Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на этот ресурс:
http://elar.urfu.ru/handle/10995/75539
Полная запись метаданных
Поле DC | Значение | Язык |
---|---|---|
dc.contributor.author | Richers, M. T. | en |
dc.contributor.author | Breugst, M. | en |
dc.contributor.author | Platonova, A. Y. | en |
dc.contributor.author | Ullrich, A. | en |
dc.contributor.author | Dieckmann, A. | en |
dc.contributor.author | Houk, K. N. | en |
dc.contributor.author | Seidel, D. | en |
dc.date.accessioned | 2019-07-22T06:47:46Z | - |
dc.date.available | 2019-07-22T06:47:46Z | - |
dc.date.issued | 2014 | - |
dc.identifier.citation | Redox-neutral α-oxygenation of amines: Reaction development and elucidation of the mechanism / M. T. Richers, M. Breugst, A. Y. Platonova et al. // Journal of the American Chemical Society. — 2014. — Vol. 136. — Iss. 16. — P. 6123-6135. | en |
dc.identifier.issn | 0002-7863 | - |
dc.identifier.other | https://doi.org/10.1021/ja501988b | |
dc.identifier.other | 1 | good_DOI |
dc.identifier.other | http://www.scopus.com/inward/record.url?partnerID=8YFLogxK&scp=84899538013 | m |
dc.identifier.other | 0d6de8c3-a134-4f11-8ee7-9fde4cbe3c58 | pure_uuid |
dc.identifier.uri | http://elar.urfu.ru/handle/10995/75539 | - |
dc.description.abstract | Cyclic secondary amines and 2-hydroxybenzaldehydes or related ketones react to furnish benzo[e][1,3]oxazine structures in generally good yields. This overall redox-neutral amine α-C-H functionalization features a combined reductive N-alkylation/oxidative α-functionalization and is catalyzed by acetic acid. In contrast to previous reports, no external oxidants or metal catalysts are required. Reactions performed under modified conditions lead to an apparent reductive amination and the formation of o-hydroxybenzylamines in a process that involves the oxidation of a second equivalent of amine. A detailed computational study employing density functional theory compares different mechanistic pathways and is used to explain the observed experimental findings. Furthermore, these results also reveal the origin of the catalytic efficiency of acetic acid in these transformations. © 2014 American Chemical Society. | en |
dc.format.mimetype | application/pdf | en |
dc.language.iso | en | en |
dc.publisher | American Chemical Society | en |
dc.rights | info:eu-repo/semantics/openAccess | en |
dc.source | Journal of the American Chemical Society | en |
dc.subject | ACETIC ACID | en |
dc.subject | KETONES | en |
dc.subject | PH | en |
dc.subject | 2-HYDROXYBENZALDEHYDES | en |
dc.subject | C-H FUNCTIONALIZATION | en |
dc.subject | CATALYTIC EFFICIENCIES | en |
dc.subject | COMPUTATIONAL STUDIES | en |
dc.subject | FUNCTIONALIZATIONS | en |
dc.subject | MECHANISTIC PATHWAYS | en |
dc.subject | MODIFIED CONDITIONS | en |
dc.subject | REDUCTIVE AMINATION | en |
dc.subject | AMINES | en |
dc.subject | ACETAL DERIVATIVE | en |
dc.subject | ACETIC ACID | en |
dc.subject | AMINE | en |
dc.subject | AMPHOLYTE | en |
dc.subject | BENZYLAMINE | en |
dc.subject | CARBONYL DERIVATIVE | en |
dc.subject | ISOQUINOLINE DERIVATIVE | en |
dc.subject | KETONE | en |
dc.subject | METAL | en |
dc.subject | OXIDIZING AGENT | en |
dc.subject | SALICYLALDEHYDE | en |
dc.subject | TOLUENE | en |
dc.subject | AMINE | en |
dc.subject | OXYGEN | en |
dc.subject | ALKYLATION | en |
dc.subject | AMINATION | en |
dc.subject | ARTICLE | en |
dc.subject | CATALYSIS | en |
dc.subject | CATALYST | en |
dc.subject | CYCLOADDITION | en |
dc.subject | DENSITY FUNCTIONAL THEORY | en |
dc.subject | ENERGY | en |
dc.subject | HYDROGEN BOND | en |
dc.subject | ISOMERIZATION | en |
dc.subject | OXIDATION REDUCTION REACTION | en |
dc.subject | OXYGENATION | en |
dc.subject | PROTON NUCLEAR MAGNETIC RESONANCE | en |
dc.subject | REACTION ANALYSIS | en |
dc.subject | REACTION OPTIMIZATION | en |
dc.subject | REDUCTION | en |
dc.subject | TEMPERATURE DEPENDENCE | en |
dc.subject | CHEMICAL STRUCTURE | en |
dc.subject | CHEMISTRY | en |
dc.subject | CONFORMATION | en |
dc.subject | OXIDATION REDUCTION REACTION | en |
dc.subject | AMINES | en |
dc.subject | CATALYSIS | en |
dc.subject | KETONES | en |
dc.subject | MODELS, MOLECULAR | en |
dc.subject | MOLECULAR CONFORMATION | en |
dc.subject | OXIDATION-REDUCTION | en |
dc.subject | OXYGEN | en |
dc.subject | TOLUENE | en |
dc.title | Redox-neutral α-oxygenation of amines: Reaction development and elucidation of the mechanism | en |
dc.type | Article | en |
dc.type | info:eu-repo/semantics/article | en |
dc.type | info:eu-repo/semantics/publishedVersion | en |
dc.identifier.doi | 10.1021/ja501988b | - |
dc.identifier.scopus | 84899538013 | - |
local.affiliation | Department of Chemistry and Chemical Biology, Rutgers, State University of New Jersey, Piscataway, NJ 08854, United States | en |
local.affiliation | Department of Chemistry and Biochemistry, University of California, Los Angeles, CA 90095, United States | en |
local.affiliation | Department für Chemie, Universität zu Köln, Greinstraße 4, 50939 Köln, Germany | en |
local.affiliation | Department of Organic Synthesis Technology, Ural Federal University, Yekaterinburg 620002, Russian Federation | en |
local.affiliation | Institut für Bioorganische Chemie, Heinrich-Heine Universität Düsseldorf, Stetternicher Forst, 52426 Jülich, Germany | en |
local.contributor.employee | Молвинских Алена Юрьевна | ru |
local.description.firstpage | 6123 | - |
local.description.lastpage | 6135 | - |
local.issue | 16 | - |
local.volume | 136 | - |
dc.identifier.wos | 000335086100049 | - |
local.identifier.pure | 374355 | - |
local.identifier.eid | 2-s2.0-84899538013 | - |
local.identifier.wos | WOS:000335086100049 | - |
Располагается в коллекциях: | Научные публикации ученых УрФУ, проиндексированные в SCOPUS и WoS CC |
Файлы этого ресурса:
Файл | Описание | Размер | Формат | |
---|---|---|---|---|
2-s2.0-84899538013.pdf | 3,42 MB | Adobe PDF | Просмотреть/Открыть |
Все ресурсы в архиве электронных ресурсов защищены авторским правом, все права сохранены.