al. — DOI 10.1002/slct.202000629 // ChemistrySelect. — 2020. — Vol. 5. — Iss. 13. — P. 4069-4073. |
Abstract: | Stereoselectivity in the mutual kinetic resolution (KR) of racemic 3,4-dihydro-3-methyl-2H-[1,4]benzoxazines and racemic 2-aryloxy propionyl chlorides was studied. Based on the results obtained, preparative methods for single enantiomers of a series of 2-aryloxy propionic acids via acylative KR of their racemates with enantiopure (S)-3,4-dihydro-3-methyl-2H-[1,4]benzoxazines have been proposed. © 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim |
Keywords: | ACYL CHLORIDES ACYLATION BENZOXAZINES KINETIC RESOLUTION STEREOSELECTIVITY |
URI: | http://elar.urfu.ru/handle/10995/102696 |
Access: | info:eu-repo/semantics/openAccess |
SCOPUS ID: | 85084705676 |
PURE ID: | 12670812 |
ISSN: | 23656549 |
DOI: | 10.1002/slct.202000629 |
metadata.dc.description.sponsorship: | The work was financially supported by the Russian Science Foundation (grant 19‐13‐00231, in the part of studying mutual kinetic resolution) and the Russian Foundation for Basic Research (grant 18‐33‐00027_mol_a, in the part of preparation of enantiomers of 2‐aryloxy propionic acids). Analytical studies were carried out using equipment of the Centre for Joint Use “Spectroscopy and Analysis of Organic Compounds” at the Postovsky Institute of Organic Synthesis, Russian Academy of Sciences (Ural Branch) |
RSCF project card: | 19-13-00231 |
Appears in Collections: | Научные публикации, проиндексированные в SCOPUS и WoS CC |
Files in This Item:
File | Description | Size | Format | |
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2-s2.0-85084705676.pdf | 2,34 MB | Adobe PDF | View/Open |
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